强磁场条件下Mn-Sb梯度复合材料的制备

研究了Mn-898wt%Sb合金在无磁场以及磁场为B=88 T、不同强度的磁场梯度作用下的凝固组织变化，并分析了上述不同强磁场条件对合金凝固组织影响的作用机理.研究表明，在较大梯度磁场作用时，试样中出现了初生MnSb相与Sb相以及共晶组织共存的现象，而且初生MnSb相与Sb相产生了明显的分层现象.此外，磁场梯度作用下初生MnSb相和Sb相的含量随着磁场梯度的增大而增加.论文对初生MnSb相和Sb相的分离机理进行了探讨，发现在梯度磁场作用下，熔融金属中不同磁化率的合金组元团簇受力不同，造成     

The effect of a surface energy term on the distribution of phases in an elastic medium with a two‐well elastic potential

We consider the problem of minimizing among functions u:?^d?Ω→?^d, u_∣?Ω=0, and measurable subsets E of Ω. Here f_h⁺, f^? denote quadratic potentials defined on Ω¯×{symmetric d×d matrices}, h is the minimum energy of f_h⁺ and ε(u) is the symmetric gradient of the displacement field u. An equilibrium state û, Ê of J(u,E) is called one‐phase if E=?? or E=Ω, two‐phase otherwise. For two‐phase states, σ∣?E∩Ω∣ measures the effect of the separating surface, and we investigate the way in which the distribution of phases is affected by the choice of the parameters h??, σ>0. Additional results concern the smoothness of two‐phase equilibrium states and the behaviour of inf J(u,E) in the limit σ↓0. Moreover, we discuss the case of additional volume force potentials, and extend the previous results to non‐zero boundary values. Copyright © 2002 John Wiley & Sons, Ltd.     

The effect of a penalty term involving higher order derivatives on the distribution of phases in an elastic medium with a two‐well elastic potential

We consider the problem of minimizing 0<p<1, h∈?, σ>0, among functions u:?^d?Ω→?^d, u_∣?Ω=0, and measurable characteristic functions χ:Ω→?. Here ?⁺_h, ?^?, denote quadratic potentials defined on the space of all symmetric d×d matrices, h is the minimum energy of ?⁺_h and ε(u) denotes the symmetric gradient of the displacement field. An equilibrium state û, χ?, of I [·,·,h, σ] is termed one‐phase if χ?≡0 or χ?≡1, two‐phase otherwise. We investigate the way in which the distribution of phases is affected by the choice of the parameters h and σ. Copyright 2002 John Wiley & Sons, Ltd.     

Mössbauer Spectroscopy on Nuclear Power Plant Materials

Experimental results of original irradiated reactor pressure vessel surveillance specimens are presented and discussed in the paper. In 1994, the new Extended Surveillance Specimen Program for Nuclear Reactor Material Study was started in collaboration with the nuclear power plant (NPP) Bohunice and NPP Research Institute Trnava (Slovakia). Three batches of special prepared Mössbauer samples (after 1, 2 and 3 years stay in irradiation channels) were measured and interpreted using the new four components approach of Mössbauer spectra evaluation with the aim to observe microstructural changes due to thermal and neutron treatment resulting from operating conditions in NPP. The systematic changes in the relative areas of Mössbauer spectra components were observed and discussed.     

On the microscopic foundations of elasticity

The modeling of the elastic properties of disordered or nanoscale solids requires the foundations of the theory of elasticity to be revisited, as one explores scales at which this theory may no longer hold. The only cases for which microscopically based derivations of elasticity are documented are (nearly) uniformly strained lattices. A microscopic approach to elasticity is proposed. As a first step, microscopically exact expressions for the displacement, strain and stress fields are derived. Conditions under which linear elastic constitutive relations hold are studied theoretically and numerically. It turns out that standard continuum elasticity is not self-evident, and applies only above certain spatial scales, which depend on details of the considered system and boundary conditions. Possible relevance to granular materials is briefly discussed. Received 18 March 2002 and Received in final form 29 May 2002     

Nonlinear optical characterization of cluster dynamic in water in oil microemulsion by a pump probe laser beam technique

We present a new pump probe laser beams configuration for the nonlinear optical characterization of microemulsions. We detect the variation of the on-axis optical intensity of the probe beam as generated by the concentration profile induced in an optically thin film of microemulsion by the pump beam. A mathematical model has been introduced to describe the phenomenon. The technique allows the determination of both Kerr-like optical nonlinearity and time constants and, therefore, it gives information both on cluster dimension and their shape. We discuss its application to WAD (water/AOT/decane, where AOT denotes sodium-bis-di-ethyl-sulfosuccinate) with the application of a strong electric field of optical source. Comparison between theoretical predictions and experimental results confirms the presence of giant optical nonlinearity in the absence of turbidity divergence. Chainlike shape of clusters, of the kind already reported with the application of strong electric field, could justify this result. Received 26 October 2002 RID="a" ID="a"e-mail: vicari@na.infn.it     

Restructuring of force networks

The compaction of granular packings or soils is a collective process which for higher densities becomes increasingly slower reaching glassy behaviour. We present a study of this problem from various points of view, in particular we will represent the evolving force network that percolates through the system by an inverse fiber rupture model. Received 15 March 2002 and Received in final form 29 July 2002     

Simulation on the Effect of Brownian Motion on Nanoparticle Trajectories in a Pulsed Microplasma Cluster Source

We describe a simulation of the nanoparticle trajectories in a pulsed cluster beam source. Clusters, formed by condensation of atomic vapor in a helium bath, and considered here as rigid spheres having a diameter of 1.5nm, were tracked during their travel inside the source cavity, an aerodynamic lens, and a cylindrical nozzle. Steady state supersonic laminar flow of helium is considered in an axi-symmetric geometry aiming to simulate, within some limitations, the conditions under which cluster formation takes place in a pulsed microplasma cluster source. In spite of the unsteady nature of the pulsed source, the time scale characterizing particle motion in the flow field is significantly smaller than the characteristic time constant for the evolution of gas pressure in the source. For this reason, a steady simulation can shed some light on the understanding of processes governing nanoparticle motion in a pulsed vaporization source. The extent to which the Brownian diffusion can affect the particle extraction from the source is investigated. Simulations have shown that the Brownian motion perturbs the clusters from the trajectories dictated by the carrier gas and increases the rate of cluster deposition on the source internal walls. However, it does not hinder the aerodynamic focalization produced by the lens even in nano-size cluster regime. This result is qualitatively confirmed by experiment.     

Evolution of magnetism in U(Ni 1- xPd x) Si single crystals

Single crystals of U(Ni_1-xPd_x)₂Si₂ with x = 0.05, 0.09 and 0.135 have been grown. Magnetization and electrical resistivity measurements were performed in a wide range of temperatures and magnetic fields in order to study stability of magnetic phases in the solid solutions between UNi₂Si₂ and UPd₂Si₂ with a special emphasis on the type of ground state. In UPd₂Si₂ the simple AFI-type antiferromagnetic structure of U moments is observed at low temperatures. UNi₂Si₂ adopts the uncompensated AF structure (UAF) with the + + - stacking of U moments along the c-axis and consequently this compound exhibits a spontaneous magnetization corresponding to 1/3 of the U moment. The substitution of Pd for Ni leads to a rapid decay of the spontaneous magnetization. The evolution of magnetization and electrical resistivity behavior with Pd doping is tentatively attributed to the coexistence of the AF-I and UAF phases in the ground state of U(Ni_0.91Pd_0.09)₂Si₂ and U(Ni_0.865Pd_0.135)₂Si₂. In this scenario, the volume fraction of the AF-I phase rapidly grows with Pd doping on account of the UAF. At lowest temperatures an irreversible transition to the UAF phase is observed when a sufficiently high magnetic field is applied along the c-axis. Received 28 March 2002 / Received in final form 8 August 2002 Published online 19 December 2002 RID="a" ID="a"e-mail: sech@mag.mff.cuni.cz