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排序方式: 共有2834条查询结果,搜索用时 15 毫秒
101.
Thomas P J Linsinger Alexander Bernreuther Philippe Corbisier Marta Dabrio Håkan Emteborg Andrea Held Andrée Lamberty Gaida Lapitajs Marina Ricci Gert Roebben Stefanie Trapmann Franz Ulberth Hendrik Emons 《Accreditation and quality assurance》2007,12(3-4):167-174
The potential approaches for third-party assessment of reference material producers are revisited and the activities of the
Reference Materials (RM) Unit of the Institute for Reference Materials and Measurements (IRMM) to obtain accreditation to
ISO Guide 34 and ISO 17025 are described. Accreditation was related to the Unit as all matrix RM activities of the institute
are concentrated there. A management system was established that allows sufficient flexibility to be applicable to a wide
range of RMs while being precise enough to ensure compliance with ISO Guides 30, 31 and especially 34 and 35. Accreditation
was achieved in 2004 with independent scopes for testing and RM production and was confirmed and extended in 2005. The key
aspects of the RM Unit's management system for RM production are presented.
Presented at BERM-10, April 2006, Charleston, SC, USA 相似文献
102.
Dan‐Huang‐Qu‐Yu capsule, a Chinese herbal medicine compound preparation, is widely used for chronic pelvic inflammatory disease. In this study, a rapid, selective, and sensitive microwave‐assisted extraction ultra‐high‐performance liquid chromatography‐Q Exactive quadrupole‐orbitrap high‐resolution mass spectrometry method was developed for analyzing its chemical compositions. A total of 85 compounds, including 22 flavonoids, 8 terpenoids, 5 quinones, 5 phthaleolactone, 23 organic acids, and 22 other compounds were identified from Dan‐Huang‐Qu‐Yu capsule. Among them, 35 major compounds were unambiguously detected by comparing them with reference standards and selected as quality control markers, which were simultaneously determined in Dan‐Huang‐Qu‐Yu capsule. The established method was successfully validated and applied for simultaneous determination of 35 bioactive compounds in Dan‐Huang‐Qu‐Yu capsule from ten sample batches. The quantitative data of the analytes were analyzed by principal component analysis for quality assessment of Dan‐Huang‐Qu‐Yu capsule. Six compounds (e.g., astragaloside IV, salvianolic acid B, ellagic acid, chlorogenic acid, N‐butylidenephthalide, and luteolin) were screened out and regarded as chemical markers for quality control of Dan‐Huang‐Qu‐Yu capsule. The established method has been proved to be a novel and useful tool for rapid research of Dan‐Huang‐Qu‐Yu capsule. This research will provide reference for the scientific research of traditional Chinese medicines. 相似文献
103.
The robustness testing of a normal-phase liquid chromatographic (LC) method for the determination of R-timolol and other related substances in S-timolol maleate was performed applying a two-level Plackett-Burman design. Two qualitative and five quantitative factors were examined. Two types of responses were considered, qualitative, i.e. chromatographic performance criteria, and quantitative ones. The latter were taken into account to determine if the analytical procedure was robust. The quantitative responses were the contents of R-timolol in two S-timolol maleate samples. Even though some significant factor effects were observed on the qualitative responses, the R-timolol contents were not significantly different from those observed at nominal conditions, which demonstrated the robustness of the procedure.Since the experiments of the Plackett-Burman design can be assimilated to laboratories in an interlaboratory study, uncertainty can be evaluated using the robustness test data. The robustness test was set-up in such a way that the required variances could be estimated. It was shown that the robustness set-up allows estimating the reproducibility uncertainty without performing an interlaboratory study. 相似文献
104.
Odlyha M. Cohen N. S. Campana R. Foster G. M. 《Journal of Thermal Analysis and Calorimetry》1999,56(3):1219-1232
This paper describes the results and conclusions of research directed towards the development and evaluation of a chemical
sensor which would provide information on the quality of indoor environments surrounding cultural objects. In our case these
objects were paintings housed in major European galleries and the main objective is their preservation through an improved
understanding of their microenvironment. The concept was to prepare and expose test tempera paintings which would behave as
dosimeters and integrate the environmental response at these locations. Artificial ageing of similar samples was performed
to provide a means of calibrating the test paintings. Samples from the test paintings were compared with artificially aged
samples and this enabled the sites to be ranked in terms of their suitability for exposure of cultural objects.
Additionally, novel methodology involving piezoelectric sensors was designed for monitoring the relative humidity and temperature
of the microenvironment of paintings. Dielectric techniques were also used for measuring the effect of relative humidity fluctuations
on artists' materials and novel non-invasive dielectric techniques in the microwave region were used for the determination
of their moisture content.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
105.
I. Nerád O. Fabrichnaya L. Kosa E. Mikšíková S. Šaušová 《Journal of Thermal Analysis and Calorimetry》1999,56(1):395-400
The thermodynamic data are assessed by using molecular solution model with excess Gibbs energy of mixing expressed by Redlich-Kister
equation with temperature dependent parameters. The optimized data involve phase equilibria, enthalpy and entropy of formation
of crystalline phases, heat capacity (Cp) data of solid and liquid pure components, enthalpy of mixing of liquid pure components, enthalpy and entropy of fusion of
solid phases. Thermodynamic quantities consistent with available experimental phase equilibria and calorimetric measurements
are established for solid phases and liquids in the system CaO·SiO2 (CS)-CaO·Al2O3·2SiO2 (CAS2)-2CaO·Al2O3·SiO2 (C2AS).
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
106.
Rashid A. Zeineh George Kyriakidis Roger Acey Christopher Smith 《Applied biochemistry and biotechnology》1986,13(2):119-125
Citrus tristeza virus (CTV) extracted from Etrog citron (C.medica L.) was immunoprecipitated. The immunoprecipitate was fractionated by SDS-PAGE and western blotted onto nitrocellulose. The CTV
antigens were determined by immunoblot analysis using rabbit anti-CTV IgG, and the protein-band pattern exhibited on the nitrocellulose
was assessed by soft-laser scanning densitometry. The densitometric tracing revealed the presence of bands that were not visible
to the naked eye. Using the superimposition mode of the instrument, it was also revealed that the protein-band patterns of
different CTV samples were not identical. Computer-aided soft-laser scanning densitometry proved to be a powerful approach
in the detection and assessment of protein bands revealed on nitrocellulose immunoblots, which we were previously unable to
do employing conventional methods. 相似文献
107.
Yahui Yan Rahima Abdulla Xiaoyan Liu Shuping Li Haji Akber Aisa 《Journal of separation science》2022,45(13):2148-2160
108.
Agnieszka Zapanik Marcin Brya Agnieszka Wakiewicz Edyta Ksieniewicz-Wo
niak Grayna Podolska 《Molecules (Basel, Switzerland)》2022,27(1)
The aim of this study was to estimate the contamination of grain coffee, roasted coffee, instant coffee, and cocoa purchased in local markets with ochratoxin A (OTA) and its isomerization product 2′R-ochratoxin A (2′R-OTA), and to assess risk of dietary exposure to the mycotoxins. OTA and 2′R-OTA content was determined using the HPLC chromatography with immunoaffinity columns dedicated to OTA. OTA levels found in all the tested samples were below the maximum limits specified in the European Commission Regulation EC 1881/2006. Average OTA concentrations calculated for positive samples of grain coffee/roasted coffee/instant coffee/cocoa were 0.94/0.79/3.00/0.95 µg/kg, with the concentration ranges: 0.57–1.97/0.44–2.29/0.40–5.15/0.48–1.97 µg/kg, respectively. Average 2′R-OTA concentrations calculated for positive samples of roasted coffee/instant coffee were 0.90/1.48 µg/kg, with concentration ranges: 0.40–1.26/1.00–2.12 µg/kg, respectively. In turn, diastereomer was not found in any of the tested cocoa samples. Daily intake of both mycotoxins with coffee/cocoa would be below the TDI value even if the consumed coffee/cocoa were contaminated with OTA/2′R-OTA at the highest levels found in this study. Up to now only a few papers on both OTA and 2′R-OTA in roasted food products are available in the literature, and this is the first study in Poland. 相似文献
109.
以云南省昆明市东川主要河流及附近土壤、植物为研究对象,对其进行采样分析,并根据美国环境保护署(U.S.EPA)推荐健康风险评价方法对东川流域多种环境因素进行了重金属的健康风险评价。结果表明,水环境中致癌物质造成的风险最大,风险值在2.35×10^(-4)~8.27×10^(-4),达到U.S.EPA推荐的最大值10^(-4),植物根部的健康风险值为0.40×10^(-1)~7.00×10^(-1),茎叶部分的风险值为2.42×10^(-2)~15.24×10^(-2),根部存在的重金属对人体的健康风险约为茎叶部分的5倍;土壤中非致癌物质的健康风险影响较大,总健康风险值区间为0.64×10^(-1)~3.83×10^(-1)。评价结果可为该区域地表水、土壤和植物资源的污染治理、保护开发提供依据。 相似文献
110.