One-step mild hydrothermal method to prepare low valent sodium vanadium(III) monohydrogenphosphate: NaV(HPO4)2

Green colored single crystals of a reduced sodium vanadium(III) monohydrogenphosphate, NaV(HPO₄)₂, were grown using a one-step mild hydrothermal method. The in situ reduction of V⁵⁺ to V³⁺ was performed using copper acetate as the reducing agent. The title compound crystalizes in the monoclinic space group Cc and exhibits a three-dimensional crystal structure that consists of distorted VO₆ octahedra connected to PO₃(OH) tetrahedra that are further connected via Na cations. The compound exhibits simple paramagnetic behavior at high temperatures and a discontinuity near 5 K is likely due to the onset of magnetic coupling. The compound was also characterized by TGA, IR and UV–vis spectroscopies.     

过渡金属盐催化甲基丙烯酸2-(N,N-二乙氨基)乙酯的自引发自由基聚合

研究了高氧化态过渡金属盐(CuX2/L、FeX3/L,X=C1或Br;L =2,2′-联吡啶、N,N'-四甲基乙二胺、N,N,N′,N″,N″-五甲基二亚乙基三胺;CuSO4)催化甲基丙烯酸2-(N,N-二乙氨基)乙酯(DEAEMA)的自引发氧化聚合,利用气相色谱跟踪单体转化率、利用凝胶渗透色谱和多角激光光散射跟踪聚合...     

Joint Reducing Subspaces of Multiplication Operators and Weight of Multi-variable Bergman Spaces

This paper mainly concerns a tuple of multiplication operators defined on the weighted and unweighted multi-variable Bergman spaces, their joint reducing subspaces and the von Neumann algebra generated by the orthogonal projections onto these subspaces. It is found that the weights play an important role in the structures of lattices of joint reducing subspaces and of associated von Neumann algebras. Also, a class of special weights is taken into account. Under a mild condition it is proved that if those multiplication operators are defined by the same symbols, then the corresponding von Neumann algebras are $*$-isomorphic to the one defined on the unweighted Bergman space.     

用可视化方法优化微生物培养基的营养条件

应用可视化方法,对生物发酵培养基的营养条件进行优化.以培养基组成构建多维向量空间,通过降维分析法将多维空间的拓扑结构展现在二维平面上,变成可视化图像,并自动产生目标函数等值线.从中得出同时满足各项指标值的最佳操作区域,并运用逆映射公式将得出最优化区域逆推到原高维空间,进而得到最优培养基组成.以锌酵母为例,介绍可视化方法优化全过程.     

Efficient synthesis of 1-deoxy-azasugars as useful synthetic tools

1-Deoxy-azasugars are efficiently prepared from sugar-lactones using a stereoinversion process and they are applied to the synthesis of a natural product.     

Two storage inventory model in a mixed environment

Multi-item inventory models with two storage facility and bulk release pattern are developed with linearly time dependent demand in a finite time horizon under crisp, stochastic and fuzzy-stochastic environments. Here different inventory parameters—holding costs, ordering costs, purchase costs, etc.—are assumed as probabilistic or fuzzy in nature. In particular cases stochastic and crisp models are derived. Models are formulated as profit maximization principle and three different approaches are proposed for solution. In the first approach, fuzzy extension principle is used to find membership function of the objective function and then it’s Graded Mean Integration Value (GMIV) for different optimistic levels are taken as equivalent stochastic objectives. Then the stochastic model is transformed to a constraint multi-objective programming problem using Stochastic Non-linear Programming (SNLP) technique. The multi-objective problems are transferred to single objective problems using Interactive Fuzzy Satisfising (IFS) technique. Finally, a Region Reducing Genetic Algorithm (RRGA) based on entropy has been developed and implemented to solve the single objective problems. In the second approach, the above GMIV (which is stochastic in nature) is optimized with some degree of probability and using SNLP technique model is transferred to an equivalent single objective crisp problem and solved using RRGA. In the third approach, objective function is optimized with some degree of possibility/necessity and following this approach model is transformed to an equivalent constrained stochastic programming problem. Then it is transformed to an equivalent single objective crisp problem using SNLP technique and solved via RRGA. The models are illustrated with some numerical examples and some sensitivity analyses have been presented.     

Synthesis,Crystal Structure and Luminescent Property of a Novel Pt（Ⅱ） Complex with Weak Metal-metal Interaction

The title complex cis-bis（tetrahydrothiophene）-bis（nitrate） platinum（H）, （tht）2Pt（NO3）2, was the reducing product from potassium hexachloroplatinate（IV） K2PtC16 where the platinum is tetra-valenced. Crystal data for CsH16N206PtS2： monoclinic, space group P21/c, a = 9.8833（5）, b = 8.6744（4）, c = 18.6407（9）A,β = 114.401（3）°, V = 1455.35（12）A3 Z = 4, Mr = 495.44, Dc = 2.261 g/cm3, F（000） = 944,μ = 9.950 mm-1, 2（MoKa） = 0.71073 A, T= 293（2） K, 2θmax = 54.96°, GOOF = 1.033, R = 0.0350 and wR = 0.0785 for 2572 observed reflections with I 〉 2σ（I）. X-ray diffraction studies reveal that the title complex has interesting weak metal-metal interactions and two molecules linked by metal-metal interaction exist as a group. Luminescent spectrum illuminates red emission of the complex at room temperature.     

Indirect fluorescence detection of amino sugars with the use of copper complexes of tryptophan and its analogues following high-performance liquid chromatographic separation

A simple, indirect fluorescence detection method has been developed for detecting specific mono-amino sugars (D-glucosamine, D-galactosamine, D-mannosamine) following chromatographic separation. The eluting amino sugars release L-tryptophan (L-Trp) from a copper-tryptophan complex which is introduced postcolumn. Analyte detection is based on measuring the increase in L-Trp fluorescence, which is quenched when complexed with copper. Two tryptophan analogues, 5-hydroxy-L-tryptophan (5-HTP) and DL-5-methoxytryptophan (5-MTP), were also evaluated as postcolumn reagents. 5-MTP was found to be a suitable alternative to L-Trp for the detection of these mono-amino sugars. Detection limits for D-glucosamine, D-galactosamine, and D-mannosamine are in the range of 0.15-0.30 nmol injected.