Ce3+离子敏化Eu3+∶Cr3+∶Sm3+∶YAG外延层的荧光现象

对Ce3+ ∶Eu3+ ∶Cr3+ ∶Sm3+ ∶YAG处延层中的荧光敏化现象进行了报道和分析 ,在较高浓度的Ce3+ 离子掺杂时 ,外延层在蓝色、绿色波段出现了新的荧光谱线 ,可解释为在Ce3+ 离子敏化作用下 ,Eu3+ 离子产生了由高位激发态能级5Di(i=1,2 ,3)直接到基态能级7Fj(j =0 ,1,2 ,3)的辐射跃迁过程 ,并且这种Ce3+ ∶Eu3+ ∶Cr3+ ∶Sm3+ ∶YAG外延层还是一种新颖的白色单晶荧光材料。     

有机染料掺杂玻璃的制备及荧光性能

铅-锡-氟磷酸盐玻璃是各种激光染料及非线性染料的理想基质,本文报道了荧光素及吖啶红掺杂铅-锡-氟磷酸盐玻璃的荧光性能,并且将吖啶红掺入有机改性的钛凝胶(TiO2-Ormosil),对两者的荧光性能进行了比较。     

Ca2Li2BiV3O12∶Eu3+荧光粉的制备和发光性能

采用高温固相法成功合成了一种可用于白光LED的Ca₂Li₂BiV₃O₁₂∶Eu³⁺新型红色荧光粉,使用X射线衍射仪和荧光分光光度计对合成样品进行了表征,研究了合成温度和Eu³⁺含量对合成样品相组成和发光性能的影响。结果表明,采用高温固相法在650~700 ℃能合成纯度较高、结晶度好的Ca₂Li₂BiV₃O₁₂∶Eu³⁺荧光粉,合成样品激发带覆盖200~400 nm,发射光谱的线状发射峰可归属于Eu³⁺的⁵D₀→⁷F_J(J= 1, 2, 3,4)特征锐线发射,Eu³⁺摩尔分数为14%时荧光粉的发光强度最大。     

化学共沉淀法制备的(Y1-x-y,Gdy)2O3∶xEu3+红色荧光粉及其发光性能

用化学共沉淀法一次煅烧工艺合成了 (Y_1-x-y,Gd_y)₂O₃∶xEu³⁺(x=0.06~0.10,y=0,0.20~0.25)系列红色荧光粉。用XRD、SEM和荧光分光光度计,对试样的晶体结构、表面形貌及发光性能进行表征。研究了Eu³⁺、Gd³⁺的掺杂浓度、表面活性剂的加入、煅烧温度对样品性能的影响。结果表明:样品为立方晶系;Gd³⁺的加入会使基体晶格发生畸变,晶胞参数增加,起到改善样品色纯度和发光效率的作用;最佳煅烧温度为900 ℃,比传统的高温固相法低500 ℃左右;所合成荧光粉的粒度主要分布在300~400 nm,结构比较松散;当x=0.08,y=0.23时,最大发射峰(λ_em=613 nm)强度最大。所合成的(Y_1-x-y,Gd_y)₂O₃∶xEu³⁺荧光粉是一种性能较好的PDP用红色荧光粉。     

Transparent and flexible field emission display device based on single‐walled carbon nanotubes

A fully transparent and flexible field emission device (FED) has been demonstrated. Single‐walled carbon nanotubes (SWCNTs) coated on arylite substrate were used as electron emitters for the FED and a novel metavanadate phosphor coated on the SWCNTs/arylite film was used as transparent and flexible screen. The SWCNTs/arylite based emitters and the SWCNTs/arylite/metal‐vanadate‐based phosphor showed a transmittance value of 92.6% and 54%, respectively. The assembled device also showed satisfactory transparency and flexibility as well as producing significant current. Metavanadate phosphor is considered to be an excellent candidate due to its superior luminescence properties and easy fabrication onto transparent and flexible conductive substrate at room temperature while retaining reasonable transparency of the substrate. Thus, its transparency and flexibility will open the door to next‐generation FEDs. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Ru(bpy)32+聚电解质光致发光电致发光性质

以Ru(bpy)3^2 作为发光材料研制聚合物电致发光器件,分别以水溶性聚乙烯基氯化铵(PAA)和聚苯乙烯基磺酸钠(PSSTS)作为母体材料,研究了聚阴阳离子对器件性质的影响。通过对器件结构、母体浓度、掺杂浓度进行优选,得到结构为ITO／PVK／Ru：PAA/LiF／Al的器件。这一器件开启电压为3．5V,效率为1．1lm/W。     

红光InAlAs量子点的结构和光学性质

利用ＭＢＥ方法在（００１）衬底上成功地生长密度大、尺寸小、发红光的ＩｎＡｌＡｓ／ＡｌＧａＡｓ量子点结构。通过原子力显微镜观察表明,ＩｎＡｌＡｓ量子的密度和大小都随覆盖厚度的增加而增大;发现Ａｌ原子的表面迁移率决定ＩｎＡｌＡｓ量子点的形貌,光荧光谱证实了量子点的发光峰值在红光范围,并结合形貌的统计得到了量子点的发光峰展宽主要昌受量子点的横向尺寸影响。     

纳米银粒子表面包覆分子共振吸收峰的红移现象

本文首次发现了两种电性不同的染料分子若丹明6G及荧光素钠包覆纳米银粒子时,染料分子共振吸收峰的红移现象,以及产生红移的条件。前者只有在KC1、KBr、KI等电解质存在时才产生红移;而后者则无需这些电解质存在。其红移量分别为27um及13nm.并对产生红移的机理进行了讨论。     

LASING FROM A DYE-DOPED PENDANT DROP AND ITS PRECESSION

We have observed lasing from the rim of dye-doped ethylene glycol pendant drops. Spatial-resolved spectral measurements show that the lasing wavelength varies along a vertical rim of the drop. Time-resolved measurements indicate that lasing precession occurs within the drop. Various lasing patterns due to lasing precession are explained. The measured precession periods for different pumping points are in good agreement with the calculated values based on morphology-dependent resonance theory.