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941.
Preparation and characterization of nanosized GdxBi0.95-xVO4:0.05Eu3+ solid solution as red phosphor
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A complete solid solutions with monophasic zircon-type structure of vanadates of formula GdxBio.95-xVO4:0.05Eu3+ (x = 04).95) are synthesized by combined method of co-precipitation and hydrothermal synthesis. Their microstructures and morphologies are characterized by X-ray powder diffraction and transmission electronic microscope, and the results show that each of all the samples has a monophasic zircon-type structure. The absorption spectrum of the prepared phosphor shows a blue-shift of the fundamental absorption band edge with increasing the gadolinium content. Under UV-light and visible-light excitation, all the prepared phosphors show the typical luminescence properties of Eu3+ in the zircon-type structure. The emission intensity of GdxBi0.95-xVO4:0.05Eu3+ (x = 0.55) is strongest in all samples under UV-light and visible-light excitations. Finally, the mechanisms of luminescence of Eu3+ in the GdxBi0.95-xVO4:0.05Eu3+ (x = 0-0.95) solid solutions are analyzed and discussed. 相似文献
942.
943.
氨苄西林与铜(Ⅱ)形成配合物,减弱了铜(Ⅱ)对核固红的荧光猝灭作用,导致体系荧光增强,据此提出了一种测定氨苄西林含量的荧光光谱法。考察了缓冲溶液、试剂加入顺序、核固红和铜(Ⅱ)的浓度、反应温度和时间、离子强度等对体系的影响。在最佳试验条件下,氨苄西林的质量浓度在0.50~26mg·L-1范围内与增强的荧光强度呈线性关系,检出限(3s/k)为0.40 mg·L-1。将方法用于氨苄西林胶囊中氨苄西林含量的测定,回收率在98.1%~101%之间,测定值的相对标准偏差(n=6)在1.7%~2.1%之间。 相似文献
944.
Energy transfer relation of a novel Ce~(3+)/Pr~(3+)/Eu~(3+) co-doped Sr_(2.975-x)La_xAlO_(4+x)F_(1-x) solid solution phosphor
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The photoluminescence properties and energy transfer of a new Ce3+/ Pr3+/ Eu3+co-doped solid-solution composition of Sr2.975-xLaxAlO4+xF1-x(LSAF) phosphor are investigated. Upon doping Pr3+into lattices of LSAF:Ce host,a shoulder emission peak is observed at about 620 nm, owing to the transition of1D2→3H4. Addition of Eu3+to LSAF:Ce3+, Pr3+phosphor results in a sharp emission peaked at 675 nm for the5D0→7F3transition and an increase of the intensity of red emission for Pr3+with increasing Eu3+concentration. The pathways of energy transfer among Ce3+, Pr3+, and Eu3+are proposed to be responsible for color addition of a red component to the primary yellow emission,enabling a potential adjustable color for blue excitable warm white. 相似文献
945.
946.
为了查清1997年水环境改善后新疆大学红湖的浮游生物群落特征及水环境的变化情况1998年5 ̄6月对红湖三个样点浮游生物进行了调查,共记录了藻类,原生动物、轮虫、甲壳动物41种,同时对水环境的改良情况进行了分析讨论。 相似文献
947.
High-resolution solution NMR experiments are extremely useful to characterize the location and the dynamics of hydrating water molecules at atomic resolution. However, these methods are severely limited by undesired incoherent transfer pathways such as those arising from exchange-relayed intra-molecular cross-relaxation. Here, we review several complementary exchange network editing methods that can be used in conjunction with other types of NMR hydration experiments such as magnetic relaxation dispersion and 1JNC′ measurements to circumvent these limitations. We also review several recent contributions illustrating how the original solution hydration NMR pulse sequence architecture has inspired new approaches to map other types of non-covalent interactions going well beyond the initial scope of hydration. Specifically, we will show how hydration NMR methods have evolved and have been adapted to binding site mapping, ligand screening, protein-peptide and peptide-lipid interaction profiling. 相似文献
948.
949.
多璧碳管/聚中性红修饰电极的制备及对鸟嘌呤和腺嘌呤的应用研究 总被引:1,自引:0,他引:1
结合纳米材料的电催化特性和中性红聚合物薄膜的分子识别能力, 以玻碳电极为基体制备了多壁碳管/聚中性红(MWNT/PNR)修饰电极, 并用表面扫描电镜和循环伏安法进行了表征. 实验表明, 该修饰电极对腺嘌呤(A)和鸟嘌呤(G)都表现出了良好的电催化性能. 在最佳条件下, 用示差脉冲伏安法对A和G进行了测定, 其氧化峰电流于A和G的浓度分别在0.01~4 μmol/L和0.01~8 μmol/L范围内呈良好的线性关系, 检测限均为5×10-9 mol/L (S/N=3). 该修饰电极可以用来同时测定DNA中的A和G. 相似文献
950.
M.B. Shelar P.A. Jadhav D.R. Patil B.K. Chougule Vijaya Puri 《Journal of magnetism and magnetic materials》2010,322(21):3355-3358
The cadmium substituted nickel ferrites Ni1−xCdx Fe2O4 (x=0.2, 0.4, 0.6) has been prepared by the self-propagating auto combustion method. Phase identification of the samples was studied by XRD patterns which are characteristics of cubic spinel structure ferrites. As the content of cadmium in the ferrites increases the lattice parameter. The tetrahedral and octahedral vibrations in the samples were studied by Fourier Transform Infrared (FT-IR) spectra. The SEM study reveals the fine-grained nature of ferrites with little agglomeration. The decrease in the drift mobility is found with increase in cadmium content. DC resistivity indicates the semiconducting nature of the samples. The Super Quantum Interference Device measurements were taken to study the magnetic properties of the samples. 相似文献