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131.
荧光法快速检测有机磷农药残留总量 总被引:1,自引:0,他引:1
在pH4.60的B-R缓冲溶液中,中性红(NR)与一定浓度的十二烷基苯磺酸钠(SDBS)发生荧光增强反应,在该体系中加入有机磷农药后,在激发波长560 nm,发射波长604 nm处体系的荧光强度明显降低,且降低程度与有机磷农药的加入量呈良好的线性关系,其线性范围和检出限分别为0.024~0.40 mg/L,0.014 mg/L。据此建立了测定有机磷农药残留总量的新方法。方法已用于面粉和土壤中有机磷农药残留总量的检测,回收率在92.0%~100.5%之间,RSD在1.1~1.9%之间。 相似文献
132.
133.
研究了有机发光器件(organic light emitting diodes, 简记为OLED)半透明电极上形成的反射相移对OLED光谱产生调制现象.以红色微腔结构顶发射OLED(top emitting OLED,TOLED)为例,基于微腔理论和传输矩阵理论建立物理模型,采用计算机数值模拟方法,得出结果表明器件发光光谱的调制作用不只局限于有机层厚度,也和反射相移有关.通过改变覆盖到顶电极表面的有机层厚度的简单方法,可以实现对顶电极反射相移的调节,从而改变TOLED光学性能.这一结果为进一步改善器件的性
关键词:
反射相移模拟
红色微腔
顶发射有机发光 相似文献
134.
利用气相色谱质谱(GC/MS)电子轰击方法,对6种不同年龄和不同性别的赤鳞鱼肉中的饱和、不饱和脂肪酸(经甲酯化后)进行了测定,用色谱法作了定量,共鉴定出18种脂肪酸。 相似文献
135.
能量为200keV的Ag离子,以1×1016,5×1016,1×1017 cm-2的剂量分别注入到非晶SiO2玻璃,光学吸收谱显示:注入剂量为1×1016 cm-2的样品的光吸收谱为洛伦兹曲线,与Mie理论模拟的曲线形状一致;注入剂量较大的5×1016,1×1017 cm-2的谱线共振吸收增强,峰位红移并出现伴峰. 透射电镜观察分析表明,注入剂量不同的样品中形成的纳米颗粒的大小、形状、分布都不同,注入剂量较大的还会产生明显的表面溅射效应,这些因素都会影响共振吸收的峰形、峰位和峰强. 当注入剂量达到1×1017 cm-2时,Ag纳米颗粒内部可能还形成了杂质团簇.
关键词:
离子注入
纳米颗粒
共振吸收
红移 相似文献
136.
Determination of Allura Red and Tartrazine in Food Samples by Sequential Injection Analysis Combined with Voltammetric Detection at Antimony Film Electrode
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J. A. Rodríguez M. G. Juárez C. A. Galán‐Vidal J. M. Miranda E. Barrado 《Electroanalysis》2015,27(10):2329-2334
An antimony film electrode prepared on‐line and installed as part of a sequential injection system, was used as an electrochemical detector to determine azo dyes in food samples. The influence of several flow variables were evaluated using a central composite design. In optimal conditions, the linear range of the calibration curve varied from 1–5 µM, with a limit of detection limit of 0.3 µM. The relative standard deviation of analytical repeatability was <5.0 %.The method was validated by comparing the results obtained with those provided by HPLC; no significant difference were seen. 相似文献
137.
Impedimetric Detection of DNA Damage with the Sensor Based on Silver Nanoparticles and Neutral Red
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Yury Kuzin Anna Porfireva Veronika Stepanova Vladimir Evtugyn Ivan Stoikov Gennady Evtugyn Tibor Hianik 《Electroanalysis》2015,27(12):2800-2808
Novel electrochemical DNA‐sensor based on glassy carbon electrode (GCE) modified with Ag nanoparticles, Neutral red covalently attached to its surface and native DNA adsorbed on modifier coating was developed for the estimation of DNA damage on example of model system based on Fenton reagent. As was shown, the oxidation process resulted in synchronous increase of electron transfer resistance and capacitance measured by electrochemical impedance spectroscopy (EIS). The contribution of each sensor component on the signal was specified and sensitivity estimated against similar surface coatings. The shift of EIS parameters was found to be higher than that of similar biosensors reported. The DNA sensor was tested on the estimation of antioxidant capacity of green tea infusions again the results of coulometric titration with electrogenerated bromine. 相似文献
138.
Teobald Kupka Aneta Buczek Magorzata A. Broda Roman Szostak Hong‐Ming Lin Lu‐Wei Fan Roman Wrzalik Leszek Stobiski 《Journal of Raman spectroscopy : JRS》2016,47(8):908-916
Pigments from red coral (Corallium rubrum) and African snail (Helixia aspersa) shell were studied non‐invasively using Raman spectroscopy with 1064‐nm laser beam. The two observed bands because of organic pigments confined in biomineralized CaCO3 matrix at about 1500 and 1100 cm−1 were assigned to ν(CC) and ν(C―C), respectively. Both signals originate from polyene(s) of largely unknown structure, containing several conjugated CC bonds. The small peak at 1016 cm−1 in the Raman spectrum of coral pigment was assigned to in‐plane ―CH3 rocking or structural deformation of polyene chain because of spatial confinement in the mineral matrix. The organic pigments in red coral and snail shell were present in inorganic matrix containing aragonite (shell) and calcite (coral). In addition, using Raman spectroscopy, it was observed that aragonite was replaced by calcite as result of healing damaged parts of snail shell. This is an important finding which indicates a great potential of nondestructive Raman spectroscopy instead of X‐ray technique, as a diagnostic tool in environmental studies. To support analysis of the observed Raman spectra detailed calculations using density functional theory (DFT with B3LYP and BLYP density functionals) on structure and vibrations of model all‐trans polyenes were undertaken. DFT calculated CC and C―C stretching frequencies for all‐trans polyenes containing from 2 to 14 CC units were compared with the observed ν(CC) and ν(C―C) band positions of the studied coral and shell. Individual correction factors were used to better match theoretical wavenumbers with observed band positions in red coral and African snail. It was concluded that all‐trans polyene pigments of red coral and dark parts of African snail shell contain 11–12 and 14 CC double bond units, respectively. However, Raman spectroscopy cannot produce any clear information on the presence and nature of the end‐chain substituents in the studied pigments. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
139.
Selective Probing of Gaseous Ammonia Using Red‐Emitting Carbon Dots Based on an Interfacial Response Mechanism
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Dr. Bang‐Ping Jiang Bo Zhou Prof. Dr. Xing‐Can Shen Yun‐Xiang Yu Dr. Shi‐Chen Ji Chang‐Chun Wen Prof. Dr. Hong Liang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(52):18993-18999
Solid‐state fluorescence sensing is one of the most appealing detection techniques because of its simplicity and convenience in practical operation. Herein, we report the development of a red‐emitting carbon dots (RCDs)‐based material as a solid‐state fluorescence sensor for the selective probing of gaseous ammonia. The RCDs were prepared by a low‐cost, one‐step carbonization method using sugar cane bagasse as the carbon precursor. The pristine RCDs were then directly coated on polyvinylidene fluoride membrane to produce a new fluorescence sensor capable of selectively distinguishing toxic gaseous ammonia from other analyte vapors through sensitive fluorescence quenching with a low detection limit. More importantly, the interfacial response mechanism occurring on the surface of the RCDs has been studied by X‐ray photoelectron spectroscopy, Fourier‐transform infrared spectroscopy, and Raman measurements. The results indicate that fluorescence quenching in the RCDs might result from ammonia‐induced Michael addition through insertion of N into the C?C group and deprotonation of the carboxyl group. To the best of our knowledge, this is the first report that provides clear insight into the mechanism of surface chemistry on CDs in the solid state. 相似文献
140.
采用超高效液相色谱法同时测定脐橙中的橘红2号和苏丹红染料。样品经乙腈超声提取,氨基固相萃取小柱净化后,用Waters ACQUITY UPLC BEH C18色谱柱分离,以乙腈-水为流动相进行梯度洗脱,采用二极管阵列检测器检测,检测波长分别为478 nm和515 nm。5种染料的质量浓度在0.20~20 mg·L-1范围内呈线性,检出限(3S/N)在0.31~0.53μg·kg-1之间。加标回收率在87.8%~99.4%之间,测定值的相对标准偏差(n=5)在0.54%~3.1%之间。 相似文献