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91.
May Lee Low Cheang Wei Chan Pei Ying Ng Ing Hong Ooi Mohd Jamil Maah Soi Moi Chye 《Journal of Coordination Chemistry》2017,70(2):223-241
Three ternary copper(II) complexes, [Cu(phen)(L-phe)Cl]·2H2O, [Cu(phen)(L-leu)Cl]·4½H2O, and [Cu(phen)(L-tyr)Cl]·3H2O, and four binary copper(II) complexes, [Cu(phen)Cl2], Cu(L-phe)2·½H2O, Cu(L-leu)2·½H2O, and Cu(L-tyr)2·H2O (where phen = 110-phenanthroline, L-phe = L-phenylalanine, L-tyr = L-tyrosine, L-leu = L-leucine and Cl- = chloride), were synthesized and characterized by elemental analysis, spectroscopic techniques (FTIR, UV–visible, fluorescence spectroscopy), magnetic susceptibility, molar conductivity, and lipophilicity measurement. X-ray diffraction determination of a single crystal of [Cu(phen)(L-tyr)Cl] showed two independent molecules in the asymmetric unit, each with the same distorted square pyramidal geometry about copper(II). p-Nitrosodimethylaniline assay revealed that the three ternary complexes were better inducers of reactive oxygen species over time than binary complexes, CuCl2, and free ligands. All the copper(II) complexes in this series inhibited the three proteolytic activities in the order Trypsin-like > Caspase-like > Chymotrypsin-like. In terms of anticancer properties, the copper(II)-phen complexes had GI50 values of less than 4 μM against MCF-7, HepG2, CNE1 and A549 cancer cell lines, more potent than cisplatin. 相似文献
92.
The paper presents a nonlinear model describing vibration of the landing gear relative to the fuselage. The model is intended
to analyze the dynamic stability of nonswiveling main-gear wheels. The model is used to show that the lateral component of
the fuselage speed has a significant effect on the critical shimmy speed
__________
Translated from Prikladnaya Mekhanika, Vol. 42, No. 9, pp. 134–142, September 2006. 相似文献
93.
The orienting properties of incompressible discotic nematic liquid crystals for creeping flows between converging and diverging planar walls (Jeffrey-Hamel) are analyzed using the Leslie-Ericksen theory. The dependence of director orientation on the reactive parameter and the flow kinematics is presented. Closed form stationary solutions for the director orientation are found when elastic effects are neglected. Stationary numerical solutions for the velocity and director fields using the full Leslie-Ericksen theory are presented. The director field in converging flow is characterized by azimuthal (radial) centerline orientation, by being asymmetric with respect to the azimuthal (radial) direction, and by having an allowed orientation range that spans two half-quadrants (full quadrants). In the limiting case of perfectly flat disk ( –) the flow-induced director orientation in converging flow is the azimuthal direction, while in diverging flow the director rotates by a full n radians. By reducing the vertex angle between the walls to vanishingly small values, converging flow solutions properly reduce to those of flow between parallel plates, but diverging flows are expected to lead to a new instability. 相似文献
94.
Reactive adsorption of thiophene on Ni/ZnO adsorbent:Effect of ZnO textural structure on the desulfurization activity 总被引:2,自引:0,他引:2
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To better understand the nature of reactive adsorption of thiophene on Ni/ZnO adsorbent, the effect of ZnO textural structure on the desulfurization activity was investigated. ZnO materials were synthesized by low-temperature solid-state reaction and the corresponding Ni/ZnO adsorbents were prepared by incipient impregnation method. The analysis results showed that the crystalline sizes of ZnO as-synthesized as well as the BET surface areas varied obviously with the calcination temperature. The activity evaluations indicated that the Ni/ZnO adsorbents prepared with ZnO possessed a favorable textural structure as active component exhibited good activity of removing thiophene. The evolutions of the main crystalline phases of Ni/ZnO adsorbents before and after reaction confirmed that ZnO played a crucial role in taking up S element and converting it into ZnS in the reactive adsorption process. It was concluded that ZnO with larger surface area and smaller crystal particles resulted in better desulfurization activity, which may be the main reason for the different activities of the Ni/ZnO adsorbents prepared with ZnO calcined at different temperatures. 相似文献
95.
Helmut Beckers Dr. Xiaoqing Zeng Dr. Helge Willner Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(5):1506-1520
Pure sym‐N2O4 isolated in solid Ne was obtained by passing cold neon gas over solid N2O4 at ?115 °C and quenching the resulting gaseous mixture at 6.3 K. Filtered UV irradiation (260–400 nm) converts sym‐N2O4 into trans‐ONONO2, a weakly interacting (NO2)2 radical pair, and traces of the cis‐N2O2?O2 complex. Besides the weakly bound ON?O2 complex, cis‐N2O2?O2 was also obtained by co‐deposition of NO and O2 in solid Ne at 6.3 K, and both complexes were characterised by their matrix IR spectra. Concomitantly formed cis‐N2O2 dissociated on exposure to filtered IR irradiation (400–8000 cm?1), and the cis‐N2O2?O2 complex rearranged to sym‐N2O4 and trans‐ONONO2. Experiments using 18O2 in place of 16O2 revealed a non‐concerted conversion of cis‐N2O2?O2 into these species, and gave access to four selectively di‐18O‐substituted trans‐ONONO2 isotopomers. No isotopic scrambling occurred. The IR spectra of sym‐N2O4 and of trans‐ONONO2 in solid Ne were recorded. IR fundamentals of trans‐ONONO2 were assigned based on experimental 16/18O isotopic shifts and guided by DFT calculations. Previously reported contradictory measurements on cis‐ and trans‐ONONO2 are discussed. Dinitroso peroxide, ONOONO, a proposed intermediate in the IR photoinduced rearrangement of cis‐N2O2?O2 to the various N2O4 species, was not detected. Its absence in the photolysis products indicates a low barrier (≤10 kJ mol?1) for its exothermic O? O bond homolysis into a (NO2)2 radical pair. 相似文献
96.
97.
Reactive nitrogen oxygen species(RNOS) implicate damage in biological systems,especially leading to inflammation,neurodegenerative and cardiovascular diseases,and cancer by altering the functions of biomolecules through the N-nitrosation and N-nitration reactions.The mechanisms of N-nitrosation and N-nitration reactions of ammonia and dimethylamine by RNOS,i.e.,N2O3,N2O4,N2O5 and ONOOH,were investigated at the CBS-QB3 level of theory.The computational results indicate that the N-nitrosation reaction prefers a concerted mechanism,in which a H-abstraction and ON-addition occur simultaneously,whereas a stepwise mechanism(also called a free radical mechanism) is more favorable for most nitrating agents in the N-nitration reaction,where NO2 first abstracts a hydrogen atom from the nitrogen of amines and then the induced intermediate reacts with NO2 once more to form the nitration products.However,the concerted pathway is still a feasible process for some nitrating agents such as N2O5.In addition,the relationship between the structures of different RNOS and their nitrosating or nitrating abilities was also investigated. 相似文献
98.
Effect of substrate temperature on microstructure and optical properties of single-phased Ag20 film deposited by using radio-frequency reactive magnetron sputtering method
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Using a radio-frequency reactive magnetron sputtering technique, a series of the single-phased Ag20 films are deposited in a mixture of oxygen and argon gas with a flow ratio of 2:3 by changing substrate temperature (Ts). Effects of the Ts on the microstructure and optical properties of the films are investigated by using X-ray diffractometry, scanning electron microscopy and spectrophotometry. The single-phased Ag20 films deposited at values of Ts below 200℃ are (111) preferentially oriented, which may be due to the smallest free energy of the (111) crystalline face. The film crystallization becomes poor as the value of Ts increases from 100℃ to 225℃. In particular, the Ag20 film deposited at Ts=225℃ loses the (111) preferential orientation. Correspondingly, the film surface morphology obviously evolves from a uniform and compact surface structure to a loose and gullied surface structure. With the increase of Ts value, the transmissivity and the reflectivity of the films in the transparent region are gradually reduced, while the absorptivity gradually increases, which may be attributed to an evolution of the crystalline structure and the surface morphology of the films. 相似文献
99.
Vibration control of the finite L-shaped beam structures based on the active and reactive power flow
LIU ChunChuan LI FengMing TANG Liang & HUANG WenHu P.O.Box School of Astronautics Harbin Institute of Technology Harbin China P.O.Box National Laboratory of Space Intelligent Control Beijing Institute of Control Engineering Beijing 《中国科学:物理学 力学 天文学(英文版)》2011,(2)
This paper analyzes the physical meaning of the active and reactive power flow in the finite L-shaped beams and studies the active vibration control of the structures based on the active and reactive power flow.The traveling wave approach is used to calculate the structural dynamic responses.Because the error of control force is inevitable in practical applications,the effects of the error of control force on the control results are studied.The study indicates that the error of control force has pronounced ... 相似文献
100.