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41.
T. Rietmann S. Sohn M. Schröder D. Lipinsky H.F. Arlinghaus 《Applied Surface Science》2006,252(19):6640-6643
In order to improve quantification of high mass ions, the influence of cluster composition on detection efficiencies has been studied using a TOF-SIMS IV with the extended capability of postaccelerating ions up to 20 keV. In this experimental study, we focus on the comparison of detection efficiencies for three types of negatively charged secondary cluster ions: gold-alkanethiolate-clusters (AuxMy), gold-sulfur-clusters (AuxSy) and gold-clusters (Aux). The clusters were sputtered from self-assembled monolayers of hexadecanethiols on gold substrates using 10 keV Ar+ primary ions. The detection efficiencies were derived on the basis of a function for the secondary electron yield and a fourth-order approximated Poisson probability distribution for electron propagation and amplification within the microchannel plate.In addition to the well-known dependence of detection efficiencies on ion mass and energy, which has already been studied for positively charged ions, we were able to show a similar behaviour for the investigated negatively charged secondary ions. We have observed major variations among the three types of clusters at similar mass and energy as predicted in a theoretical approach. The observed differences are due to the different composition of the investigated clusters which has a major influence on the kinetic ion induced electron emission within the microchannel plate. For the first time it was possible to experimentally verify these predictions for detection efficiencies. 相似文献
42.
Satya Prakash 《Pramana》1989,33(1):109-131
This article summarizes the recent radiochemical investigations on mass, charge kinetic energy and fragment angular distributions
in low energy fission of actinides. 相似文献
43.
In this note we study constant mean curvature surfaces in asymptotically flat 3-manifolds. We prove that, outside a given compact subset in an asymptotically flat 3-manifold with positive mass, stable spheres of given constant mean curvature are unique. Therefore we are able to conclude that the foliation of stable spheres of constant mean curvature in an asymptotically flat 3-manifold with positive mass outside a given compact subset is unique.
44.
45.
Based on the Dyson-Schwinger equations of QCD in the "rainbow" approximation, the fully dressed quarkpropagator Sf(p) is investigated, and then an algebraic parametrization form of the propagator is obtained as a solutionof the equations. The dressed quark amplitudes Af and Bf built up the fully dressed quark propagator and the dynamicalrunning masses Mf defined by Af and Bf for light quarks u, d and s are calculated, respectively. Using the predictedrunning masses Mf, quark condensates <0|q(0)q(0)|0> = -(0.255 GeV)a for u, d quarks, and <0|s s|0> = 0.8<0|q(0)q(0)]0)for s quark, and experimental pion decay constant fπ = 0.093 GeV, the masses of Goldstone bosons K, π, and η are alsoevaluated. The numerical results show that the masses of quarks are dependent on their momentum p2. The fully dressedquark amplitudes Af and Bf have correct behaviors which can be used for many purposes in our future researches onnonperturbative QCD. 相似文献
46.
文章介绍2001年度国家自然科学奖二等奖获奖成果,在北京正负电子对撞机上采集了Ψ(2S)粒子大数据样本,开展了粲偶素物理的广泛研究:完成了6个粲偶素涉及质量,宽度和衰变化支比等大批重要参数的首次测量或高精度测量;通过对Ψ(2S)和J/Ψ强衰变性质的比较研究,观察到一系列反常现象,挑战现有理论图像。该项研究成果对量子色动力学的检验与发展具有重要意义,为我国粲偶素物理实验研究的继续发展并保持先进水平奠定坚实基础。 相似文献
47.
M. Esmaeelpour 《Applied Surface Science》2006,252(18):6353-6359
This research investigates the effect of ion implantation dosage level and further thermal treatment on the physical characteristics of chromium coatings on Si(1 1 1) substrates. Chromium films had been exposed to nitrogen ion fluencies of 1 × 1017, 3 × 1017, 6 × 1017 and 10 × 1017 N+ cm−2 with a 15 keV energy level. Obtained samples had been heat treated at 450 °C at a pressure of 2 × 10−2 Torr in an argon atmosphere for 30 h. Atomic force microscopy (AFM) images showed significant increase in surface roughness as a result of nitrogen ion fluence increase. Secondary ion mass spectroscopy (SIMS) studies revealed a clear increased accumulation of Cr2N phase near the surface as a result of higher N+ fluence. XRD patterns showed preferred growth of [0 0 2] and [1 1 1] planes of Cr2N phase as a result of higher ion implantation fluence. These results had been explained based on the nucleation-growth of Cr2N phase and nitrogen atoms diffusion history during the thermal treatment process. 相似文献
48.
Technical cellulose-2.5-acetates (CA 2.5) were characterized regarding their carbohydrate composition in comparison to the raw material. The association of the CA 2.5 samples in acetone was studied by size exclusion chromatography (SEC) using various acetone grades and styrene divinylbenzene copolymer columns. In HPLC grade acetone with and without addition of 1% water up to three different pre-humps eluted in front of the main fraction of the polymer. The evaluation of the main peak by light scattering measurements resulted in high molar masses indicating that for these technical CA 2.5 samples even the main fraction is not dissolved without association. No pre-humps or association phenomena were observed after addition of 1 ppm LiBr to HPLC grade acetone or with p.a. grade acetone. In addition pre-hump enriched and pre-hump free fractions were isolated by fractionated precipitation. The carbohydrate composition of these fractions was determined and correlated with their association pattern in SEC investigations. 相似文献
49.
This paper examines the capabilities of cryogenic sample handling to examine composition and structure of hydrogel materials where siloxane components are central to the analysis. XPS analysis of multicomponent polymers with cryogenic sample handling following exposure to aqueous environments has revealed the composition and kinetics of near surface reorganization for siloxane and fluorocarbon containing polymers. In this study we report results from a ToF-SIMS protocol for cryogenic sample handling applied to the analysis of surface changes upon hydration/dehydration of hydrogel polymers. Comparison of results from angle dependent XPS and ToF-SIMS are discussed for a range of commercial soft contact lens materials. Both methods detected changes in surface chemistry between the hydrated (frozen) and dehydrated surfaces. Analysis of the hydrated surfaces detected polymer components indicative of the commercial formulation as well as ice clusters. Analysis of the dehydrated materials detected changes in surface chemistry relative to the hydrated surface in addition to loss of water due to sample dehydration. A quantitative standard additions method for ToF-SIMS data was used to determine submonolayer amounts of PDMS impurities at the surface of the hydrogels. ToF-SIMS analysis of a series of seven poly (allyl methacrylate-g-dimethylsiloxane), AMA-g-DMS, graft copolymers in the hydrated state revealed high mass oligomeric ion distributions for systems with bulk PDMS content greater than 25 wt.%. This marks the first time that detection of high mass oligomeric ion distributions from hydrated (frozen) surfaces has been reported. Analysis of the dehydrated surface detected formation of high mass oligomeric ion distributions for systems with PDMS bulk content greater than 15 wt.%, but only detected these ion distributions in wet (frozen) samples when the bulk concentration was greater than 25 wt.%. 相似文献
50.
Yamada Kaoru Matsutani Shigeaki Uchiyama Akira Takahashi Toshio 《Journal of inclusion phenomena and macrocyclic chemistry》1991,11(1):49-54
Analyses of crown ether complexes of alkali metal ions and characterization of the complexes formed inm-nitrobenzyl alcohol have been carried out by fast atom bombardment (FAB) mass spectrometry. By using m-nitrobenzyl alcohol as a matrix for measurements, the stoichiometry of the complexes was assessed on the basis of the observed FAB peaks. In addition, the formation of crown ether-alkali metal complexes at a 2 : 1 molar ratio was enhanced by increasing the ionic radius of the metal ion in agreement with previous observations. On these grounds, FAB mass spectrometry may provide a rapid means for investigation of the complexation behavior of crown ethers and the stoichiometry of the complexes. 相似文献