全文获取类型
收费全文 | 7948篇 |
免费 | 265篇 |
国内免费 | 682篇 |
专业分类
化学 | 7744篇 |
晶体学 | 74篇 |
力学 | 79篇 |
综合类 | 25篇 |
数学 | 566篇 |
物理学 | 407篇 |
出版年
2024年 | 12篇 |
2023年 | 64篇 |
2022年 | 193篇 |
2021年 | 180篇 |
2020年 | 177篇 |
2019年 | 180篇 |
2018年 | 169篇 |
2017年 | 204篇 |
2016年 | 194篇 |
2015年 | 162篇 |
2014年 | 230篇 |
2013年 | 706篇 |
2012年 | 304篇 |
2011年 | 281篇 |
2010年 | 218篇 |
2009年 | 296篇 |
2008年 | 341篇 |
2007年 | 359篇 |
2006年 | 296篇 |
2005年 | 307篇 |
2004年 | 313篇 |
2003年 | 304篇 |
2002年 | 1778篇 |
2001年 | 238篇 |
2000年 | 157篇 |
1999年 | 132篇 |
1998年 | 109篇 |
1997年 | 113篇 |
1996年 | 108篇 |
1995年 | 122篇 |
1994年 | 87篇 |
1993年 | 88篇 |
1992年 | 84篇 |
1991年 | 52篇 |
1990年 | 31篇 |
1989年 | 24篇 |
1988年 | 37篇 |
1987年 | 32篇 |
1986年 | 18篇 |
1985年 | 22篇 |
1984年 | 29篇 |
1983年 | 7篇 |
1982年 | 21篇 |
1981年 | 15篇 |
1980年 | 15篇 |
1979年 | 10篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1971年 | 32篇 |
1970年 | 16篇 |
排序方式: 共有8895条查询结果,搜索用时 0 毫秒
61.
Zur Synthese von fungizid wirksamen Isocamphanderivaten: Synthesen in der Isocamphanreihe, 34. Mitt.
Gerhard Buchbauer Helmut Spreitzer Margarete Kneidinger 《Monatshefte für Chemie / Chemical Monthly》1990,121(6-7):549-554
Summary Some esters of isocamphenilanic acid (4) have been prepared and tested for their fungicidal and insecticidal activity. Esters of various acids with isocamphanyl ethylalcohol (5) have also been synthesized and included in the fungicidal/acaricidal/insecticidal screening programme. All esters bear a geminal dimethyl group at C-3 of the bicyclus which is important because of its shielding effect. 相似文献
62.
E. A. Dikusar N. G. Kozlov V. I. Potkin T. D. Zvereva A. P. Yuvchenko M. P. Bei N. V. Kovganko 《Chemistry of Natural Compounds》2006,42(5):539-542
Previously unreported esters 1b–20b were synthesized from natural terpene alcohols, sterols, plant phenols, and camphar oxime (1a–20a) by reaction with o-carborane-C-carboxylic acid chloride.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 434–436, September–October, 2006. 相似文献
63.
Dominik Rejman 《Tetrahedron》2007,63(5):1243-1253
The work deals with the synthesis of hydroxypyrrolidine analogs of nucleosides. Starting from the optically pure l- or d-tartaric acid, we improved the synthesis of enantiomeric trans-3,4-dihydroxypyrrolidines and elaborated a procedure for the synthesis of all possible diastereoisomers of 3-hydroxy-4-pyrrolidinyl derivatives of both purine and pyrimidine nucleobases. The prepared compounds were tested for cytostatic and antiviral properties but no significant activity was found. 相似文献
64.
65.
S. A. Shevelev V. M. Vinogradov I. L. Dalinger T. I. Cherkasova 《Russian Chemical Bulletin》1993,42(11):1857-1861
A method for the synthesis of bi-, ter-, and quaterpyrazoles by cyclization ofC-(diformylmethyl)nitropyrazoles with hydrazine has been elaborated. Some of theirC- andN-derivatives have been obtained. The compounds prepared have been characterized by1H,13C,14N, and15N NMR spectra.For communication 6, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1941–1945, November, 1993. 相似文献
66.
Three different membranes, based on poly(dimethylsiloxane) (PDMS), cation-exchange material and poly(vinyl alcohol) (PVA) respectively, were tudied for the separation of pyridine-water mixtures by pervaporation. The PDMS membrane was preferentially permeable to pyridine and the other two were selective towards water. Three membranes showed different permeation performance, allowing the application of the technique to the separation of feeds of different composition. The temperature profile of the permeability suggests that it is possible to carry out the operation at an elevated temperature in order to achieve high productivity. A combination of the three types of membranes was designed for the production of anhydrous pyridine from dilute pyridine aqueous solution by pervaporation. 相似文献
67.
Pt(II) and Pd(II) dichloride complexes with 5,7-ditertbutyl-1,2,4-triazolo[1,5-a]pyrimidine (dbtp) have been synthesized and characterized by infrared and 1H, 13C NMR, 13C CPMAS spectroscopy. The structures of the cis-PtCl2(dbtp)2 · EtOH (1) and cis-PdCl2(dbtp)(dmso) (2) has been determined by signal-crystal X-ray diffraction. In both complexes the X-ray crystal structures shows that heterocycle ligand (dbtp) binds the central atom monodentate via nitrogen atom N(3). In addition, compound (2) is interesting for its structural features, because it is the first report of mixed dichloride Pd(II) complexes with N-donor (triazolopyrimidine) and S-donor (dimethylsulfoxide) ligands. In this structure the Pd–Cl distances are: 2.302(1) and 2.281(1) Å, Pd–N 2.041(3) Å and Pd–S 2.245(1) Å. The 1H, 13C NMR studies show clearly that these structures are retained in solution. 相似文献
68.
R.-L. Yun Y.-M. Chang C.-H. Lin K.-H. Hu C.-M. Shu 《Journal of Thermal Analysis and Calorimetry》2006,85(1):107-113
In industrial processes, information
on the safety property of chemicals is essentially crucial for safe handling
during unit operations. Ensuring the safe use of combustible or flammable
substances in processes is unlikely without detailed investigations of their
flammability characteristics and related hazards. We studied 3-methyl pyridine
(3-picoline), e.g., flammability limits (LFL/UFL), maximum explosion pressure
(P
max), maximum
explosion pressure rise (dP/dt)max, minimum oxygen concentration
(MOC), vapor deflagration index (K
g),
and characterized the influence of inert steam (H2O)
on critical parameters for 3-picoline/water mixtures at 270°C, 1 atm,
various oxygen concentrations, and vapor mixing ratios (100/0, 30/70, 10/90
and 5/95 vol.%) with a 20-L-Apparatus in simulated conditions, respectively.
The results showed that the flammability characteristics
of 3-picoline(aq) all increased with the oxygen concentration.
However, as the composition of inert steam increased, the flammability parameters
and the degree of fire and explosion hazards were significantly reduced, instead.
This study elucidated the flammability properties of 3-picoline mixed with
inert steam. The conclusions could be applied to proactively prevent the relevant
processes from incurring fire and explosion accidents. 相似文献
69.
《Tetrahedron letters》2004,45(30):5799-5801
(+)-β-Hydroxymethylenecamphor 1 and enamines 2a-e were transformed into chiral camphor-based pyridine derivatives 3a-e via a tandem condensation reaction in good yields. 相似文献
70.
Starting from the natural neo-clerodane diterpenoid teubotrin (1) several neo-clerodane derivatives (3-7,9-11) have been obtained. The naturally occurring diterpenoid teuscordinon (12) has also been synthesized from teubotrin (1), showing thereby how some of these transformations can be useful for the synthesis of other natural neo-clerodane diterpenes. The latter are of interest due to their activity as insect antifeedants and other important biological properties. 相似文献