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41.
用3, 5-二硝基苯甲酸对仲丁胺进行柱前衍生, 将其衍生物在CHIRALCEL OD-H手性固定相上拆分, 并通过二极管阵列紫外检测器对其衍生物进行检测, 建立了一种拆分仲丁胺消旋体、测定仲丁胺光学纯度的新方法. 以正己烷和乙醇或异丙醇为流动相, 在CHIRALCEL OD-H手性固定相上对仲丁胺衍生物进行了拆分, 并考察了流动相组成和柱温对该对映体衍生物分离的影响, 获得较好的分析条件, 分离因子大于1.2. 非手性试剂柱前衍生化法测定仲丁胺光学纯度与旋光度方法比较, 结果一致. 方法可用于仲丁胺对映体的质量控制. 相似文献
42.
In this paper, we consider the entanglement dynamics of a four-qubit model [2006 Phys. Rev. A 74 042328] where two entangled qubits a and b locally interact with separate qubits A and B via the spin-exchange-like Hamiltonian. We study the effect of purity of initial entangled state of qubits a, b on the entanglement evolution and its relation with energy transfer. Also, we find that the total bipartite entanglement of qubits a, b plus A, B is not a constant any longer when the initial entangled state of a, b is not pure, which is a complement to the result in the paper [2007 J. Phys. B 40 S45] for the pure case. 相似文献
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We study time dependence of various measures of entanglement (covariance entanglement coefficient, purity entanglement coefficient, normalized distance coefficient, entropy coefficients) between resonantly coupled modes of the electromagnetic field in ideal cavities with oscillating boundaries. Two types of cavities are considered — a three-dimensional cavity possessing eigenfrequencies 3 = 31, whose wall oscillates at the frequency w = 21, and a one-dimensional (Fabry–Perot) cavity with an equidistant spectrum n = n1 where the distance between perfect mirrors oscillates at the frequencies 1 and 21. The behavior of entanglement measures in these cases turns out to be completely different, although all three coefficients demonstrate qualitatively similar time dependences in each case (except some specific situations where the covariance entanglement coefficient based on traces of covariance submatrices seems to be essentially more sensitive to entanglement than other measures, which are based on determinants of covariance submatrices). Different initial states of the field, namely, vacuum, squeezed vacuum, thermal, Fock, and even/odd coherent states, are considered. 相似文献
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46.
Wilhelm Blödorn Robert Krismer Hugo M. Ortner Jens Stummeyer Peter Wilhartitz Gerold Wünsch 《Mikrochimica acta》1989,99(3-6):423-432
Trace metals (20 elements) in high-purity chromium, molybdenum and tungsten are collected and preconcentrated by precipitation and adsorption on cellulose collectors. The compound methods allow the application of AAS and ICP-AES as determination methods for the production control of highly pure refractory metals under routine conditions.Presented in part at the 1989 European Winter Conference on Plasma Spectrochemistry, Reutte, Austria 相似文献
47.
Luminescence efficiency of self-activated CaWO4 under 147 nm vacuum ultraviolet (VUV) radiation excitation is about 90% of that of BaMgAl10O17:Eu2+ (BAM), the commercial blue plasma display panel (PDP) phosphor. However, the color purity and the particle size of the former needs substantial modification before it can be considered for application in PDP. CaWO4:Tm exhibits Tm3+ emission peaks in the blue region due to energy transfer from WO4 to Tm3+ ions but the overall emission intensity under 147 nm excitation is reduced when compared to that of CaWO4. 相似文献
48.
介绍了测量不确定度的评定方法及其在基准试剂纯度、干涉滤光片波长标准物质、锌合金成分标准物质中的应用实例。 相似文献
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A review of recent trends in the dispersion, purification, and assembly of colloidal nanoparticles highlights a number of growing analogies with ideas borrowed from polymer science. Beyond the similar scales of size, several key concepts lying at the foundation of polymer physics—such as polydispersity, fractionation, phase ordering, and viscoelasticity—are taking on new and unique significance in the contemporary realm of nanotechnology. Leveraging “soft matter” at the nanoscale to simplify materials processing and improve material performance is becoming a reality, with potentially profound implications for a number of emerging technologies. © 2013 Wiley Periodicals, Inc. J Polym Sci Part B: Polym. Phys. 2013 , 51, 1195–1208 相似文献