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571.
WANG Biao LIANG Xi-shuang LIU Feng-min ZHONG Tie-gang ZHAO Chun LU Ge-yu QUAN Bao-fu State Key Laboratory on Integrated Optoelectronics College of Electronic Science Engineering Jilin University Changchun P.R.China 《高等学校化学研究》2009,25(1)
Na superionic conductor(NASICON) nanoparticles were synthesized by a modified sol-gel method and sintered at a temperature range of 800―1000 ℃.The performance of the samples was characterized by the analysis methods of X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),and transmission electron microscopy(TEM) as well as conductivity measurement.Compared with those sintered at other temperatures,the NASICON material sintered at 900 ℃ had the best crystalline structure and higher conductivi... 相似文献
572.
573.
利用柠檬酸络合法制备了SrFe(Cu,Ti)O_(3-δ)混合导体透氧材料. 采用XRD、O_2-TPD、H_2-TPR、SEM等测试技术考察了材料的稳定性. 结果表明,SrFe_(0.7)Cu_(0.3)O_(3-δ)在低氧压下会发生相分解,产生SrCuO__2杂相,而掺杂Ti后的SrFe_(0.6)Cu_(0.3)Ti_(0.1)O_(3-δ)在低氧压下保持单一的钙钛矿结构. H_2-TPR和O_2-TPD的测试表明,Ti~(4+)的掺杂提高了材料的氧脱附起始温度和其它金属离子的还原温度. SrFe_(0.6)Cu_(0.3)Ti_(0.1)O_(3-δ)膜在透氧过程中,会有Cu~(2+)和Sr~(2+)从钙钛矿结构中析出,在原晶粒边界形成新的小晶粒,但这种轻微的组分偏析没有影响到材料的透氧量,此透氧膜在66 h的操作过程中显示了良好的稳定性. 相似文献
574.
Thin films of La2Zr2O7 (LZO) are highly regarded as possible buffer layers in the coated conductor configuration. This report describes a new synthesis for thin crystalline LZO films, based on a largely water-based solution, mainly containing metal acetates, acetic acid and an organic amine-base: triethanolamine. Initially, a thin layer of amorphous material is deposited on the textured Ni-5 at%W substrate by means of dip-coating. Only by careful control of the thermal treatment can the layer be transformed into a crystalline layer. Important parameters in this respect are the heating rate and the dwell time. The amorphous gel is analysed by HR-TGA/DTA and HR-TEM. The textured layers are analysed by XRD, pole figures, RHEED, AFM and SEM. 相似文献
575.
The formation of perovskite nanopowders of the common proton-conducting, electrolyte material Ba(Zr1−xYx)O3−δ is demonstrated by room temperature mechanosynthesis for the compositional range x=0, 0.058 and 0.148. This is achieved with a planetary ball mill at 650 rpm in zirconia vials, starting from BaO2 with ZrO2, (ZrO2)0.97(Y2O3)0.03 or (ZrO2)0.92(Y2O3)0.08 precursors, respectively. Powder X-ray diffraction (XRD) reveals the formation of the perovskite phase in the early stages of milling with phase purity being achieved after milling times of 240 min for composition x=0.058 whereas 420 min is necessary for composition x=0.148. In contrast, traces of ZrO2 are apparent in composition x=0 even after milling times of 420 min. The use of BaCO3 as precursor does not allow the formation of the perovskite phase for any composition. The perovskite crystallites are spherical in shape with an average size determined from XRD of ca. 30 nm in agreement with transmission electron microscopy observations. FTIR spectra demonstrate that contamination levels of BaCO3 in the mechanosynthesized powders are very low. The spherical shape and nanoscale of the crystallites allow densification levels that are highly competitive when compared to BaZrO3-based materials formed by alternative synthesis techniques documented in the literature. 相似文献
576.
BICUVOX.10(Bi2V0.9Cu0.1O5.35)粉体和膜片采用固态反应法(SSR)和EDTA-柠檬酸联合络合法(EC)制备,并使用X射线衍射、扫描电镜、氧气渗透测试和电化学阻抗谱方法对材料的件能进行了对比表征和测试.XRD和SEM结果表明,采用EC法更容易制备纯相的BICUVOX.10粉体,但是膜片的稳定性较SSR法制备的差.在不引起电压波动的前提下,采用SSR方法和EC方法制备的膜片上能加载的最大电流分别为1.6和1.2A/cm2,对应的400℃条件下透氧量分别为4.5和3.9ml/(min cm2).膜片的微结构如粒径等对透氧性能和电导性能影响很大. 相似文献
577.
Shijing Zhan Xuefeng Zhu Baofeng Ji Weiping Wang Xiaoliang Zhang Jibo Wang Weishen Yang Liwu Lin 《Journal of membrane science》2009,340(1-2):241-248
Asymmetrical thin membranes of SrCe0.95Y0.05O3−δ (SCY) were prepared by a conventional and cost-effective dry pressing method. The substrate consisted of SCY, NiO and soluble starch (SS), and the top layer was the SCY. NiO was used as a pore former and soluble starch was used to control the shrinkage of the substrate to match that of the top layer. Crack-free asymmetrical thin membranes with thicknesses of about 50 μm and grain sizes of 5–10 μm were successfully pressed on to the substrates. Hydrogen permeation fluxes (JH2) of these thin membranes were measured under different operating conditions. At 950 °C, JH2 of the 50 μm SCY asymmetrical membrane towards a mixture of 80% H2/He was as high as 7.6 × 10−8 mol/cm2 s, which was about 7 times higher than that of the symmetrical membranes with a thickness of about 620 μm. The hydrogen permeation properties of SCY asymmetrical membranes were investigated and activation energies for hydrogen permeation fluxes were calculated. The slope of the relationship between the hydrogen permeation fluxes and the thickness of the membranes was −0.72, indicating that permeation in SCY asymmetric membranes was controlled by both bulk diffusion and surface reaction in the range investigated. 相似文献
578.
579.
对于一种Bi-2223的复合导体,利用ANSYS软件,我们分析了在直流磁场下励磁过程中,自场损耗对复合导体热稳定性的影响;然后假定Bi-2223超导带内不同的损耗值,通过计算,确定了达到超导带分流温度的最小损耗值。 相似文献
580.
简述了高温超导体的特点,系统介绍了第二代高温超导体的研究状况、制备工艺,并分析了第二代高温超导体在核聚变领域的应用前景。 相似文献