DNA Interaction,DNA Photocleavage,Photocytotoxicity In Vitro,and Molecular Docking of Naphthyl-Appended Ruthenium Complexes

With the development of metal-based drugs, Ru(II) compounds present potential applications of PDT (photodynamic therapy) and anticancer reagents. We herein synthesized two naphthyl-appended ruthenium complexes by the combination of the ligand with naphthyl and bipyridyl. The DNA affinities, photocleavage abilities, and photocytotoxicity were studied by various spectral methods, viscosity measurement, theoretical computation method, gel electrophoresis, and MTT method. Two complexes exhibited strong interaction with calf thymus DNA by intercalation. Production of singlet oxygen (¹O₂) led to obvious DNA photocleavage activities of two complexes under 365 nm light. Furthermore, two complexes displayed obvious photocytotoxicity and low dark cytotoxicity towards Hela, A549, and A375 cells.     

Exploring the Origin of Maximum Entropy States Relevant to Resonant Modes in Modern Chladni Plates

The resonant modes generated from the modern Chladni experiment are systematically confirmed to intimately correspond to the maximum entropy states obtained from the inhomogeneous Helmholtz equation for the square and equilateral triangle plates. To investigate the origin of maximum entropy states, the inhomogeneous Helmholtz equation is modified to consider the point interaction coming from the driving oscillator. The coupling strength associated with the point interaction is characterized by a dimensionless factor α. The δ potential of the point interaction is numerically modelled by a truncated basis with an upper index N. The asymptotic behavior for the upper index N is thoroughly explored to verify that the coupling strength of α = 1.0 can make the theoretical resonant modes agree excellently with the maximum entropy states as N→∞. It is further authenticated that nearly the same resonant modes can be obtained by using a larger coupling strength α when a smaller upper index N is exploited in the calculation.     

Dynamics of Self-Organized and Self-Assembled Structures,by Rashmi C. Desai and Raymond Kapral

The arrival of the first hard X-ray free electron laser facilities promises new advances in structural dynamics and nanoscale imaging that will have impact across the sciences. This introductory review is intended to cover the basic physics behind this potential and illustrate the current state-of-the-art by discussing a number of recent findings from the LCLS facility at the Stanford Linear Accelerator Centre (SLAC). We concentrate on the new science using these light sources rather than the new light source technology itself, although a brief introduction to the operation of LCLS is given. Emphasis is placed upon the new regime of high intensity X-ray matter interaction physics with ultrashort X-ray pulses. We discuss how the unique combination of X-ray parameters will open new opportunities for time resolved structural studies and how the high brightness enables a new class of coherent diffraction X-ray imaging. The potential importance of this new imaging method in the study of nanostructures and biological systems at the sub-cellular and molecular level will be outlined.     

Dissipative particle dynamics simulation for the effect of interaction on the self-assembly behaviours of heterogemini surfactant in aqueous solution

Self-assembly behaviours of heterogemini surfactant in aqueous solution have been explored by means of dissipative particle dynamics simulation. Five kinds of heterogemini molecules are involved and a variety of novel morphologies have been obtained. Results based on detailed analyses show that head–tail and tail–water interactions play different roles in the formation of six kinds of self-assembly morphologies. The key factors are tail–water and head–tail repulsions separately for morphology with small (sphere) and relatively large scales (rod, planar grid, lamella and tunnels). Besides, the appearance of network in only one system can be regarded as a particular type of intermediate state. Coexistence of several sphere micelles in an amplified dissipative particle dynamics system gives us a better understanding of interactions inside the soft matter. Our simulation results can provide a theoretical guide to further research towards self-assembly behaviours of heterogemini surfactants and practical applications of these matters.     

Quadrupolar matter-wave soliton in two-dimensional free space

We study two-dimensional (2D) matter-wave solitons in the mean-field models formed by electric quadrupole particles with long-range quadrupole–quadrupole interaction (QQI) in 2D free space. The existence of 2D matter-wave solitons in the free space was predicted using the 2D Gross–Pitaevskii Equation (GPE). We find that the QQI solitons have a higher mass (smaller size and higher intensity) and stronger anisotropy than the dipole–dipole interaction (DDI) solitons under the same environmental parameters. Anisotropic soliton–soliton interaction between two identical QQI solitons in 2D free space is studied. Moreover, stable anisotropic dipole solitons are observed, to our knowledge, for the first time in 2D free space under anisotropic nonlocal cubic nonlinearity.     

Long—Range Effects on the Pyroelectric Coefficient of Ferroelectric Superlattice

Long-range effects on the pyroelectric coefficient of a ferroelectric superlattice consisting of two different ferroelectric materials are investigated based on the transverse Ising model.The effects of the interfacial coupling and the thickness of one period on the pyroelectric coefficient of the ferroelectric superlattics are studied by taking into account the long-range interaction.It is found that with the increase of the strength of the long-range interaction,the pyroelectric coefficient decreases when the temperature is lower than the phase transition temperature;the mumber of the pyroelectric peaks decreases gradually and the phase transition temperature increases,It is also found that with the decrease of the interfacial coupling and the thickness of one period.the phase transition temperature and the number of the pyroelectric peaks decrease.     

Pfaffian Solutions and Resonant Interaction Properties of a Coupled BKP Lattice

In this paper, we give a coupled lattice equation with the help of Hirota operators, which comes from a special BKP lattice. Two-soliton and three-soliton solutions to the coupled system are constructed. Furthermore,resonant interaction of the two-soliton solution is analyzed in detail. Under some special resonant condition, it is shown that low soliton can propagate faster than high one. Finally, the N-soliton solution is presented in the Pfaffian form.     

Chirality Quantum Phase Transition in Noncommutative Dirac Oscillator

The charged Dirac oscillator on a noncommutative plane coupling to a uniform perpendicular magnetic field is studied in this paper. We map the noncommutative plane to a commutative one by means of Bopp shift and study this problem on the commutative plane. We find that this model can be mapped onto a quantum optics model which contains Anti-Jaynes-Cummings (AJC) or Jaynes-Cummings (JC) interactions when a dimensionless parameter ζ (which is the function of the intensity of the magnetic field) takes values in different regimes. Furthermore, this model behaves as experiencing a chirality quantum phase transition when the dimensionless parameter ζ approaches the critical point. Several evidences of the chirality quantum phase transition are presented. We also study the non-relativistic limit of this model and find that a similar chirality quantum phase transition takes place in its non-relativistic limit.     

Ground-State Properties ,of C, O, and Ne Isotopes in Hartree——Fock-Bogoliubov Calculation with Gogny Interaction

Ground-state properties of C, O, and Ne isotopes are described in the framework of Hartree-Fock-Bogoliubov theory with density-dependent finite-range Gogny interaction D1S. We include all the contributions to the Hartree-Fock and pairing feld arising from Gogny and Coulomb interaction as well as the center of mass correction in the numerical calcu/ations. These ground-state properties of C, O, and Ne isotopes are compared with available experimental results, Hartree-Fock plus BCS, shell model and relativistic Hartree--Bogoliubov calculations. The agreement between experiments and our theoretical results is pretty well. The predicted drip-line is dependent strongly on the model and effective interaction due to their sensitivity to various theoretical details. The calculations predict no evidence for halo structure predicted for C,O, and Ne isotopes in a previous RHB study.     

A Renormalization Group Study of the Ising Model on a Triangular Lattice with Long-Range Interactions

The critical exponents of the triangular lattice Ising model with long-range interactions γ^-s are calculated by the real space renormalization group. Using the simplest Kadanoff blocks and the lowest approximation of cumulant expansion, it is shown that there exists a finite critical temperature when 4(1 - ㏑2/㏑3) < s < 4.