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81.
Arakawa R Shimomae Y Morikawa H Ohara K Okuno S 《Journal of mass spectrometry : JMS》2004,39(8):961-965
A low molecular mass polyester was analyzed by desorption/ionization on porous silicon (DIOS) mass spectrometry. The results were compared with those of matrix-assisted laser desorption ionization (MALDI) mass spectrometry using matrixes of alpha-cyano-4-hydroxycinnamic acid (CHCA) and 10,15,20-tetrakis(pentafluorophenyl)porphyrin (F20TPP). The CHCA matrix was not suitable for characterization of low molecular mass components of the polyester because the matrix-related ions interfered with the component ions. On the other hand, the F20TPP matrix showed no interference because no matrix-related ions appeared below m/z 822. However, the solvent selection for determining optimal conditions of sample preparation was limited, because F20TPP does not dissolve readily in any of the available organic solvents. In the DIOS spectra, the polymer ions were observed at high sensitivity without a contaminating ion. No matrix is needed for DIOS spectra of low molecular mass polyesters, facilitating sample preparation and selectivity of a precursor ion in post-source decay measurements. 相似文献
82.
An equation for a polarization curve of a hydrophobized electrode is proposed for electrosynthesis of a soluble electroactive product in an inner-kinetic mode. The equation contains the concentration of the target product (TP) in an explicit form. The shape of the curve depends on the biquadratic root of the TP concentration and the square root of the ratio between exchange currents of the side and target reactions. 相似文献
83.
Cordierite porous ceramics Z, X, and K were prepared using three mixtures of clay minerals: Z from kaolinite, talc, and aluminum
hydroxide, X from kaolinite, talc, vermiculite, and aluminum hydroxide, and K from kaolinite, talc, and magnesium oxide. Ceramics
were different in porosity, specific surface area, cordierite polymorphs, and secondary crystalline phases. Vermiculite influenced
textural architecture of calcined cordierite ceramics X and predestinated crystallization of the high-temperature hexagonal
α-cordierite with secondary minerals enstatite, spinel and corundum. Ceramics Z contained low-temperature orthorhombic β-cordierite,
enstatite, and corundum, K was diphase of β-cordierite and forsterite. Total pore area (TPA) and specific surface area (SSA)
of X, in spite of the higher porosity and the pore size distribution in the range of 300–1000 nm, were smaller in comparison
with TPA and SSA of Z. Ceramics K retained high porosity, two maxima at 300–1000 nm and 50–200 nm in the pores size distribution,
and the highest TPA and SSA compared to those observed in ceramics Z and X.
Presented at the 8th Conference on Solid State Chemistry, 6-11 July 2008, Bratislava, Slovak Republic. 相似文献
84.
Yinpo Qiao Xiaopeng Zhao 《Colloids and surfaces. A, Physicochemical and engineering aspects》2009,340(1-3):33-39
Carbonaceous materials with different hierarchical porous structures for electrorheological (ER) dispersed phase have been synthesized by carbonization of as-prepared starch/silica precurser at different temperatures. The N2 adsorption isotherms show that Cmeso-700 and Cmeso-500 particles have the BET surface areas of 1028 and 603 m2 g−1, respectively. They both have the mesoporous pores with size of about 4.6 nm and the microporous pores (1.1 and 1.5 nm, respectively). The BET surface areas and C/O atomic ratio of porous carbon materials can be increased with the carbonization temperatures. The rheological measurements indicate that the Cmeso-700 and Cmeso-500 ERF have the better ER effect resulted from their hierarchical porous structures. The shear stress of Cmeso-700 ERF is 900 Pa at 1000 s−1 under 3 kV mm−1, which is almost 4.5 times larger than that of Cmicro-350 ERF. The mesoporous carbon ERFs also show the better sedimentation stability than microporous carbon ERFs. The different ER effect of carbonaceous particles may derive from their different dielectric polarization property induced by the hierarchical porous structures. 相似文献
85.
Separation of cannabinoids on three different mixed‐mode columns containing carbon/nanodiamond/amine‐polymer superficially porous particles 下载免费PDF全文
Chuan‐Hsi Hung Janusz Zukowski David S. Jensen Andrew J. Miles Clayton Sulak Andrew E. Dadson Matthew R. Linford 《Journal of separation science》2015,38(17):2968-2974
Three mixed‐mode high‐performance liquid chromatography columns packed with superficially porous carbon/nanodiamond/amine‐polymer particles were used to separate mixtures of cannabinoids. Columns evaluated included: (i) reversed phase (C18), weak anion exchange, 4.6 × 33 mm, 3.6 μm, and 4.6 × 100 mm, 3.6 μm, (ii) reversed phase, strong anion exchange (quaternary amine), 4.6×33 mm, 3.6 μm, and (iii) hydrophilic interaction liquid chromatography, 4.6 × 150 mm, 3.6 μm. Different selectivities were achieved under various mobile phase and stationary phase conditions. Efficiencies and peak capacities were as high as 54 000 N/m and 56, respectively. The reversed phase mixed‐mode column (C18) retained tetrahydrocannabinolic acid strongly under acidic conditions and weakly under basic conditions. Tetrahydrocannabinolic acid was retained strongly on the reversed phase, strong anion exchange mixed‐mode column under basic polar organic mobile phase conditions. The hydrophilic interaction liquid chromatography column retained polar cannabinoids better than the (more) neutral ones under basic conditions. A longer reversed phase (C18) mixed‐mode column (4.6 × 100 mm) showed better resolution for analytes (and a contaminant) than a shorter column. Fast separations were achieved in less than 5 min and sometimes 2 min. A real world sample (bubble hash extract) was also analyzed by gradient elution. 相似文献
86.
单晶硅是Eg为1.1eV的间接带隙半导体材料,在可见光区不发光,不能应用于光电子领域.但是,Canham 1990年首次发现[1],适当条件下形成的多孔硅在室温下就可发出强度能与Ⅲ-Ⅴ族半导体发光二极管相媲美的可见光。 相似文献
87.
88.
HU Tao YANG Weiwei WANG Cheng BU Yali JIN Feng ZHANG Dongwen GU Min LIU Wenhui LIANG Qinghua LIU Ruiqing FENG Xiaomiao MA Yanwen 《高等学校化学研究》2021,37(2):286-292
Sodiumion batteries(SIBs)have attracted intensive attention as promising alternative to lithium-ionbatteries(LIBs)for large scale energy storage systems because of low cost of sodium,similar energy storage mechanism and the reasonable performance.However,it is still a great challenge to search and design a robust structure of anode materials with excellent cycling stability and high rate capability for SIBs.Herein,multilayer porous vanadium nitride(VN)microsheets are synthesized through a facile and scalable hydrothermal synthesis-nitrogenization strategy as an effective anode material for SIBs.The multilayer porous VN microsheets not only offer more active sites for fast Na+insertion/extraction process and short diffusion pathway,but also effectively buffer the volume change of anode due to more space in the multilayer porous structure.The large proportions of capacitive behavior imply that the Na+charge storage depends on the intercalation pseudocapacitive mechanism.The multilayer porous VN microsheets electrodes manifest excellent cycling stability and rate capability,delivering a discharge capacity of 156.1 mA·h/g at 200 mA/g after 100 cycles,and a discharge capacity of 111.9 mA·h/g at 1.0 A/g even after 2300 cycles with the Coulombic efficiency of nearly 100%. 相似文献
89.
以互通多孔碳(IPC)为载体,水热条件下在碳表面原位反应生成纳米结构的二氧化锰(MnO2),制备互通多孔碳/二氧化锰纳米(IPC/MnO2)复合电极材料. 采用扫描电镜(SEM),透射电镜(TEM),X射线衍射(XRD),热重分析(TGA)对其结构进行表征;采用循环伏安法、恒流充放电和交流阻抗对其电化学性能进行研究. 结果表明:生成的MnO2均匀地负载在碳的表面,形成多层次结构,并且随着温度的升高IPC表面负载的MnO2由纳米颗粒变为纳米片状结构;MnO2纳米片具有典型的K-Birnessite 型晶体结构;复合物中MnO2的含量约为34%(w). 在100 ℃制备的IPC/MnO2复合材料在三电极系统中最高比电容达到了411 F·g-1;随着反应温度的升高,比容量先增长后基本保持不变. 以IPC/MnO2为正极,活性炭(AC)为负极,1 mol·L-1 Na2SO4溶液为电解液组装成IPC/MnO2//AC 混合超级电容器,发现IPC/MnO2电极的电容器其电位窗口从1 V扩展到1.8 V,容量可达86F·g-1,且表现出良好的电容特性和大电流放电性能. 相似文献
90.
Covalent organic frameworks (COFs) are a class of crystalline porous organic polymers with polygonal porosity and highly ordered structures. The most prominent feature of the COFs is their excellent crystallinity and highly ordered modifiable one-dimensional pores. Since the first report of them in 2005, COFs with various structures were successfully synthesized and their applications in a wide range of fields including gas storage, pollution removal, catalysis, and optoelectronics explored. In the meantime, COFs also exhibited good performance in chemical and biological sensing, because their highly ordered modifiable pores allowed the selective adsorption of the analytes, and the interaction between the analytes and the COFs’ skeletons may lead to a detectable change in the optical or electrical properties of the COFs. In this review, we firstly demonstrate the basic principles of COFs-based chemical and biological sensing, then briefly summarize the applications of COFs in sensing some substances of practical value, including some gases, ions, organic compounds, and biomolecules. Finally, we discuss the trends and the challenges of COFs-based chemical and biological sensing. 相似文献