全文获取类型
收费全文 | 10248篇 |
免费 | 1712篇 |
国内免费 | 967篇 |
专业分类
化学 | 10360篇 |
晶体学 | 85篇 |
力学 | 122篇 |
综合类 | 31篇 |
数学 | 25篇 |
物理学 | 2304篇 |
出版年
2024年 | 18篇 |
2023年 | 159篇 |
2022年 | 373篇 |
2021年 | 529篇 |
2020年 | 703篇 |
2019年 | 556篇 |
2018年 | 499篇 |
2017年 | 572篇 |
2016年 | 775篇 |
2015年 | 755篇 |
2014年 | 840篇 |
2013年 | 995篇 |
2012年 | 865篇 |
2011年 | 847篇 |
2010年 | 665篇 |
2009年 | 655篇 |
2008年 | 589篇 |
2007年 | 531篇 |
2006年 | 406篇 |
2005年 | 343篇 |
2004年 | 252篇 |
2003年 | 209篇 |
2002年 | 172篇 |
2001年 | 147篇 |
2000年 | 95篇 |
1999年 | 84篇 |
1998年 | 54篇 |
1997年 | 38篇 |
1996年 | 31篇 |
1995年 | 24篇 |
1994年 | 23篇 |
1993年 | 30篇 |
1992年 | 24篇 |
1991年 | 13篇 |
1990年 | 13篇 |
1989年 | 8篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 454 毫秒
121.
聚合物硼氢阴离子还原剂的制备及其对酯的还原研究 总被引:3,自引:0,他引:3
氯型季我安盐型强碱性阴离子交换树脂711^#与硼氢化钾反应制得聚合物硼氢阴离子还原剂,树脂容量3.2mmol BH4/g。用于不同酯化合物的还原,操作简便,树脂可再生重复使用。 相似文献
122.
Gold nanoparticles in polyelectrolyte multilayers film can be easily prepared by repeating immersion of a substrate in poly(diallyl dimethylammonium) chloride (PDDA)-AuCl4− complexes solution followed by reduction Au3+ through heating. UV-vis spectroscopy, cyclic voltammetry (CV) and tapping-mode atomic force microscopy (AFM) are used to confirm the successful construction of the polyelectrolyte multilayers film and the formation of gold nanoparticles. The multilayers film shows electrocatalytic activity to dioxygen reduction. 相似文献
123.
利用静电纺丝法与气固反应相结合, 成功地制备了硫化锌掺锰/聚乙烯醇复合纳米纤维, 并对所制备的复合物进行了表征, 探讨了复合物的结构及其性能. 相似文献
124.
The assembly strategy to prepare a monolayer of bovine serum albumin on the surface of silica gel supported gold nanoparticles is described. The stereo‐specific recognition ability of this material was evaluated by enantioresolution of Dansyl‐norvaline. For enantiomeric separation, the influences of buffer concentration and the concentration of organic modifier on the separation performance were investigated. A better separation in terms of enantioresolution and peak shape was found with the phosphate concentration at 30 mM. Moreover, the peak shape and resolution can be improved by the addition of methanol solution. Enantioresolution of Dansyl‐norvaline was obtained from this material at optimized conditions. It appears that the immobilization of a monolayer of bovine serum albumin on gold nanoparticles as the chiral selector of Dansyl‐derivative amino acid is promising. 相似文献
125.
The feasibility of using Zr(IV)-porphyrins as novel ionophores for preparing anion-selective polymeric membrane electrodes is examined. Electrodes constructed using o-nitrophenyl octyl ether plasticized poly(vinyl chloride) membranes containing Zr(IV)-octaethylporphyrin (OEP) dichloride (Zr(IV)[OEP]Cl2) or Zr(IV)-tetraphenylporphyrin (TPP) dichloride (Zr(IV)[TPP]Cl2) were found to exhibit enhanced potentiometric selectivity toward fluoride compared to electrodes based on a typical anion-exchanger (e.g. tridodecylmethylammonium chloride). At pH 5.5, the electrodes displayed the following selectivity sequences: ClO4− > SCN− > I− > F− > NO3− > Br− > NO2− > Cl− and F− > ClO4− > SCN− > I− > NO2− > NO3− > Br− > Cl− for membranes doped with Zr(IV)[OEP]Cl2) and Zr(IV)[TPP]Cl2, respectively. Both ionophores are shown to operate via a charged carrier mechanism, with 10 mol% of lipophilic tetraphenylborate derivative in the membrane phase required to achieve optimal selectivity. Electrodes prepared with both metalloporphyrin species display super-Nernstian response toward fluoride with slopes typically greater than −100 mV per decade. It is shown, via UV-VIS spectroscopy of the membrane phase, that this behavior occurs due to spontaneous formation of hydroxide ion bridged porphyrin dimers in the membrane in the presence of the lipophilic anionic additive. The dimers are easily converted to monomeric species upon increasing the concentration of fluoride in the sample solution. Decreasing the pH of sample buffer background solution (from pH 5.5 to pH 3) decreases the lower detection limit (DL) of the electrode response toward fluoride (by two-order of magnitude) and improves the electrodes’ selectivity. 相似文献
126.
127.
128.
纳米核壳式铜-锡双金属粉的制备及性能研究 总被引:7,自引:0,他引:7
A kind of novel core-shell Cu-Sn bimetallic nanoparticles has been prepared by a new method (displacement method), in which Sn was made to cover on the surface of Cu nano-core. The preparation method and reaction mechanism have been discussed. This reaction happened under the existence of coordinate agent-(NH2)2CS and protective agent PVP. The nanoparticles prepared were with a core-shell structure, granule diameter between 50~100 nm and good dispersing capability. The Cu-Sn nanoparticles proposed has better oxidation-resistant ability than Cu nanoparticles with corresponding granule diameter and can be applied as lubricant additives as well as antibacterial agent. When the additive amount is very low (0.1wt‰~0.5wt‰), it can improve the PB of the lubricant by 92%~106%, and also enhance its antiwear characteristics and friction-reducing properties. At the concentration of 1 000 ppm, it can reach an antibacterial ratio of 99.99%. 相似文献
129.
Bodnarchuk M. I. Kovalenko M. V. Stroyuk A. L. Kuchmii S. Ya. 《Theoretical and Experimental Chemistry》2004,40(5):287-292
The photochemical behavior of solutions containing a mixture of CdS and CdTe nanoparticles under pulsed irradiation conditions was investigated. It was shown that electron transfer from the CdS particles to the CdTe nanoparticles occurs during the photoexcitation of such systems. The effectiveness of the process is increased with increase in the size of the CdTe nanoparticles. Such behavior is due to decrease in the potential of the CdTe conduction band with increase in the size of the nanoparticles as a result of the appearance of quantum-dimensional effects. 相似文献
130.
聚丙烯/纳米蒙脱土复合材料的结晶动力学研究 总被引:5,自引:1,他引:5
徐笑非 《分析测试技术与仪器》2002,8(1):26-30
采用热分析方法,研究了聚丙烯/纳米蒙脱土复合材料(PP/CLAY)的等温结晶行为,并分别用Avrami方程和赵志英方法对所得数据进行了分析,研究结果表明,纳米蒙脱土微粒对聚丙烯等温和非等温结晶行为均有不同程度的影响,可提高聚丙烯的结晶速率并改善结晶结构。 相似文献