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131.
采用水热法合成了配位聚合物[Co2(HBTC)2(H2O)6]·C4H10N2·2H2O}n(H3BTC为1,3,5-均苯三羧酸,C4H10N2为哌嗪),通过X射线单晶衍射、红外光谱和荧光光谱进行表征,并用TGA研究了该配位聚合物的热稳定性.晶体属三斜晶系,P1空间群,a=1.05437(9)nm,b=1.05485(9)nm,c=0.71482(5)nm,α=102.4623(28)°,β=91.3500(42)°,γ=111.0186(29)°,V=0.72018(10)nm3,Mr=764.37,Dc=1.762g·cm-3,Z=1,μ(MoKα)=1.25mm-1,F(000)=394,R=0.0307,wR=0.0815.晶体的基本构建单元中包含2个Co()中心、2个配位的HBTC分子和6个配位的水分子.基本构建单元通过相互链接形成具有“Z”型结构的一维配位聚合链,链间通过两种不同的氢键(O—H…O和N—H…O)相互作用,进而形成具有三维骨架结构的微孔晶体,微孔大小为0.71nm×0.82nm.荧光光谱表明,常温下用λex=312nm的光激发后,配位聚合物在329nm处出现强烈的荧光发射. 相似文献
132.
The chromatographic separation properties of long, thin adsorption tubes enable substance-specific quantitative enrichment and reduction to be achieved when sampling and thermal desorption are carried out in the same flow direction. The specific retention volumes, and also the breakthrough and peak end volumes, of 69 compounds in the boiling range between-164 and 126°C and of a relative molecular mass between 16 and 119 were determined at temperatures between 30 and 130°C: normal alkanes, isoalkanes, cycloalkanes, alkenes, polyenes, alkynes, aromatics, ethers, alcohols, aldehydes, ketones, carboxylic acids and their esters, nitroalkanes, O-heterocycles, S-heterocycles, chloroalkanes, water, nitrogen monoxide, nitrogen dioxide, carbon dioxide, and sulfur dioxide. The correlation between adsorbent temperature and specific retention volume of these components, presented in the form of diagrams, permits the required quantity of adsorbent to be determined for a given sample volume. Contrary to literature sources, even extremely volatile compounds such as propane, propene, methanol, formaldehyde, formic acid, and chloromethane can be quantitatively retained on Tenax provided the operating conditions are appropriately selected. 相似文献
133.
Two molecular imprinting polymer (MIP) monolithic columns with (S)-(-)-1,1'-bi-2-naphthol and (R)-(+)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol as the templating molecules, respectively, have been prepared by in situ polymerization using 4-vinylpyridine and ethylene dimethacrylate as functional monomer and cross-linker, respectively. The columns with good flow-through properties were obtained by changing the molar ratio of the functional monomer and the template molecule. The effects of mobile-phase composition on separation of enantiomers were systematically investigated. The results indicate that hydrophobic interaction in aqueous solution and hydrogen-bonding interaction in ACN between the enantiomers and polymers could play important roles in the retention and resolution. The effects of chromatographic conditions, such as flow rate, column temperature, sample loading, on the enantioseparation were also studied. Further, these two MIP columns show a cross-reactivity. 相似文献
134.
聚丙烯共混物反应挤出过程中的降解抑制 总被引:4,自引:0,他引:4
聚丙烯/(丙烯腈-苯乙烯)共聚物在过氧化二异丙苯存在下反应共混挤出时,加入亚油酸三甘酯可以有效地抑制过程的降解,从挤出物中分离出聚丙烯组分测试熔体流动速率表明,加入亚油酸三甘酯后,其熔体流动速率有很大下降,扫描电子显微镜的观察表明,调节过氧化二异丙苯和亚油酸三甘酯的加入量,可有效控制降解并生成较多的接枝物相容性,显著改善相形态。 相似文献
135.
Tsutomu Oishi Kensoh Kagawa Minoru Fujimoto 《Journal of polymer science. Part A, Polymer chemistry》1995,33(8):1341-1352
Two types of optically active N-[N′-(α-methylbenzyl)amino/carbonyl-n-alkyl]maleimides (MBAC) were synthesized from maleic anhydride, 6-amino-n-caproic acid (or 12-amino-n-dodecanoic acid), and (R)-(+)-α-methylbenzylamine. Radical homopolymerizations of MBAC were performed in several solvents at 60 and 110°C for 24 h to give optically active polymers. Radical copolymerizations of MBAC were performed with styrene (ST) and methyl methacrylate (MMA) in dioxane at 60°C. The monomer reactivity ratios and the Alfrey-Price Q-e values were determined. Chiroptical properties of the polymers and copolymers were investigated. © 1995 John Wiley & Sons, Inc. 相似文献
136.
Polyethylene based composites are attractive materials for advanced circuit board applications because of their unique combination of properties: low dielectric constant and loss factor, light weight, high flexural modulus and low thermal expansion coefficient controlled in all spatial directions. This investigation describes a process to consolidate chopped fibers of ultra‐high molecular weight polyethylene concurrently with its bonding to a copper foil. Bonding is affected by a thin sheet of low‐density polyethylene, incorporating a crosslinking agent with a concentration gradient across the sheets thickness. In this single step process, the composite material is formed and bonded to the metal foil, achieving good adhesion without the use of extraneous glue. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
137.
Summary A porous polymer resin loaded with hydrous zirconium oxide (Zr-gel) was evaluated as a stationary phase for the liquid chromatographic separation of disubstituted aromatic compounds. The prepared Zr-gel was used to separate disubstituted phenols andortho-substituted benzoic acid derivatives in reversed-phase mode. The retention time of catechol was greater than those of other disubstituted phenols; this implies that the Zr-gel has specificity for the phenolic hydroxyl group. The retention behavior ofortho-substituted benzoic acid derivatives on the Zr-gel was also evaluated in reversedphase mode using buffer. Phthalic acid was specifically retained in the vicinity of pH 6.0, which has been regarded as the equal adsorbic point. Similar behavior was also observed for salicylic acid, although the retention time of salicylic acid was less than that of phthalic acid. It seems that the specific retention behavior of hydrous zirconium oxide is a result of complexation with ligands such as hydroxyl and carboxyl groups. The results of this study have revealed that the retention mechanism of hydrous zirconium oxide is a combination of ion exchange and interaction based on complexation with ligands. 相似文献
138.
139.
XI Jingyu QIU Xinping ZHU Wentao & CHEN Liquan Department of Chemistry Tsinghua University Beijing China 《中国科学B辑(英文版)》2005,48(6)
All solid-state lithium polymer batteries may be one of the best choices for the future electrochemical power source, characterized by high energy densities, good cyclability, reliability and safety[1,2]. Owing to its potential capability to replace the t… 相似文献
140.
Noble metal nanoparticles were prepared by the in situ reduction of the respective metal salt precursors in the presence
of various protective polymers. Transmission electron microscopy (TEM) has been used to determine the particle shapes and
morphologies. These are strongly influenced by the reduction methods and conditions chosen, but the choice of the protective
polymer is equally important for controlling the particle morphologies and for the stabilization of the colloids. A whole
spectrum of nanoparticle morphologies and shapes was obtained, ranging from nanoagglomerates which are nevertheless well-defined
and well-stabilized to nanosized single crystals with triangular shape.
Received: 2 February 1998 Accepted: 29 May 1998 相似文献