全文获取类型
收费全文 | 1969篇 |
免费 | 86篇 |
国内免费 | 285篇 |
专业分类
化学 | 2010篇 |
晶体学 | 5篇 |
力学 | 60篇 |
综合类 | 8篇 |
数学 | 26篇 |
物理学 | 231篇 |
出版年
2024年 | 7篇 |
2023年 | 11篇 |
2022年 | 30篇 |
2021年 | 29篇 |
2020年 | 55篇 |
2019年 | 35篇 |
2018年 | 41篇 |
2017年 | 77篇 |
2016年 | 63篇 |
2015年 | 56篇 |
2014年 | 56篇 |
2013年 | 204篇 |
2012年 | 83篇 |
2011年 | 85篇 |
2010年 | 72篇 |
2009年 | 98篇 |
2008年 | 88篇 |
2007年 | 123篇 |
2006年 | 107篇 |
2005年 | 114篇 |
2004年 | 133篇 |
2003年 | 84篇 |
2002年 | 87篇 |
2001年 | 70篇 |
2000年 | 74篇 |
1999年 | 56篇 |
1998年 | 55篇 |
1997年 | 56篇 |
1996年 | 40篇 |
1995年 | 52篇 |
1994年 | 42篇 |
1993年 | 33篇 |
1992年 | 36篇 |
1991年 | 17篇 |
1990年 | 15篇 |
1989年 | 9篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 9篇 |
1983年 | 5篇 |
1982年 | 4篇 |
1981年 | 8篇 |
排序方式: 共有2340条查询结果,搜索用时 0 毫秒
51.
Sylvie BertinJean-Jacques Robin 《European Polymer Journal》2002,38(11):2255-2264
Recycling of mixed plastic wastes composed of low-density polyethylene (LDPE) matrix and polypropylene (PP) was carried out by compounding using single-screw or twin-screw extruders. Blends of virgin polymers have been prepared to compare mechanical properties of both virgin and regenerated materials. First, a model composition of virgin LDPE/PP blend was prepared to study the effect of process parameters and that of different types of compatibilizers. Second, the results were applied to plastic wastes coming from industrial post-consumer plastic wastes. By adding compatibilizing agents such as ethylene-propylene-diene monomer, ethylene-propylene monomer, or PE-g-(2-methyl-1,3-butadiene) graft copolymer, elongation at break and impact strength were improved for all blends. The effect of these various copolymers is quite different and is in relation with their chemical structure. The recycled blends exhibit suitable properties leading to applications that require good mechanical properties. 相似文献
52.
IntroductionItiswellknownthatmetallocenesactivatedwithmethylaluminoxane (MAO)arehighlyactivehomogeneousZiegler Nattacatalyststhatproducepolyolefinwithcon trolledstereoregularityandnarrowmolecularweightdistri bution ,1 4 however,themolecularweightofthepolym… 相似文献
53.
Different grades of linear low density polyethylenes (LLDPEs) have been quenched cooled step-wise and crystallised isothermally
at (a series of increasing) temperatures in a DSC (thermal fractionated samples). These samples have been investigated by
temperature modulated DSC (MDSC). The heat flow curves of the thermal fractionated materials were compared with those obtained
from samples crystallised at a relatively slow cooling rate of 2 K min-1(standard samples).
The melting enthalpy obtained from the total heat flow of the thermal fractionated samples was 0-10 J g-1higher than those of standard samples. The melting enthalpy obtained from the reversing heat flows was 13-31 J g-1lower in the thermal fractionated samples than in the standard samples. The ratio of the reversing melting enthalpy to the
total melting enthalpy increased with decreasing density of the PE. The melting temperature of the endotherms formed by the
step-wise cooling was 9 K higher than the crystallisation temperature.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
54.
Aiming to develop a high performance fiber reinforced rubber of SBR, a special technique using electron beam (EB) irradiation-induced graft-polymerization was applied to ultra-high molecular-weight polyethylene (UHMWPE) fibers. Although UHMWPE is chemically inert, N-vinyl formamide (NVF) could be graft-polymerized onto the UHMWPE fiber surface with this special technique. A maximum grafting percentage of 23.6% was achieved. The composite of SBR and grafted UHMWPE fibers with maximum grafting indicated a linear increase in the initial modulus and strength with the fiber content. At the fiber content of 10%, the initial modulus was improved about five times with respect to that of the pure SBR, while the strength was done about twice. At this moment, only a small reduction could be observed in the strain compared with that of pure SBR. The fiber reinforced rubber with a good performance was obtained in the system of SBR and grafted UHMWPE fibers. 相似文献
55.
Kawaljeet Singh Samra Ravinder Singh Lakhwant Singh 《Journal of Macromolecular Science: Physics》2013,52(10):691-698
Polyethylene terephthalate (PET) films of 50?μm thickness were exposed to swift-heavy 50?MeV copper and 84?MeV oxygen ions, with fluence varying from 1?×?1011 to 1?×?1013 ions cm?2. Differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) and UV-visible spectroscopic techniques were used to characterize the irradiated samples. The XRD and DSC analysis indicated the loss of crystallinity during/after the irradiation. The FTIR spectra revealed the formation of alkyne end groups, C═C groups and structural deformation with increase of ion fluence. Considerable reduction in the value of the optical bandgap was inferred from the study of the UV-visible absorption curves. 相似文献
56.
57.
P. K. Kamweru F. G. Ndiritu T. K. Kinyanjui Z. W. Muthui R. G. Ngumbu P. M. Odhiambo 《Journal of Macromolecular Science: Physics》2013,52(7):1338-1349
Plastic bags mostly made of polyethylene (PE) cause pollution as solid waste due to their non-degradability nature. Initiation of a degradative process by enhanced photo-oxidation is a possible method for an accelerated degradation. This paper presents temperature treatment effects on PE films where photodegradation was initiated using ultraviolet (UV) irradiation in the ranges of 200–300 nm and 300–400 nm for 2 hr. Effects of temperature of 40°C and 55°C on non-UV-irradiated and UV-irradiated PE films processed by conventional methods were investigated and evaluated after 50 hr, 150 hr, and 350 hr of temperature exposure. The effects of UV wavelength range irradiation on the degradation were deduced. Measuring the dynamic moduli using a dynamic mechanical analyzer monitored the degradation. The decrease in average storage modulus was 62% with treatment at 55°C, higher than the 16% drop at 40°C for unirradiated samples after 350-hr exposure. Cross-linking in UV-exposed samples, characterized by an increase in dynamic modulus (stiffening), was observed followed by a reduction of storage modulus. Temperature treatment at 55°C together with 300–400-nm UV range irradiation resulted in the largest increase, i.e., 22% after 150 hr, followed by the largest reduction of storage modulus, i.e., 74.6% for a cumulative 350-hr exposure. 相似文献
58.
Exhaled breath condensate is a promising, non-invasive, diagnostic sample obtained by condensation of exhaled breath. Starting from a historical perspective of early attempts of breath testing towards the contemporary state-of-the-art breath analysis, this review article focuses mainly on the progress in determination of non-volatile compounds in exhaled breath condensate. The mechanisms by which the aerosols/droplets of non-volatile compounds are formed in the airways are discussed with methodological consequences for sampling. Dilution of respiratory droplets is a major problem for correct clinical interpretation of the measured data and there is an urgent need for standardization of EBC. This applies also for collection instrumentation and therefore various commercial and in-house built devices are described and compared with regard to their design, function and collection parameters. The analytical techniques and methods for determination of non-volatile compounds as potential markers of oxidative stress and lung inflammation are scrutinized with an emphasis on method suitability, sensitivity and appropriateness. The relevance of clinical findings for each group of possible non-volatile markers of selected pulmonary diseases and methodological recommendations with emphasis on interdisciplinary collaboration that is essential for future development into a fully validated clinical diagnostic tool are given. 相似文献
59.
Yuichi Tominaga Takuya Kubo Kenji Sueyoshi Ken Hosoya Koji Otsuka 《Journal of polymer science. Part A, Polymer chemistry》2013,51(15):3153-3158
To synthesize the novel molecular‐ and pH‐stimulus‐responsive hydrogel, we prepared poly(ethylene glycol)‐based hydrogel containing ionic groups. We evaluated the fundamental swelling/shrinking properties of the hydrogels synthesized by various conditions. Decreasing the molecular weight of a crosslinker provided the increasing of the equilibrium swelling ratio. Also, the equilibrium swelling ratio was changed by the introduction of functional ionic monomers and its compositions. Furthermore, the swelling/shrinking behaviors of the hydrogels were affected by the environmental condition of aqueous solution, in fact the hydrogels were considerably shrunk (to one‐fifth volume) using a di‐ionic solute in the aqueous solution through the ionic interactions between the hydrogel and the solutes. Additionally, the specific shrinking to diamine compounds was also observed in response to pH change. These results clearly show the swelling/shrinking responsibility of the hydrogels toward the molecular recognitions and its pH conditions. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3153–3158 相似文献
60.
《高分子科学杂志,A辑:纯化学与应用化学》2013,50(6):765-770
Antibacterial activity was imparted with polyamidoamine (PAMAM) side chain dendritic polyurethane (SCDPU‐PEG) by doping of silver particles. Antibacterial activities of both the polyurethane (SCDPU‐PEG) and its silver doped structures were investigated against Escherichia coli bacteria. The silver doped polymeric structures were found to exhibit antibacterial activity while the polymer without silver loading showed no antibacterial activity. Formation of silver doped side chain dendritic polymers was investigated from the UV‐vis plasmon absorption band of silver particles. 相似文献