Determination of gallium by graphite furnace atomic absorption spectrometry with combined use of a tungsten-coated L'vov platform tube and a chemical modification technique

Tungsten-coated non-pyrolytic graphite (NPG), pyrolytic graphite (PG) and pyrolytic L'vov platform graphite (PPG) tubes were prepared, and their analytical performances were compared. The coating process simply involved injecting 100 μl of a sodium tungstate solution (0.01 mol l⁻¹) into each graphite tube, followed by heating according to a temperature programme similar to an atomisation cycle for the determination of gallium. This procedure for coating was repeated at least 12, 25, and 7 times towards NPG, PG, and PPG tubes, respectively. Among these tubes, the tungsten-coated PPG tube showed excellent performance for the determination of gallium. By combined use of a chemical modifier such as aluminium(III) or nickel(II) a detection limit (3σ) of 6 pg and sensitivity (1% absorption) of 3–4 pg were achieved. The practical potential of the proposed technique was demonstrated for the determination of gallium in several samples of alloys and fresh water.     

Microfluidic platform serves as controllable fabrication of binary Mo/Ir nanodots/carbon hetero-material for efficient electrocatalytic nitrogen reduction

Electrocatalytic nitrogen reduction reaction (NRR) is regarded as a potential routine to achieve environment-friendly ammonia production, because of its abundant nitrogen resources, clean energy utilization and flexible operation. However, it is hindered by low activity and selectivity, in which condition well-designed catalysts are urgently in need. In this work, a binary Mo/Ir nanodots/carbon (Mo/Ir/C) hetero-material is efficiently constructed via microfluidic strategy, of which the nanodots are homogeneously distributed on the carbon skeleton and the average size is approximately 1 nm. Excellent performance for NRR is obtained in 1 mol L⁻¹ KOH, of which the optimized ammonia yield and faradic efficiency are 7.27 μg h⁻¹ cm⁻² and 2.31% respectively. Moreover, the optimized ammonia yield of 6.20 μg h⁻¹ cm⁻² and faradic efficiency of 10.59% are also obtained in 0.005 mol L⁻¹ H₂SO₄. This work achieves the continuous-flow synthesis and controllable adjustment of hetero-materials for favorable morphologies, which provides an innovative pathway for catalyst design and further promotes the development of ammonia production field.     

基于网络教学平台的PBL教学模式在物理化学实验教学中的实践

基于网络教学平台系统,结合“蔗糖水解速率常数的测定”“液体饱和蒸气压的测定”“燃烧热的测定”等3个物理化学常规实验,介绍了在物理化学实验教学中实施以问题为导向的教学法（PBL）的具体实施步骤,探讨了该教学模式在化学实验教学实践中的应用。结果表明该教学模式教学效果良好,具有一定的推广价值。     

航空稳像光电平台设计

分析了随机振动对调制传递函数的影响,指出角位移是影响航空成像质量的主要因素.研究了特定条件下可容许的MTF下降,并转变为稳定系统的设计参量,用来指导稳像系统的设计.利用空间机构学及平行四边形平动原理,研制了一种新的无角位移减振稳像平台,满足既无角位移又达到减振要求.根据设计理论给出了设计实例,对频率高于100 HZ的振动,衰减达34dB,并利用动力学软件进行测试仿真,仿真曲线验证无角位移减振的正确性,同时对无角位移机构进行光学测试,结果耦合角度小于8″,可以满足航空成像要求.     

精密工作台的设计与实验研究

微器件装配技术是实现组合结构的微机械电子学系统(MEMS)的关键技术之一,精密工作台系统则是微装配系统的一个重要组成部分。精密工作台系统包括粗动工作台和微动工作台:粗动工作台包括精密机械及其传动系统、光栅定位系统、直流力矩电机驱动系统及计算机控制系统;微动工作台包括微动台、压电陶瓷驱动电源和电感测微移。实验结果表明,粗动台系统的最高速度为5mm/s,最低速度为3.4μm/s,系统的重复定位精度为±1μm;微动台系统的定位精度可达到±1μm。     

带弱"平台"皮秒光孤子的数值研究

通过数值求解变系数非线性薛定谔方程,发现光纤系统对带有弱“平台”的皮秒光孤子有独特的传输特性。在常参数光纤系统中,这种光孤子体现“呼吸”特性,而在特殊的分布参数光纤系统中,则能较平稳地传输。     

毛细管等电聚焦/毛细管无胶筛分电泳二维蛋白质分离平台的构建

设计并制作了一种新型的中空纤维接口,以此为核心构建了毛细管等电聚焦(CLEF)／毛细管无胶筛分(CNGE)电泳二维蛋白质分离技术平台,实现了将二维凝胶电泳从平板转移到毛细管中。利用该二维分离平台,对血红蛋白样品进行了高效、快速分离分析,验证了该二维分离平台的可行性及分离效能。实验结果表明：二维分离系统总的峰个数和分离效能都比各自一维分离系统有较大提高。     

下视惯性平台瞄准线稳定的数理分析

分析了下视惯性平台瞄准线稳定的工作原理,解析了惯性稳瞄平台坐标系的数学模型,在坐标转换法的基础上推导了瞄准线稳定的数学公式。     

Determination of beryllium by electrothermal atomic absorption spectrometry using tungsten surfaces and zirconium modifier

Electrothermal atomization of beryllium from graphite and tungsten surfaces was compared with and without the use of various chemical modifiers. Tungsten proved to be the best substrate, giving the more sensitive integrated atomic absorption signals of beryllium. Tungsten platform atomization with zirconium as a chemical modifier was used for the determination of beryllium in several NIST SRM certified reference samples, with good agreement obtained between the results found and the certified values. The precision of the measurements (at 10 μg L⁻¹), the limit of detection (3σ), and the characteristic mass of beryllium were 2.50%, 0.009 μg L⁻¹ and 0.42 pg, respectively.     

海洋平台的时域低阶建模与主动控制研究

以海洋平台为对象, 开展时域低阶建模与主动控制的研究. 首先采用OKID(observer/Kalman filter identification)辨识方法, 根据系统的输入和输出时间历程数据计算出系统的Markov参数, 然后采用特征系统实现方法(eigensystemrealization algorithm, ERA)建立起一个阶数较低的系统状态空间模型, 随后基于该低阶模型采用LQG (linear quadratic Gaussian)控制方法进行控制律的设计, 最后将该控制律引入到系统的有限元模型中进行反馈闭环控制, 验证控制律的有效性. 数值仿真结果显示, 所给方法是有效和可行的.