废塑料-煤共处理液化的研究进展

煤和废塑料共处理液化是一种新的煤直接液化技术,它的主要特点是利用废塑料作为主要的氢来源,本文介绍了目前已取得的一些主要进展,并指出了下一步工作的方向。     

政府-企业-居民多维演化博弈下城市垃圾绿色发电的政府财政策略优化研究

城市垃圾发电技术趋于成熟,但是部分企业并没有选择绿色技术进行清洁焚烧绿色发电,引发公众抗议。针对现行财政策略对企业绿色发电行为引导的不足,建立政府-企业-居民多维演化博弈模型,分析财政决策变量对企业绿色发电行为策略的影响,提出命题并推导证明电价补贴、垃圾处理费支付、税收退税和设备采购抵税这四个财政决策变量能够有效引导企业绿色发电行为的参数值域,并基于现实数据进行Matlab仿真,分析各财政决策变量对企业绿色发电行为策略的收敛性和敏感性作用,最后提出财政策略优化建议。结果表明通过财政间接扶持方式引导企业绿色技术行为,能使电价补贴处于更低阈值,减少财政直接支出成本,不可过度依赖电价补贴,需改善垃圾处理费支付水平,丰富税收扶持手段。     

光学塑料的发展与应用

简述光学塑料的发展与应用,介绍光学塑料的品种及性能,塑料透镜的种类和对材料的要求,对今后的发展动向和技术关键进行了探讨。     

UV-VIS and FTIR spectral studies of CR-39 plastics irradiated with X-rays

A study has been made on the UV-VIS and FTIR spectra of CR-39 plastics irradiated with 50 kVp tube X-rays in the dose range 0ndash;45 MR. The optical transmittance over the wavelength region of 200–1000nm decreases with the X-ray exposure, much greater decrease being observed in the UV region. The IR absorption spectra of the irradiated samples show the presence of two new strong absorption bands at the frequencies 655 and 2340 cm⁻¹, indicative of the gas CO₂ produced inside the plastic.The absorbance of these bands increases linearly with the X-ray dose.     

塑料注射充模流变过程的高速摄影研究

塑料注射成型是加工热塑性塑料的一种主要方法。注射过程中,塑料在注射机料筒和模具中经历着复杂的运动和变化过程,直接影响到充模的过程,和塑料制品的微观、细观、宏观结构(取向、结晶、熔合均匀性等),从而影响到塑料制品的物理—机械性能。所以充模过程是注射成型的核心过程。 本文采用透明模实验装置,对多种模具型腔的注射充模流变过程进行了高速摄影研究。文中介绍了试验装置、光路系统,以及摄影结果,并采用影片运动数据分析处理系统,对园形模腔的充模流变过程进行了定量动态分析,研究了充模流变过程的运动规律。这对完善塑料注射成型工艺的基础理论,摆脱了目前生产中经验式和技艺式处理问题的工作方法,对减少模具设计和工艺参数确定过程中的盲目性具有重要的意义。     

Treatment and Disposal of Pharmaceutical Wastewater: Toward the Sustainable Strategy

The literature on the treatment of pharmaceutical wastewater over the period 1990–2015 has been reviewed to develop a sustainable treatment strategy. Analysis of the existing methods for treatment and disposal practices of pharmaceutical waste has been undertaken on the classification of the treatment methods under well-identified broad specific groups. The review reveals the associated merits and demerits of the traditional and the emerging methods and the challenges involved in overcoming the shortcomings. Considering the very diverse nature of the contaminants and the poor success rates of the existing technologies, it transpires that no single classical technology is capable of fully taking care of the hazards emanating from pharmaceutical waste discharges. On the other hand, some recent technologies such as membrane-integrated hybrid technologies are emerging as more successful ones than the conventional technologies. But, scale up confidence with respect to such new technologies is still very limited and needs to be substantially improved through extensive investigation on the pilot scale using real pharmaceutical wastewater rather than synthetic wastewater. This review directs the research focus to the development of sustainable treatment technologies.     

芳烷基酚树脂玻纤增强材料性能的研究

用芳烷基酚树脂与玻璃纤维布制成纤维增强材料，研究了引材料的高温热老化性能和在３０－５０％热沸太航热醋和含氯离子的热沸醋酸下的腐蚀性能。     

Catalytic degradation of polyolefins over hexagonal mesoporous silica: Effect of aluminum addition

Degradations of polypropylene (PP) and polyethylene (PE) over pure hexagonal mesoporous silica and aluminum-containing hexagonal mesoporous silica catalysts were studied in a fixed bed catalytic reactor at 380 and 430 °C, respectively. The thermal and catalytic degradations of both PP and PE in liquid-phase-contact and vapor-phase-contact modes over pure hexagonal mesoporous silica had no significant effect on the product yields. The liquid products were widely distributed in hydrocarbons with boiling point ranges of 36–405 °C. By adding a small amount of aluminum to the hexagonal mesoporous material, aluminium-containing hexagonal mesoporous silica exhibited good performance in cracking heavy molecular weight hydrocarbons into light hydrocarbons. High liquid yields and less coke deposits were obtained in liquid-phase-contact reaction with increasing aluminum content. The liquid products were mainly composed of C₅–C₁₀ hydrocarbons with boiling points of 36–174 °C, and propene, butene, and butane were main components in gaseous products. The effect of degradation temperature was not observed on product yields though degradation rate of polyolefin into liquid products was faster. Conversely, in vapor-phase-contact reaction, an increase in gaseous yield was observed when increasing the amount of aluminum and temperature of the cracking reactor, while the residue yield remained constant.     

利用焦化工艺处理废塑料技术研究 Ⅱ. 200 kg焦炉中试试验

利用200 kg焦炉考察两种废塑料(PS和WMP)与首钢炼焦配煤按不同比例均匀混合共焦化所得焦炭的质量变化规律，以期能为焦化工艺处理废塑料技术的工业应用提供基础数据。研究表明：废塑料与煤共焦化所得焦炭冶金焦率和焦炭质量降低明显，且随着废塑料添加比例增加，所得焦炭质量劣化程度整体加大；与添加同比例的PS相比，添加WMP虽得到较差的冶金焦率，但所得焦炭的转鼓强度（M40和M10）和反应后强度（CSR）均优于添加PS的情形；废塑料与炼焦配煤简单混合共焦化，严重影响焦炭质量，不能应用于工业实践。     

泡沫塑料柱色谱法纯化可溶性锌（镉）盐

研制出复合泡沫塑料色诸柱，并且将其用于可溶性锌（镉）盐的深度纯化，除去重金属杂质离子Ｆｅ￣（２＋）、Ｃｒ￣（３＋）、Ｍｎ￣（２＋）、Ｐｂ￣（２＋）、Ｃｕ￣（２＋）、Ｃｏ￣（２＋）和Ｎｉ￣（２＋），快速而效果显著。