全文获取类型
收费全文 | 930篇 |
免费 | 57篇 |
国内免费 | 63篇 |
专业分类
化学 | 739篇 |
晶体学 | 6篇 |
力学 | 28篇 |
综合类 | 77篇 |
数学 | 51篇 |
物理学 | 149篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 62篇 |
2021年 | 102篇 |
2020年 | 46篇 |
2019年 | 42篇 |
2018年 | 19篇 |
2017年 | 29篇 |
2016年 | 39篇 |
2015年 | 30篇 |
2014年 | 39篇 |
2013年 | 67篇 |
2012年 | 47篇 |
2011年 | 42篇 |
2010年 | 35篇 |
2009年 | 24篇 |
2008年 | 38篇 |
2007年 | 39篇 |
2006年 | 30篇 |
2005年 | 42篇 |
2004年 | 24篇 |
2003年 | 36篇 |
2002年 | 27篇 |
2001年 | 14篇 |
2000年 | 23篇 |
1999年 | 18篇 |
1998年 | 14篇 |
1997年 | 15篇 |
1996年 | 10篇 |
1995年 | 11篇 |
1994年 | 13篇 |
1993年 | 9篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1959年 | 3篇 |
排序方式: 共有1050条查询结果,搜索用时 15 毫秒
91.
通过对13种植物生长调节剂的试验,建立了用于筛选植物生长调节剂的生物检测方法,该方法第1步采用萝卜、黄瓜、小麦、油菜4种幼苗生长法联合筛选,第2步采用萝卜子叶扩张法、黄瓜子叶生根法联合筛选,这样能保证有生长调节剂活性的化合物在普筛中不被漏筛,而且方法简便,测试周期短。 相似文献
92.
《Analytical letters》2012,45(4):567-574
The goal of this study was to develop and validate a high-performance liquid chromatography method for the quantification of two essential oil constituents (myristicin and linalool) from extracts of the three aromatic plants exposed to low-intensity microwave radiation. The analysis was performed by high-performance liquid chromatography using a mobile phase consisting of ultrapure water and acetonitrile. The separations were carried out in the following conditions: isocratic conditions for 30 minutes with 100% acetonitrile and then linear gradient conditions from 100% acetonitrile to 25% acetonitrile for 15 minutes. The developed method was validated in terms of linearity, limits of detection, limits of quantification, precision, accuracy, and robustness. The results show that plants react differently under microwave stress and change their essential oil content as a response. 相似文献
93.
Fifteen new ferrocene derivatives containing 1H‐1,2,4‐triazole moiety were synthesized in various yields by the condensation of ferrocenecarboxaldehyde with 1‐aryl‐3‐(1H‐1,2,4‐triazo‐1‐yl)‐propen‐1‐ones in toluene. Their structures have been confirmed by 1H NMR, IR, MS and elemental analysis. In addition, the crystal structure of 4l was determined. The antifungal and plant growth regulatory activities of the title compounds are discussed. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
94.
合成了10个未见文献报道的三羧酸乙基DHT的酯类化合物,新化合物的水溶性、脂溶性均较DHT好,并有一定抗病毒活性,其中化合物2的活性最高,对TMV的抑制百分率达到90%,优于对比的DHT 相似文献
95.
District heating plants are becoming more common in European cities. These systems make it possible to furnish users with warm water while locating the production plants in the outskirts having the double benefit of lowering the impact of pollution on the center of the city and achieving better conversion performances. In order to amortize the costs throughout the year, the system often includes a combined heat and power (CHP) plant, to exploit the energy during the summer as well, when the demand for warm water decreases. A linear programming model for the optimal resource management of such a plant is presented and some results for a real case are reported. A distribution network design problem is also addressed and solved by means of mixed integer linear programming. 相似文献
96.
Summary A method was developed for the determination of nitrobenzoic acids and nitrophenols as well as of diaminoaromatics and was
applied to the analysis of water samples from the former ammunition plant at Elsnig (Saxony, Germany).
The procedure is based on a preseparation into a neutral, an acidic and a basic fraction by multi-step extraction at different
pH values followed by HPLC analysis with UV and electrochemical detectors, coupled in series.
Applying optimized enrichment conditions, all investigated compounds were extracted from spiked distilled water with recoveries
>80% and variation coefficients <7%. Similar results were obtained with spiked ground water samples.
After enrichment, all compounds can be analysed by HPLC with UV detection at concentrations below 100 ngL−1. The electrochemical detector (ELCD) allowed a selective and sensitive detection of the nitrophenols and especially of the
diaminoaromatics and, therefore, provides, some advantages in the analysis of real samples.
Presented at the 21st ISC held in Stuttgart, Germany, 15th–20th September, 1996 相似文献
97.
通过对氢化-1,3,5-均三嗪-2,4-二酮衍生物抗病毒活性QSAR计算,预测标题化合物具有较好抗病毒活性,由氢化-1,3,5-均三嗪-2,4-二酮、丙烯酸甲酯和乙二醇衍生物经三步反应合成这些化合物,新化合物经^1H NMR,IR,MS确认结构。 相似文献
98.
玉帘不同外植体培养,诱导出胚性、中间型和非胚性3种类型的愈伤组织,并再生植株.由胚性愈伤组织与叶肉细胞分离出原生质体,进行培养,启动了细胞分裂并形成了多细胞团.同时,还研究了影响玉帘组织培养以及原生质体分离和培养的诸因素. 相似文献
99.
地下厂房位置及轴线方向的选择是一项重要的地质工作,本文在分析琅山抽水蓄能电站厂房区工程地质条件的基础上,就厂房位置及其轴线方向的优化选择,进行了分析和研究。 相似文献
100.
Marta Espina Palanco Klaus Bo Mogensen Katrin Kneipp 《Journal of Raman spectroscopy : JRS》2016,47(2):156-161
We report surface‐enhanced Raman studies on intact plant material using onion layers as a biological target, and silver nanoaggregates and silver island films as enhancing plasmonic structures. Surface‐enhanced Raman scattering (SERS) enhancement allows the detection of strong Raman signatures of chemical constituents of the surface of the onion layer such as cellulose, proteins, and flavonols. Because of long‐time incubation, SERS sensors can access the extracellular space in the inner of the layer. The location of silver nanoparticles inside the onion layer has been monitored by the SERS images collected from chemicals present in the onion and/or reporter molecules attached to the nanoparticles. Our studies show a competitive adsorption of intrinsic bio molecules of the onion layer and reporter molecules. Different spectra from different places of the layer indicate the complex heterogeneous chemical structure of the plant material. The pH‐sensitive reporter molecule para mercapto benzoic acid attached to the nanoparticles allows us to infer pH values inside the extracellular matrix of the onion layer. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献