热重法测定石油磺酸钙的有效组分含量

建立了用热重法测定石油磺酸钙中有效组分含量的方法,该方法和SH／T0034—90《添加剂中有效组分测定法》（橡胶薄膜渗透法）结果基本一致,相关系数达到0．9787．精密度试验表明,本方法具有较好的重复性．     

Influence of change in obstacle blocking rate gradient on LPG explosion behavior

The aim of this study was to examine the propagation characteristics of liquified petroleum gas (LPG)/air explosion. As such, the flame propagation process and pressure parameters of LPG explosion with an equivalent ratio of 1 were obtained using horizontal, long straight pipes and a high-speed camera. The large eddy simulation and power-law flame model were used to reproduce the simulation results, and the morphological evolution of the flame front during the explosion process was analyzed. The results showed that as the blockage ratio gradient increased, the time required for the flame to propagate from the electrode to the end of the pipe increased. Meanwhile, a flocculent flame formed at the end of the pipeline with a blockage ratio of 91%. Additionally, the maximum flame propagation speed changed in the same way as the blockage ratio. The gradient change of the barrier blockage ratio considerably influenced the pressure kinetics characteristics of LPG explosion: the maximum explosion pressure increased first and then decreased, the time to reach the maximum explosion pressure increased, and the deflagration index increased first and then decreased. The chemical kinetics analysis of premixed gas showed that when propane, n-butane, and isobutane were present in the premixed system, some of the elemental reactions that promote n-butane consumption inhibited propane and isobutane consumption. Meanwhile, the formation and consumption rate of H*, O*, and OH* from LPG during the explosion process was less than that of single-component combustible gas except propane.