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81.
82.
I. Kurkova 《Journal of statistical physics》2003,111(1-2):35-56
We consider the problem of temperature dependence of the Gibbs states in two spin-glass models: Derrida's Random Energy Model and its analogue, where the random variables in the Hamiltonian are replaced by independent standard Brownian motions. For both of them we compute in the thermodynamic limit the overlap distribution
N
i=1
i
i
/N[–1,1] of two spin configurations , under the product of two Gibbs measures, which are taken at temperatures T,T respectively. If TT are fixed, then at low temperature phase the results are different for these models: for the first one this distribution is D
0
0+D
1
1, with random weights D
0, D
1, while for the second one it is
0. We compute consequently the overlap distribution for the second model whenever T–T0 at different speeds as N. 相似文献
83.
We present the implementation into the MOLPRO package of a model for the interaction of a central system with its surrounding environment. The properties of a target system enclosed by a noncovalently bound environment or solvent are modeled as those of a system embedded into the effective pseudopotential arising from the exact electrostatic Coulomb potential and the approximated exchange-repulsion potential. For the latter we use the charge-density overlap model, which relates the exchange-repulsion interaction energy between two species with the overlap of their ground-state electron charge densities. The solutions of the modified Hartree-Fock equations for the target system are obtained self-consistently. This way the exchange-induction effects arising from the converged electron-charge density of the embedded system are implicitly included. Inclusion of the correlation effects is provided by the use of post-Hartree-Fock and density-functional techniques available in the MOLPRO package. The computational and conceptual advantages provided by this approach are shown in the calculation of the dipole polarizabilities of halide and chalcogenide anions in different environments. 相似文献
84.
回顾介绍了葛庭燧院士的生平和他在科学研究、人才培养方面所作出的贡献,展示了他的高尚情操,分析了他取得卓著成就的原因. 相似文献
85.
E. Kasabova D. Alamanova M. Springborg V. G. Grigoryan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,45(3):425-431
The soft deposition of Ni13 and Cu13 clusters on Ni(111) and Cu(111) surfaces is studied by
means of constant-energy molecular-dynamics simulations.
The atomic interactions are described by the Embedded Atom Method.
It is shown that the shape of the nickel clusters deposited on Cu(111) surfaces remains rather intact,
while the copper clusters impacting on Ni(111) surfaces collapse forming double and triple layered
products. Furthermore, it is found that for an impact energy of 0.5 eV/atom the structures of all
investigated clusters show the lowest similarity to the original structures, except for the case of
nickel clusters deposited on a Cu(111) surface. Finally, it is demonstrated that when cluster and
substrate are of different materials, it is possible to control whether the deposition results in
largely intact clusters on the substrate or in a spreading of the clusters. This separation into
hard and soft clusters can be related to the relative cohesive energy of the crystalline materials. 相似文献
86.
The structure of trans‐[Cr(Me2tn)2Cl2]2ZnCl4 (Me2tn = 2,2‐dimethylpropane‐1,3‐diamine) was determined by a single‐crystal X‐ray diffraction study at 173 K. The analysis reveals that there are three crystallographically independent chromium(III) complex cations in the title compound. The chromium(III) atoms are coordinated by four nitrogen atoms of Me2tn and two chlorine atoms in a trans arrangement, displaying a distorted octahedral geometry. The two six‐membered chelate rings in three complex cations are oriented in an anti chair–chair conformation with respect to each other. The Cr–N and Cr–Cl bond lengths average 2.0862(2) and 2.3112(6) Å, respectively. The ZnCl42– have slightly distorted tetrahedral arrangement with Zn–Cl lengths and the Cl–Zn–Cl angles are influenced by hydrogen bonding. The resolved absorption maxima in the electronic d–d spectrum were fitted with a secular determinant for a quartet energy state of the d3 configuration in a tetragonal field. It is confirmed that the nitrogen atoms of the Me2tn ligand are strong σ donors, but the chloro ligands have weak σ‐ and π donor properties toward the chromium(III) ion. 相似文献
87.
Y. Zheng S. L. Simon G. B. McKenna 《Journal of Polymer Science.Polymer Physics》2002,40(18):2027-2036
Amorphous polymers below their glass‐transition temperature are inherently not at equilibrium. As a result, their structures continuously relax in an attempt to reach the equilibrium state. The current models of structural recovery can quantitatively describe the process. One of the parameters needed for the models is the nonlinearity parameter x. It has been proposed that x can be obtained from experimental data with the so‐called peak‐shift method. In this work, we use the Tool–Narayanaswamy–Moynihan model to identify the factors that determine the accuracy of the peak‐shift method and to quantify the errors in the value of x obtained from the peak‐shift method. In addition, we determine the influence of the error in x on the evaluation of the nonexponential model parameter β. Finally, the peak‐shift method is compared with the traditional curve‐fitting method for model parameter determination. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2027–2036, 2002 相似文献
88.
Quasi‐elastic scattering of 1–2 keV electrons is considered with respect to measuring the H content in hydrogenated amorphous carbon (a‐C:H) materials. Interest in the technique lies in the fact that H cannot be typically detected by electron spectroscopic means (AES or XPS for instance). The feasibility of the approach is demonstrated and a quantification procedure is proposed. At the same time however, limitations of the technique (electron stimulated H desorption, low intensity of the H related signal and its spectral interference with the π‐plasmon peak) are discussed. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
89.
Yuru Zou Yuanyuan Yao Wenxia Li 《Journal of Mathematical Analysis and Applications》2008,340(2):1422-1432
Based on a scheme by Lau and Ngai, a sufficient and necessary condition for an IFS of contractive similitudes to satisfy the open set condition is given. A class of Sierpinski carpets with parameters (λ1,λ2) is then investigated. 相似文献
90.
两端对称负折射率缺陷复合光子晶体:多通道滤波和光开关 总被引:1,自引:1,他引:0
采用传输矩阵法对两端对称负折射率缺陷复合光子晶体结构[D(AB)mD]N的透射特性进行了研究.结果表明:当N=2时,该结构透射谱的禁带出现两个完全共振透射峰,当N增加时,每个共振透射峰又分裂为N-1条;当复合光子晶体的层数m逐渐增加时,透射峰的品质因子逐渐提高,且分裂的共振透射峰距离逐渐减少;既为该结构实现高品质的多通... 相似文献