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11.
《Green Chemistry Letters and Reviews》2013,6(2):187-193
Abstract Various 2,6-dibenzylidene cycloalkanones were readily prepared in a few minutes with good yields by simply mixing aromatic aldehydes with cycloalkanones in the presence of catalytic amounts of p-toluenesulfonic acid as a solid heterogeneous catalyst under solvent-free condition. 相似文献
12.
A new and efficient method for the demethylation of 6-membered aza-heterocyclic methyl ethers is described using lithium chloride and para-toluenesulfonic acid. This process is chemoselective for aza-heterocyclic methyl ethers in the presence of aryl methyl ethers.
13.
A simple synthesis of novel (Z)-3-arylidene-2,3-dihydrobenzo[b][1,4]thiazepin-4(5H)-ones from bromo compounds derived from Baylis–Hillman adducts involving selective S-alkylation followed by a lactum formation has been described. 相似文献
14.
Shao-Yong Wu Yoffi Segall Mark Sanders Robert F. Toia John E. Casida 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):221-224
Abstract Peracid oxidation of triester and related phosphorothionates and diester phosphorothioic acids with excess magnesium monoperoxyphthalate in water gives, among other products, dialkyl hydrogenphos-phonates in yields of up to 70%. Hydrogenphosphonate formation is facilitated by the presence of a good leaving group in the starting material. 相似文献
15.
Muhammad Sajid Muhammad Rizwan Dilshad Muhammad Saif Ur Rehman Dehua Liu Xuebing Zhao 《Molecules (Basel, Switzerland)》2021,26(8)
Furfural is one of the most promising precursor chemicals with an extended range of downstream derivatives. In this work, conversion of xylose to produce furfural was performed by employing p-toluenesulfonic acid (pTSA) as a catalyst in DMSO medium at moderate temperature and atmospheric pressure. The production process was optimized based on kinetic modeling of xylose conversion to furfural alongwith simultaneous formation of humin from xylose and furfural. The synergetic effects of organic acids and Lewis acids were investigated. Results showed that the catalyst pTSA-CrCl3·6H2O was a promising combined catalyst due to the high furfural yield (53.10%) at a moderate temperature of 120 °C. Observed kinetic modeling illustrated that the condensation of furfural in the DMSO solvent medium actually could be neglected. The established model was found to be satisfactory and could be well applied for process simulation and optimization with adequate accuracy. The estimated values of activation energies for xylose dehydration, condensation of xylose, and furfural to humin were 81.80, 66.50, and 93.02 kJ/mol, respectively. 相似文献
16.
Starting from tetraacetylribofuranose and 6-chloropurine, in the presence of was synthesized for the first time under microwave irradiation. The title compound 6-chloro-9-β-D-purinenucleoside (Ⅳ) and 6-methoxy-9-β-D-purinenucleoside (Ⅴ) was easily obtained by treatment of the intermediate (Ⅲ) with Na2CO3 in CH3OH solution refluxing for 8min and 2hr respectively. 相似文献
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18.
Summary This paper is focused on the preparation of a library of highly efficient, tailor made, macroporous resins as supports for
reagents and scavengers. From this library a macroporous resin, prepared with 40% cross-linking and with a porogen level of
300% in toluene gave a material superior to those presently available, and was shown to be highly efficient in the preparation
of novel highly reactive polymer supported reagents, including scavengers and oxidants. 相似文献
19.
The one-pot synthesis of spirooxindoles via three-component reaction of urea, isatin, and 1,3-dicarbonyl compounds in the presence of a catalytic amount of p-toluenesulfonic acid in acetonitrile has been carried out.