Reaction of the dimethoxyaminyl radical with tertiary nitrosoalkanes as a method for the preparation of N-alkyl-N′-methoxydiazene N-oxides

The reaction of the dimethoxyaminyl radical with functionally substituted nitrosoalkanes (2) in a 2:1 ratio at 20°C gives the corresponding N-alkyl-N-methoxydiazene N-oxides (3) as a single isomer in preparative yields.N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117913 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10, pp. 2443–2445, October, 1992.     

Synthesis and Characterization of p—[Perfluoro—1—（2—fluorosulfonylethoxy）]ethylated Polystyrene

A new fluorinated polystyrene bearing a p-sulbstiuted perfluoro[1-(2-fluorosulfonylethoxy)]ethyl group was synthesized via one-electron oxidation of polystyrene by perfluoro[2-(2-fluorosulfonylethoxy)]propionyl peroxide at different peroxide to polystyrene molar ratios.The yield of perfluoroalkylation decreases with the increase of the reactant molar ratio.The modified polymer has been characterized by various techniques:the ring pefluoro[1-(2-fluorosulfonylethoxy)]ethylation has been proved by FT-IR and ^19FNMR;the X-ray photoelectron spectra(XPS) show the maximum binding energy of F18,O18,C18(two kinds of carbon atoms,namely C-H and C-F)and S2p,respectively; desulfonylation of the fluorinated polystyrene appearing at 217℃ has been found by its thermogravimetric analysis (TGA).The determinations of contact angle,refractive index and glass transition temperature of the modified polymer have disclosed that when the contact angle increases with the increase of the molar ratio,the refractive index and glass transition temperature decrease.The polydispersity values indicate that the degradation of the polymer chains did not occur during the reaction.     

The influence of simulation conditions in molecular dynamics investigations of model β-sheet peptides

The influence of simulation methods, cutoff based and particle mesh Ewald (PME) on the accuracy by which experimentally derived nuclear Overhauser effect (NOE) data are reproduced, has been investigated using 500-ns-long molecular dynamics simulations on a model -sheet peptide in explicit solvent. The structural and conformational features under the different conditions were evaluated in terms of flexibility, secondary structure content, hydrogen-bonding pattern and percent of native contacts as a function of time. It was found that the different simulation methods strongly influence the dynamics of the peptide, confirming previous observations based on ideal peptide models simulated for much shorter times. Moreover, the results of our simulations prove once more that it is necessary to reach extremely long time scales to obtain enough statistics to accurately reproduce experimental NOE restraints even in the case of the PME method, despite its tendency to the stabilization of conformations which are structurally closely related to the ones derived through experiment. Possible implications regarding the stabilization and folding mechanisms, together with their relationship to the experimental study of peptide models, are discussed.     

Synthesis and ozonization of (+)-4α-(1-trimethylsilyloxyethen-1-yl)-2-carene

(+)-4-(1-Trimethylsilyloxyethen-1-yl)-2-carene was synthesized, and the products of its ozonization were identified.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1984–1987, October, 1995.     

GC investigation of olefins with chemically bonded gamma-mercaptopropylsilane-copper(II) complexes

Summary A column packing containing thiol groups chemically bonded to the silica surface was synthesized. The thiol functional groups were used as ligands capable of forming stable complexes with Cu(II). The prepared material was characterized by gas chromatography using unsaturated linear and branched hydrocarbons as well as cyclic and aromatic hydrocarbons. The occurrence of specific metal—olefin interactions resulting from the formation of -complexes during the chromatographic process was observed.Part IV of a series on transition metal complexes in GC. Part III see ref. [1].     

Randomly transitional phenomena in the system governed by Duffing's equation

This paper deals with turbulent or chaotic phenomena which occur in the system governed by Duffing's equation, a special type of two-dimensional periodic system. By using analog and digital computers, experiments are carried out with special reference to the change of attractors and of average power spectra of the random processes under the variation of the system parameters. On the basis of the experimental results, an outline of the random process is made clear. The results obtained in this paper will be applied to various physical problems and will also serve as material for the development of a proper mathematics of this phenomenon.     

应用于地形匹配导航的激光高度计设计

为解决基于雷达高度表探测的地形匹配导航系统探测精度不高、易受电子干扰影响而失效、且在跨海飞行时无法导航的难题,设计了一种激光高度计来代替雷达高度表进行地形探测。采用二极管泵浦固体激光器技术设计激光发射装置,输出近红外/蓝绿双波长激光,既可以测量陆地地形高度,又可以穿透海水探测海底地形;并根据激光高度计拟达到的性能指标选择合适的光电探测器,优化设计了光学系统、扫描系统和信号处理系统。所设计的激光高度计具有体积小、重量轻、高重频、探测灵敏度高、抗电磁干扰能力强等特点。     

电场极化方向对自由空间电场测量的影响

介绍了自主研制的脉冲电场原始波形测量系统的模块组成与基本工作原理。针对在未知被测电场方向及复杂的电场环境下垂直干扰电场对自由空间电场测量产生的影响,通过建立自由空间电场测量系统前端的简化模型,对不同尺寸天线与屏蔽盒进行仿真计算。仿真计算结果与理论分析基本一致,结果表明：干扰电场响应信号与待测电场响应信号相差2个数量级以上,干扰电场的影响可忽略不计。     

Preparation and characterization of Cu (II) supported on poly(8‐hydroxyquinoline‐p‐styrene sulphonate) and its application as catalyst for the synthesis of hexahydroquinolines

Cu ( II ) supported on poly(8‐hydroxyquinoline‐p‐styrenesulfonate) (Cu ( II )@PHQSS) was prepared and fully characterized by the different techniques including fourier transform infrared spectroscopy (FT‐IR), ¹H NMR, ¹³C NMR, thermal gravimetric analysis (TGA), differential thermal gravimetric (DTG), differential thermal analysis (DTA), scanning electron microscope (SEM) and energy dispersive X‐ray analysis (EDS). Afterward, the Cu ( II )@PHQSS as nanostructured catalyst was used as catalyst for the synthesis of hexahydroquinolines.