全文获取类型
收费全文 | 8452篇 |
免费 | 1680篇 |
国内免费 | 1063篇 |
专业分类
化学 | 6398篇 |
晶体学 | 130篇 |
力学 | 504篇 |
综合类 | 74篇 |
数学 | 475篇 |
物理学 | 3614篇 |
出版年
2024年 | 31篇 |
2023年 | 122篇 |
2022年 | 307篇 |
2021年 | 418篇 |
2020年 | 560篇 |
2019年 | 372篇 |
2018年 | 327篇 |
2017年 | 292篇 |
2016年 | 447篇 |
2015年 | 391篇 |
2014年 | 457篇 |
2013年 | 746篇 |
2012年 | 510篇 |
2011年 | 567篇 |
2010年 | 401篇 |
2009年 | 478篇 |
2008年 | 509篇 |
2007年 | 544篇 |
2006年 | 500篇 |
2005年 | 402篇 |
2004年 | 334篇 |
2003年 | 353篇 |
2002年 | 252篇 |
2001年 | 198篇 |
2000年 | 221篇 |
1999年 | 160篇 |
1998年 | 169篇 |
1997年 | 135篇 |
1996年 | 147篇 |
1995年 | 126篇 |
1994年 | 115篇 |
1993年 | 98篇 |
1992年 | 96篇 |
1991年 | 62篇 |
1990年 | 66篇 |
1989年 | 47篇 |
1988年 | 41篇 |
1987年 | 30篇 |
1986年 | 31篇 |
1985年 | 20篇 |
1984年 | 14篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 7篇 |
1979年 | 14篇 |
1978年 | 9篇 |
1975年 | 6篇 |
1974年 | 11篇 |
1973年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
针对VO2薄膜在微测辐射热计上的应用,采用射频反应溅射法,在室温下制备氧化钒薄膜;研究了氧分压对薄膜沉积速率、电学性质及成分的影响.通过调节氧分压,先获得成分接近VO2的非晶化薄膜,再在400℃空气中氧化退火,便可制得高电阻温度系数,低电阻率的VO2薄膜,电阻温度系数约为-4%/℃,薄膜方块电阻为R□为100—300kΩ;薄膜在室温下沉积,400℃下退火的制备方法与微机电加工(micro electromechanic
关键词:
二氧化钒
电阻温度系数
氧分压
射频反应溅射法 相似文献
12.
C M Srivastava 《Pramana》1989,32(3):251-267
A theory of high temperature superconductivity in YBa2Cu3O7_δ compound has been developed on the basis of the momentum pairing of electrons through the relativistic Darwin interaction.
The transport behaviour of electrons is explained in terms of a mechanism of correlated electron transfer arising from the
electron-phonon coupling. A model Hamiltonian has been developed to describe the superconducting properties of the system.
This gives an energy gap which is higher than the BCS value. Attempts have been made to explain the absence of isotope effect,
the linear dependence of specific heat, the presence of larger temperature-independent paramagnetism in the normal phase and
the softening of some of the optic phonon modes observed in this system. 相似文献
13.
A.N Bekrenev 《Journal of Physics and Chemistry of Solids》2002,63(9):1627-1631
An unusually high mobility of atoms under intensive impulse reactions is explained by the behavior of point defects at the shock wave front. It is shown that either a shock wave front or moving dislocations can capture the interstitials, or they can be thermally activated in the direction of the shock wave propagation. 相似文献
14.
15.
强流脉冲电子束在材料中的能量沉积剖面、能量沉积系数和束流传输系数受其入射角的影响很大,理论计算了0.5~2.0MeV的电子束以不同的入射角在Al材料中的能量沉积剖面和能量沉积系数,并且还计算了0.4~1.4MeV电子束以不同入射角穿透不同厚度C靶的束流传输系数。计算结果表明,随着入射角的增大,靶材表面层单位质量中沉积的能量增大,电子在靶材料中穿透深度减小,能量沉积系数减小,相应的束流传输系数也减小;能量为0.5~2.0MeV的电子束当入射角在60°~70°时在材料表面层单位质量中沉积的能量较大。 相似文献
16.
Results of two urgent and practically important directions of research on the indirect oxidation of organic compounds by highly reactive intermediates generated electrochemically from oxygen (HO2
–, HO2
·, HO·) are considered and orderly arranged. The studies in question are the indirect synthesis and mineralization of organic toxicants in waste water. 相似文献
17.
The transport of monodisperse as well as polydisperse colloid suspensions in a two-dimensional, water saturated fracture with spatially variable and anisotropic aperture is investigated with a particle tracking model. Both neutrally buoyant and dense colloid suspensions are considered. Although flow and transport in fractured subsurface formations have been studied extensively by numerous investigators, the transport of dense, polydisperse colloid suspensions in a fracture with spatially variable and anisotropic aperture has not been previously explored. Simulated snapshots and breakthrough curves of ensemble averages of several realizations of a log-normally distributed aperture field show that polydisperse colloids exhibit greater spreading than monodisperse colloids, and dense colloids show greater retardation than neutrally buoyant colloids. Moreover, it is demonstrated that aperture anisotropy oriented along the flow direction substantially increases colloid spreading; whereas, aperture anisotropy oriented transverse to the flow direction retards colloid movement. 相似文献
18.
19.
Ya. I. Kurys’ N. S. Netyaga V. G. Koshechko V. D. Pokhodenko 《Theoretical and Experimental Chemistry》2007,43(5):334-342
A guest-host nanocomposite based on electroconducting polyaniline doped with 12-phosphotungstic acid and V2O5 as well as its bifunctional analog containing not more than 5 mass% nanosized platinum were obtained. A study was carried
out on the structure of these nanocomposites, their redox characteristics, and electrocatalytic activity in the reduction
of oxygen. These nanocomposites were found to display catalytic properties in the electrochemical reduction of oxygen, while
the presence of even a slight amount of nanosized platinum in the bifunctional composite leads to a significant increase in
its electrocatalytic activity.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 5, pp. 307–314, September–October, 2007. 相似文献
20.
Mao‐Chuan Yuan Ping‐I Shih Chen‐Han Chien Ching‐Fong Shu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(14):2925-2937
We have synthesized a blue‐light‐emitting polyfluorene (PF) derivative ( PF‐CBZ‐OXD ) that presents bulky hole‐transporting carbazole and electron‐transporting oxadiazole pendent groups functionalized at the C‐9 positions of alternating fluorene units. The results from photoluminescence and electrochemical measurements indicate that both the side chains and the PF main chain retain their own electronic characteristics in the copolymer. An electroluminescent device incorporating this polymer as the emitting layer was turned on at 4.5 V; it exhibited a stable blue emission with a maximum external quantum efficiency of 1.1%. Moreover, we doped PF‐CBZ‐OXD and its analogue PF‐TPA‐OXD with a red‐light‐emitting iridium phosphor for use as components of phosphorescent red‐light emitters to investigate the effect of the host's HOMO energy level on the degree of charge trapping and on the electrophosphorescent efficiency. We found that spectral overlap and individual energy level matching between the host and guest were both crucial features affecting the performance of the electroluminescence devices. Atomic force microscopy measurements indicated that the dipolar nature of PF‐CBZ‐OXD , in contrast to the general nonpolarity of polydialkylfluorenes, provided a stabilizing environment that allowed homogeneous dispersion of the polar iridium triplet dopant. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2925–2937, 2007 相似文献