液晶填充碲酸盐光子晶体光纤偏振旋转器

提出一种液晶填充碲酸盐玻璃的柚子型光子晶体光纤偏振旋转器,利用全矢量有限元法,对液晶填充碲酸盐玻璃的柚子型光子晶体光纤的偏振旋转特性进行数值模拟,并分析了光纤结构参数、环境温度、工作波长等对光纤偏振旋转特性的影响.研究结果表明:此种偏振旋转器具有较高的旋转效率、较低的工作串扰和较短的旋转长度,在工作波长为1.55μm、偏振角度为45°时,其值分别达到99.947%、-32.84dB和197μm;另外,随着光纤薄壁厚度的增加,旋转长度随之升高,随着工作波长的变大,旋转长度随之降低,随着温度的增加,旋转长度随之升高.这种新型的光子晶体光纤为偏振旋转器的研发提供了参考.     

Yb~(3+)和Er~(3+)共掺杂氟硼酸盐玻璃材料光学跃迁及红外到可见上转换

利用 J-O理论和吸收光谱实验数据计算了 Er3 +掺杂的氟硼酸盐玻璃材料的光学跃迁参数 ,从而得到了一些能级间跃迁的振子强度、跃迁几率、分支比、及寿命等数据。在室温下观察到了在 970 nm LD激发下红色和绿色上转换发光 ,讨论了红色上转换发光强度与 LD电流的关系。     

低熔点微晶封接玻璃的研究

系统地研究了Ｂ２Ｏ３－ＺｎＯ－ＰｂＯ－ＳｉＯ２系统玻璃的组成与性能，给出玻璃配方与其物化性能测试结果，并就晶核剂以及部分成分对低熔点微晶封接玻璃性能的影响进行了讨论，封接玻璃已广泛地用于微光像增强器，激光器，氙灯，湿敏电阻器等金属与金属，金属与玻璃，玻璃与玻璃，玻璃与陶瓷的封接。     

Er3+:Yb3+共掺杂氟氧混合物玻璃的上转换发光研究

制备了化学配方为 (5 0 -x)GeO2 ·PbF2 ·WO3·(6 +x)CdF2 ·1 4Yb2 O3·0 6Er2 O3(x =10 ,2 0 ,30 )氟氧混合物玻璃。研究了 930nm发光二极管激发下Er3+ :Yb3+ 共掺杂情形下的Er3+ 离子的上转换发光特性 ,观测到了Er3+ 离子中心波长位于 5 4 3,5 5 0和 6 5 5nm处的三个强荧光发射带。通过对样品的反斯托克斯喇曼光谱的测量 ,确定了基质的最大声子能量 ,在此基础上分析了上转换荧光的产生机制。利用基质的平均电负性差和平均阳离子场强这两个参数 ,讨论了基质材料中GeO2 和CdF2 含量的调整对上转换发光的影响。     

含Eu3+离子的Na2O-K2 O-SiO2-Al2O3系统玻璃的制备及其变温发射光谱与结构特性

通过高温熔融法制备了含Eu^3 离子的Na2O-K2O-SiO2-Al2O3系统玻璃。在488nm波长光的激发下，系统地研究了上述玻璃从77K到700K温度范围的变温发光特征。发现总的荧光强度首先随温度的升高而大幅度升高，然后随温度的升高而减少，用声子辅助吸收与热激活过程及温度淬灭效应定性地解释了上述强度的变化，同时测量与分析了Eu^3 离子的晶格场参量。结果表明，Eu^3 离子与氧离子的距离随着温度升高而变短，而Eu^3 离子的配位数不随温度而变化。     

Raman characterizations and structural properties of the binary TeO2?WO3, TeO2?CdF2 and ternary TeO2?CdF2?WO3 glasses

The Raman spectroscopy technique was used to characterize the microstructure and the crystallization properties of the as‐cast and heat‐treated binary TeO₂ WO₃, TeO₂ CdF₂ and ternary TeO₂ CdF₂ WO₃ glasses and glass ceramics. The results were compared with those obtained by using the X‐ray diffraction technique. The effect of the WO₃ and CdF₂ contents on the TeO₂ glass network and the intensity ratios of the deconvoluted Raman peaks were determined. The shifts in the Raman band wavenumbers and the intensity values for each band were investigated. The Raman results indicated that the glasses were mainly formed by the [TeO₄] and [TeO₃] units. The [TeO₄] units convert to [TeO₃] units with the addition of WO₃ and CdF₂ into tellurite glasses. All the crystalline phases such as α‐TeO₂, δ‐TeO₂ and γ‐TeO₂ existing in the TeO₂ WO₃, TeO₂ CdF₂ and TeO₂‐ WO₃ CdF₂ glasses were determined. The transformation of the metastable γ‐TeO₂ phase into stable α‐TeO₂ was observed for the (1 − x)TeO₂ xWO₃ (where x = 0.15, 0.20, 0.25), 0.90Te₂ 0.10CdF₂, the 0.85TeO₂ 0.10CdF₂ 0.05WO₃ and 0.80TeO₂ 0.10CdF₂ 0.10WO₃ glasses, and the transformation of the metastable δ‐TeO₂ phase into the stable α‐TeO₂ was also observed for the TeO₂ CdF₂ WO₃ glass system. In addition, an unidentified phase formation, labeled ε, was determined. Copyright © 2009 John Wiley & Sons, Ltd.     

Confirming the lattice contraction in CdSe nanocrystals grown in a glass matrix by Raman scattering

This work gives the evidence of the lattice contraction in CdSe nanocrystals (NCs) grown in a glass matrix. The CdSe NCs were investigated by atomic force microscopy (AFM), optical absorption (OA), and Raman spectroscopy. The average size of CdSe NCs can be estimated by AFM images. Using the OA spectra and the effective‐mass approximation, it was also possible to estimate the average sizes of CdSe NCs, which agree very well with the AFM data. These results showed that the CdSe NCs grow with increasing time of heat treatment. The blue shift of the longitudinal optical (LO) modes and surface optical (SO) phonon modes with an increase in the average radius of the NCs, shown in the Raman spectra, was explained by the lattice contraction in CdSe NCs caused by thermodynamic interactions at the interface with the host glass matrix. Copyright © 2010 John Wiley & Sons, Ltd.     

Fabrication of red-emitting CaAlSiN3: Eu2+ through phosphor-in-glass approach for application in rear combination lamp

In this study, the red-emitting phosphor-in-glass (PiG) using the CaAlSiN₃: Eu²⁺ (CASN) phosphor is reported for the first time. The CASN: Eu²⁺ PiG samples with a maximum luminous flux of 25.1–29.4 for l minute at laser power of 1 W/mm² was obtained using a low-temperature glass frit and GPS furnace. Despite the increase in the phosphor from 15 to 25 wt%, the PiG produced at low temperature of 380 °C showed robust properties. Finally, the red PiG module designed for rear lamp applications maintains over 90% lumens for a minute at 350 mA and achieves an intense red light having a color temperature of 4589 K.     

Structure and properties of soda lime silicate glass doped with rare earth

Soda-lime-silicate glasses doped with different rare-earth oxides (La₂O₃, CeO₂, Nd₂O₃, Gd₂O₃ and Y₂O₃) of 1 mol% content were prepared with the traditional melting-quenching methods. In order to reveal the effects of rare-earth elements on the behavior of soda-lime-silicate glass, the structure of soda-lime-silicate glasses doped with different rare-earth oxides were determined with Fourier transform infrared spectrometer using the KBr method, and viscosity of glass melts were measured by the rotating crucible viscometer, the melting temperature of the studied glasses were derived on the basis of Arrhenius Equation, moreover the density, bending strength and molar volume were measured and calculated. The effect of rare-earth dopants on the structure of soda-lime-silicate was analyzed by a shift of peak position and variation in the full-width at half-maximum. The effect of doping rare-earth oxides into glass on the viscosity, density and bending strength was interpreted by changing in structure of soda-lime-silicate glasses doped with rare-earth oxides.     

DC conductivity of new single and mixed alkali oxyfluorovanadate glasses

New glasses have been prepared according to these formulas (70-x)V₂O₅-30BaF₂-xAF, where AF=LiF or NaF and (60-x)V₂O₅-30BaF₂-10LiF-xAF, where AF=NaF and x=10, 15, 20, 25 and 30 mol%. Density of the glasses was measured and molar volume calculated and they correlated with the AF content. The dc conductivity has been measured in the temperature range from 302 to 453 K. The dc conductivity increases with temperature and V₂O₅ content, while it decreases with the alkali fluoride content. Conductivity has been correlated with the calculated polaron distance, R, and glass transition temperature, T_g. The activation energy, W, increases with the increase in the alkali fluoride, while it decreases with the V₂O₅ content. Some parameters like polaron distance, R, polaron radius, r_p, ion concentrations, n(V), n(Li) or n(Na), hopping energy, W_H, density of localized states at Fermi level, N(E_F), polaron coupling constant, γ_p, polaron band width, J, hopping mobility, μ, and carrier density for electronic conduction, N_c, were calculated to explain the conduction mechanism and behavior of the present glasses.