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991.
Martin Bender Steven Delvaux Arno B.J. Kuijlaars 《Journal of Approximation Theory》2011,163(11):1606-1637
We study multiple orthogonal polynomials of Meixner–Pollaczek type with respect to a symmetric system of two orthogonality measures. Our main result is that the limiting distribution of the zeros of these polynomials is one component of the solution to a constrained vector equilibrium problem. We also provide a Rodrigues formula and closed expressions for the recurrence coefficients. The proof of the main result follows from a connection with the eigenvalues of (locally) block Toeplitz matrices, for which we provide some general results of independent interest.The motivation for this paper is the study of a model in statistical mechanics, the so-called six-vertex model with domain wall boundary conditions, in a particular regime known as the free fermion line. We show how the multiple Meixner–Pollaczek polynomials arise in an inhomogeneous version of this model. 相似文献
992.
993.
The proper orthogonal decomposition (POD) is a model reduction technique for the simulation of physical processes governed by partial differential equations (e.g.,fluid flows). It has been successfully used in the reduced-order modeling of complex systems. In this paper, the applications of the POD method are extended, i.e., the POD method is applied to a classical finite difference (FD) scheme for the non-stationary Stokes equation with a real practical applied background. A reduced FD scheme is established with lower dimensions and sufficiently high accuracy, and the error estimates are provided between the reduced and the classical FD solutions. Some numerical examples illustrate that the numerical results are consistent with theoretical conclusions. Moreover, it is shown that the reduced FD scheme based on the POD method is feasible and efficient in solving the FD scheme for the non-stationary Stokes equation. 相似文献
994.
本文研究了一类单群的数量刻画问题.运用有限单群分类定理及群的元素阶的素图表示的结构定理,获得了有限群G同构于有限正交单群PΩ2n+1(q)(n≥13),当且仅当群的元素的阶的集合一致和群的Sylow子群的正规化子的阶之集合一致.在某种意义推进施武杰教授的一个猜想. 相似文献
995.
996.
Noguerol-Cal R López-Vilariño JM González-Rodríguez MV Barral-Losada L 《Talanta》2011,85(4):2080-2088
Capacity to migrate of a representative group of polymeric additives, dyes, antioxidants, hindered amine light stabilizers (HALS) or antistatics, from plastic toys to saliva was analyzed to protect children in their habits of sucking and biting. Most of target additives appear no-regulated in toys normative but adverse effects on human health of some of them have been demonstrated and their presence in others commercial articles normative has been included.In order to offer an effective and easy tool to perform these controls, migration tests by dynamic and static contact, followed by a preconcentration step by liquid-liquid extraction (LLE) and ultra performance liquid chromatographic analysis with ultraviolet-visible and evaporative light scattering detections (UPLC-UV/Vis-ELSD) have been optimized to evaluate the migrated amounts of the additives in saliva simulant. The detection limits of the migration methodologies were ranged from 8.68 × 10−2 to 1.30 × 10−3 mg migrated (L simulant)−1.Influence of several variables on this mass transport, as time, temperature and friction, was also analyzed to achieve the most aggressive methodology to protect consumers.Migration of several studied additives, whose presence has been demonstrated in several purchased commercial toys, has been observed. 相似文献
997.
998.
一般来说, 点群理论认为Möbius带环分子最高的对称性只能是C2. 本文讨论了由18个苯环组成的环并苯的异构体分子, 包括柱面的Hückel型分子(HC-[18])和扭转180°的Möbius带环分子(MC-[18]). 结果表明除了点对称性外, Möbius带环分子还存在一种可称为环面螺旋旋转(TSR)变换的对称性, 为此还引用了环面正交曲线坐标系. 此外, 还讨论了这些分子关于TSR对称性匹配的原子集和原子轨道(AO)集. 根据TSR对称性的循环群特征, 可以建立此类群的不可约表示及有关特征标. 这类分子的分子轨道(MO)关于TSR群的不可约表示是纯的, 然而所含的相应的原子轨道对称性匹配的线性组合(SALC-AO)成分可以是多种的. 相似文献
999.
Maiti M Siegmund V Abramov M Lescrinier E Rosemeyer H Froeyen M Ramaswamy A Ceulemans A Marx A Herdewijn P 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(3):869-879
Orthogonal nucleic acids are chemically modified nucleic acid polymers that are unable to transfer information with natural nucleic acids and thus can be used in synthetic biology to store and transfer genetic information independently. Recently, it was proposed that xylose-DNA (dXNA) can be considered to be a potential candidate for an orthogonal system. Herein, we present the structure in solution and conformational analysis of two self-complementary, fully modified dXNA oligonucleotides, as determined by CD and NMR spectroscopy. These studies are the initial experimental proof of the structural orthogonality of dXNAs. In aqueous solution, dXNA duplexes predominantly form a linear ladderlike (type-1) structure. This is the first example of a furanose nucleic acid that adopts a ladderlike structure. In the presence of salt, an equilibrium exists between two types of duplex form. The corresponding nucleoside triphosphates (dXNTPs) were synthesized and evaluated for their ability to be incorporated into a growing DNA chain by using several natural and mutant DNA polymerases. Despite the structural orthogonality of dXNA, DNA polymerase β mutant is able to incorporate the dXNTPs, showing DNA-dependent dXNA polymerase activity. 相似文献
1000.
综述了高分子合金相容剂的重要研究进展,包括相容剂体系和相容性表征的研究。目前新研制出的相容剂主要有PVDF—g—AAc—g~TPU、EAGMA、PP~g—MAH和PP_g—MAH—St;这些相容剂克服了高分子合金和高分子基复合材料热稳定性差的缺点,降低了共混物的加工温度,并提高了材料的强度和抗冲击性能。现代表征技术在检验相容剂增容效果和表征高分子合金相容性起到了很好的作用,利用转矩流变仪和DSC检验相容剂的作用基团、扫描电镜和透射电镜观测EMG增容后的MDPE/PA6和MDPE/PET的断口形貌和组分的平均粒径、偏光显微镜和WAXD表征交联LLDPE~PP/LLDPE/PP合金晶型和结晶行为。作者针对相容剂对合金性能影响的研究存在的争议与分歧,认为高分子合金相容剂向功能化和复合化发展。 相似文献