全文获取类型
收费全文 | 16219篇 |
免费 | 3160篇 |
国内免费 | 1773篇 |
专业分类
化学 | 14136篇 |
晶体学 | 852篇 |
力学 | 298篇 |
综合类 | 90篇 |
数学 | 389篇 |
物理学 | 5387篇 |
出版年
2024年 | 54篇 |
2023年 | 181篇 |
2022年 | 611篇 |
2021年 | 689篇 |
2020年 | 1090篇 |
2019年 | 791篇 |
2018年 | 670篇 |
2017年 | 660篇 |
2016年 | 1029篇 |
2015年 | 918篇 |
2014年 | 1018篇 |
2013年 | 1763篇 |
2012年 | 997篇 |
2011年 | 1004篇 |
2010年 | 829篇 |
2009年 | 880篇 |
2008年 | 794篇 |
2007年 | 864篇 |
2006年 | 755篇 |
2005年 | 658篇 |
2004年 | 607篇 |
2003年 | 568篇 |
2002年 | 1005篇 |
2001年 | 392篇 |
2000年 | 331篇 |
1999年 | 290篇 |
1998年 | 279篇 |
1997年 | 215篇 |
1996年 | 218篇 |
1995年 | 151篇 |
1994年 | 129篇 |
1993年 | 86篇 |
1992年 | 101篇 |
1991年 | 77篇 |
1990年 | 85篇 |
1989年 | 53篇 |
1988年 | 45篇 |
1987年 | 34篇 |
1986年 | 40篇 |
1985年 | 27篇 |
1984年 | 37篇 |
1983年 | 17篇 |
1982年 | 24篇 |
1981年 | 17篇 |
1980年 | 10篇 |
1979年 | 16篇 |
1978年 | 8篇 |
1977年 | 9篇 |
1975年 | 10篇 |
1973年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 453 毫秒
81.
V. A. Petrosyan 《Russian Chemical Bulletin》1995,44(8):1353-1364
The results of studies on electrosynthesis involving carb- and heteroanions generated by cathodic deprotonation of acids (CDA), carried out in the laboratory headed by the author, are surveyed. These studies resulted in the elaboration of efficient electrochemical versions of the known Michaelis-Becker, Wittig-Horner, and Perkin reactions; electrochemical analogs of homolytic aromatic substitution, alkylation, heterocyclization,etc. were developed. Based on CDA, convenient and promising methods for preparing variousN-, O-, P-, S-, andC-alkylated and arylated substances have been developed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1411–1422, August, 1995.The author is grateful to Professor V. A. Dorokhov, Professor V. P. Litvinov, and researchers from the laboratories of N. D. Zelinsky Institute of Organic Chemistry headed by them, who participated in joint studies.The work was carried out with financial support from the International Science Foundation (Grant No. MHYOO). 相似文献
82.
Milind V. Kulkarni Annamraju Kasi Viswanath R. Marimuthu Tanay Seth 《Journal of polymer science. Part A, Polymer chemistry》2004,42(8):2043-2049
Spectroscopic [UV–visible and Fourier transform IR (FTIR)] and thermal properties of chemically synthesized polyanilines are found to be affected by varying the protonation media (acetic, citric, oxalic, and tartaric acid). The optical spectra show the presence of a greater fraction of fully oxidized insulating pernigraniline phase in polyaniline doped with acetic acid. In contrast, the selectivity in the formation of the conducting phase is higher in oxalic acid as a protonic acid media. The FTIR spectra of these polymers reveal a higher ratio of the relative intensities of the quinoid to benzenoid ring modes in acetic acid doped polyaniline. Scanning electron micrographs revealed a sponge‐like structure derived from the aggregation of the small granules in acetic acid and oxalic acid doped polyaniline. A three‐step decomposition pattern is observed in all the polymers, regardless of the protonic acid used for the doping. The second step loss related to the loss of dopant is found to be higher in the oxalic acid doped polymer. In accordance with these results the conductivity is also found to be higher in oxalic acid doped material. The temperature dependent conductivity measurements show the thermal activated behavior in all the polymers. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2043–2049, 2004 相似文献
83.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
84.
85.
Ottokar Leminger 《Optical and Quantum Electronics》2002,34(5-6):435-443
Photonic crystals exhibit band gaps, meaning that electromagnetic fields cannot propagate in them for specific ranges of wavelengths
and directions. The calculation of band structure diagrams has been intensively studied and is now well understood. In contrast
to that, so-called wave-vector diagrams (i.e. dispersion surfaces, depicting the loci of all relevant wave vectors at a fixed
wavelength) are less known and used. In principle, they show how the effective index of the structure depends on the direction
of propagation. A method to calculate explicitly wave-vector diagrams for two-dimensional photonic crystals is derived which
leads finally to quadratic eigenvalue problems. Results for square and triangular lattices are presented and some applications
are discussed. 相似文献
86.
阐述了紫外无机非线性光学晶体分子工程学探索方法的基本特点,具体分析深紫外无机非线性光学晶体硼铍酸锶(SBBO)以氟硼铍酸钾(KBBF)为主要参考晶体的分子设计方法,随后根据晶体结构研究、单晶培养、和非线性光学性能测定等实验结果讨论SBBO作为新型深紫外无机晶体的主要优点,即它既具有更短的紫外吸收边(接近155nm)和较大的非线性光学系数(d22(SBBO)=06×d22(BBO)=138pm/V),同时晶体无明显层状习性,并肯有良好的化学稳定性和机械性能 相似文献
87.
本文报道了一种测角单晶NMR探头。该探头采用单线圃双调谐电路,工作频率在90MHz-110 MHz连续可调,可进行交叉极化大功率去耦实验。文中提出了一种简单而有效的测角装置,可使单晶绕三个互相垂直轴转动实现单晶的NMR测量。作为典型的应用例子,本文利用该探头实现了单晶DGO(2NH2CH2COOH·H2C2O4)屏蔽张量的测量。 相似文献
88.
单晶光纤损耗谱测量装置 总被引:4,自引:1,他引:3
本文描述了一套用以测量单晶光纤损耗谱的装置。本装置由卤钨灯,单色仪,积分球,AgORbCs光电倍增管以及数据采集,处理和控制系统组成。可测量300~1150nm的光谱范围。利用本装置可获得单晶光纤的吸收光谱,透过率谱,散射光谱以及散射位置谱。 相似文献
89.
90.