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281.
V. E. Kirichenko E. P. Promyshlennikova K. I. Pashkevich 《Russian Chemical Bulletin》1994,43(5):812-815
The dependence of the variations in the differential molar free energy of sorption of polyfluorocarboxamides RFC(O)NR2 (RF = CF3(CF2)
i
,i=0 to 5, R=H or Me) on capillary columns on the molecular structure of the amides, the temperature of analysis, and the nature of the stationary phases (OV-101, XE-60, and PEG-40M) were investigated by GLC. The peculiarities of the variation of the sorption characteristics of amides in XE-60 and PEG-40M polar phases, which cause the inversion of the order of retention of the members of pseudohomologous series, were found.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 868–871, May, 1994.We are grateful to R. V. Golovnya and D. N. Grigor'eva (Institute of Food Substances of the RAS, Moscow) for their participation in the discussion of the results obtained. 相似文献
282.
V. P. Bubnov I. S. Krainskii E. E. Laukhina E. B. Yagubskii 《Russian Chemical Bulletin》1994,43(5):746-750
The effect of the parameters of the electric arc (helium pressure, current and voltage, clearance between electrodes) and of the peculiarities of the setup design (arrangement of electrodes, distance between the arc and the cooling surface, temperature of the soot condensation surface) on the yield of fullerenes has been studied. Conditions for producing soot with a C60 and C70 content up to 43% (toluene extract) have been found.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 805–809, May, 1994.The authors are grateful to N. G. Spitsyna and A. V. Dubovitskii for the determination of the content of C60 and C70 fullerenes in the extract.The work was financially supported by the Russian Foundation for Basic Research (Project 93-03-18705). 相似文献
283.
Sokolova T. N. Grishin Yu. K. Timofeev I. V. Kartashov V. R. 《Russian Chemical Bulletin》1994,43(6):1044-1047
Regiochemistry and stereochemistry of the addition of mercury salts to benzobarrelene and tetrafluorobenzobarrelene have been studied in acetic acid and methanol. The effect of the substrate structure on the regiochemistry of the reaction is discussed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1105–1108, June, 1994. 相似文献
284.
E. F. Kvashina 《Russian Chemical Bulletin》1994,43(12):2121-2121
The interaction of ditoluenetitanium with CO{in2} has been studied. Based on hydrolysis, thermolysis, and IR spectral data, the conclusion is drawn that a low-valent titanium oxalate is formed.This study was financially supported by the Russian Foundation for Basic Research (Project No. 93-03-5538).Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2241–2242, December, 1994. 相似文献
285.
286.
D.P. Woodruff 《Surface science》2002,500(1-3):147-171
The range of surface structural problems of interest in understanding the physics and chemistry of solid surfaces is reviewed with reference to the available methods and their strengths and limitations. Key challenges being addressed currently concern the achievable precision of measurements and their physical and chemical significance, and the complexity of the problems which may be solved. Past progress and future problems are illustrated with a series of examples ranging from the relaxation of simple clean metal surfaces through complex semiconductor reconstructions to large molecular adsorption and coadsorption systems and complex adsorbate-induced reconstructions. The strengths and limitations of scanning tunnelling microscopy as a complement to true quantitative structural methods are discussed, as is the role of chemical state specificity and elemental specificity in solving complex molecular adsorbate systems. 相似文献
287.
Experiments employing photoreflectance spectroscopy have uncovered band bending due to electrically active defects at the Si(1 1 1)–SiO2 interface after sub-keV Ar+ ion bombardment. The band bending of about 0.5 eV resembles that for Si(1 0 0)–SiO2, and both interfaces exhibit two kinetic regimes for the evolution of band bending upon annealing due to defects healing. The healing takes place about an order of magnitude more quickly at the (1 1 1) interface, however, probably because of less fully saturated bonding and higher compressive stress. 相似文献
288.
Koichi Itoh Takeji Takui 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(2):29
This review paper deals with an overview of molecule-based magnetism as a rapidly developing interdisciplinary field, topological symmetry rule as the first principle of spin alignment in organic open-shell systems in the ground state, the proposal of organic through-bond 1D and 2D ferro- and superparamagnets and the detection of the first organic high-spin molecule, m-phenylenebis(phenylmethylene) in the quintet ground state (S = 2), followed by extended organic high-spin systems with π-conjugation such as aromatic hydrocarbons having S = 3, 4, 5. The paper also describes a theoretical approach to the understanding of electronic spin structures of organic high-spin molecules by invoking both Heisenberg and Hubbard model Hamiltonians, weakly interacting intramolecular high-spin systems from both experimental and theoretical sides, the spin density distribution of the first organic high-spin molecule in terms of electron- nuclear multiple resonance spectroscopy and the detection and characterization of ionic high-spin hydrocarbons, emphasizing the establishment of high spin chemistry underlying organic molecular magnetism. 相似文献
289.
H. Kuramochi J. Okabayashi F. Takano M. Mizuguchi T. Manago H. Akinaga 《Surface science》2004,550(1-3):192-198
Strong magnetic poles at characteristic rectangular defects have been observed using a magnetic force microscope on a MnAs(
1 0 0) thin film with the thickness of 30 nm. The MnAs thin film was epitaxially grown on a GaAs(0 0 1) substrate. The magnetic poles were in one-arranging direction, being independent of the magnetization direction of the film. The poles were pinned at the edges of the rectangular defects until just below the Curie temperature, and formed a stable magnetic-field loop on the MnAs surface. The stability of the magnetic pole pinning shows the distinctive feature of the magnetic domain structure on the surface with a strong anisotropy, which was built in the heterostructure of MnAs and GaAs. 相似文献
290.
Ajay K. Saini Clifford M. Carlin Howard H. Patterson 《Journal of polymer science. Part A, Polymer chemistry》1992,30(3):419-427
New model compounds for poly[N,N′-bis(phenoxyphenyl)pyromellitimide] have been synthesized in order to investigate the formation of imine bonds which are proposed to form during the curing process and lead to crosslinking in the bulk polymer. Raman studies show that terminal amines can react with imide carbonyls during curing to form C?N bonds. The Raman band due to C?N appears at 1656 cm?1 and the band due to C?O closest to the imine bond is observed at 1742 cm?1. These results are in agreement with previously published results on vapor deposited polyimide films. 相似文献