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101.
Q. Zhong L. He T. E. Beesley W. S. Trahanovsky P. Sun C. Wang D. W. Armstrong 《Chromatographia》2006,64(3-4):147-155
The comparisons of five different chiral stationary phases (CSPs) based on 2,6-dinitro-4-trifluoromethylphenyl (DNP-TFM) ether substituted β-cyclodextrin are presented. The five CSPs differ from each other in the linkage/spacer chemistry, or on the position of the substituents on β-cyclodextrin, or in the sequence of the synthetic procedure. The results show that there are two optimum combinations: (1) DNP-TFM randomly substituted on the β-cyclodextrin as the chiral selector along with a carbamate linkage chain bonding it to the silica support; and (2) β-cyclodextrin derivatized by DNP-TFM substituents only on the C-2 and C-3 positions of the cyclodextrin with an ether linkage chain anchoring it to the silica gel. These two combinations show complementary separations for some enantiomers. The spacer chain effect is much more pronounced for the CSP based on the β-cyclodextrin derivatives with DNP-TFM substituents only on C-2 and C-3 positions than its randomly substituted counterpart. The sequence of derivatizing the cyclodextrin and attaching it to silica gel also affects its selectivity and efficiency. The β-cyclodextrin should be derivatized before it is linked to the silica gel. 相似文献
102.
The first part of the paper deals with a critical discussion of the methodical basis of essential work of fracture (EWF) concept with respect to the specimen geometry (especially the notch depth) and application to polymers. In the second part, an in situ testing device, which combines a tensile testing machine with an optical strain-field measuring system, has successfully demonstrated possibility of characterization of fracture behaviour of polystyrene-polybutadiene block copolymers and block copolymer/homopolymer blends as examples of nanostructured polymer materials. It has been shown that knowledge of the time evolution of the strain field close to the crack tips leads to a simple verification of the basic precondition for the applicability of the EWF concept, the precondition “plastic zone coalescence-before-stable crack propagation”. 相似文献
103.
含间苯基聚芳醚酮的合成与性能研究 总被引:3,自引:0,他引:3
含间苯基聚芳醚酮的合成与性能研究林权,张万金,吴忠文,尹玖梅(吉林大学化学系,长春,130021)(中国科学院长春应用化学研究所)关键词聚芳醚酮,间苯基,熔点,结晶度聚芳醚酮作为一类耐高温特种工程塑料,由于具有优异的热、电、机械性能,已被广泛应用于电... 相似文献
104.
Frank R. Fronczek Richard D. Gandour Laura M. B. Gehrig Lyman R. Caswell Karen A. McDowell I. Alam 《Journal of inclusion phenomena and macrocyclic chemistry》1987,5(3):379-383
The first crystal structure of a potassium cation complex with dicyclohexano-18-crown-6 is reported. The potassium 2-nitrophenoxide complex ofsyn-cis-syn dicyclohexano-18-crown-6 crystallizes in the triclinic space group P
with cell constantsa=8.604(2),b=10.772(4),C=16.123(5)Å, =73.86(3)°,=77.61(3)°, =82.68(3)° andZ=2 forD
c
=1.31 g cm–3. Least-squares refinement based on 2742 observed reflections led to a final conventionalR value of 0.040. Dicyclohexano-18-crown-6 has the shape of a saddle with the potassium cation sitting at the saddlepoint. The structure of the 2-nitrophenoxide anion is dominanted by the quinoid resonance contributor. Because the complex is devoid of significant intercomplex interactions, it is a prototypical 1:1:1 complex.
Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82043 (26 pages).Now Mrs. K. M. Balo. 相似文献
105.
共沉淀浸渍法制备由合成气直接合成二甲醚的Cu-Mn催化剂 总被引:9,自引:4,他引:9
采用共沉淀浸渍法,制备了直接合成二甲醚的Cu-Mn-Zn催化剂,通过对组成成分及其配比的研究,发现Cu含量一定的条件下,n(Zn)/n(Mn)摩尔比对催化剂性能有较大的影响,当n(Zn)/n(Mn)=1/3~1/2时,催化剂对CO的转化率和对二甲醚的选择性达到最佳,分别为53.6%和63.5%;如锰添加比例过大,对催化剂催化合成二甲醚有微弱抑制;添加锌比例过大,会大大降低CO的转化率。载体Y分子筛的含量对催化剂性能也有影响,用量过大将降低催化剂的活性和对二甲醚的选择性,当其含量为33%时,催化剂上CO转化率和选择性可分别达到66%和68%,且催化剂活性随分子筛含量减少不再有明显的变化。 相似文献
106.
脂肪族胺、醇和醚的气相质子亲合能(PA)与N, O原子所带电荷(qx)以及烷基的极化效应指数(PEI)的关系可表示为其中a、b、c为系数。回归分析结果表明, 上式较好地表达了脂肪族胺、醇和醚的气相碱性变化规律。 相似文献
107.
Reed M. Izatt Gypzy C. Lindh Peter Huszthy Glen A. Clark R. L. Bruening Jerald S. Bradshaw James J. Christensen 《Journal of inclusion phenomena and macrocyclic chemistry》1989,7(5):501-509
The macrocycle-mediated fluxes of alkali, alkaline earth, and several transition metal cations have been determined and compared in a H2O-CH2Cl2-H2O liquid membrane system using four water-insoluble macrocycles containing a dialkylhydrogenphosphate moiety. Transport of alkali metal cations by these ligands was greatest from a source phase pH = 12 or above into an acid receiving phase (pH = 1.5). Very low fluxes were observed for the transport of the alkaline earth cations and all transition metal ions studied except Ag+ and Pb2+ which were transported reasonably well by these new macrocycles.Deceased: September 5, 1987. 相似文献
108.
The apparent molal volumes and compressibilities of NaCl, KCl, and CsCl in mixtures of 18-Crown-6 and water have been calculated from density and speed-of-sound measurements at 25°C. The partial molal volumes and compressibilities of the salts when all cations have formed complexes with 18-Crown-6 molecules have been evaluated. The sign and magnitude of the volume and compressibility changes of complex formation strongly suggest that the charge of the cation becomes very effectively screened by the crown ether. 相似文献
109.
含甲硫基和肟醚基的N-甲氧基氨基甲酸酯类化合物的合成及生物活性研究 总被引:3,自引:0,他引:3
为了寻找高效、低毒的农药, 设计合成了一系列新的含甲硫基和肟醚基的N-甲氧基氨基甲酸酯类化合物5a~5q, 其结构经IR, 1H NMR, LC/MS和元素分析确认. 生物活性测定表明, 部分化合物在50 mg/L下对稻瘟病菌(Pyricularia oryzae)、灰霉病菌(Botrytis cinerea)、水稻纹枯病菌(Rhizoctonia solani)和小麦白粉病菌(Blumeria griminis)有很好的抑菌活性. 相似文献
110.
Jerry L. Atwood Hosny Elgamal Gregory H. Robinson Simon G. Bott James A. Weeks William E. Hunter 《Journal of inclusion phenomena and macrocyclic chemistry》1984,2(1-2):367-376
In contrast to aluminum alkyls, alkyl aluminum halides such as EtAlCl2 react with crown ethers to form cation-anion pairs which exhibit the liquid clathrate effect. Specifically, [12-C-4·AlCl2][AlCl3Et] and [18-C-6·AlCl2][AlCl3Et] have been isolated and characterized by X-ray diffraction techniques. The cations show aluminum in an octahedral environment made up of four of the oxygen atoms from the crown and two chlorine atoms. The 12-C-4 derivative crystallizes in the monoclinic space group P21/c with cell constants of a=7.497(4), b=22.121(8), c=12.339(5) Å, =94.99(3)o, and Z=4 for =1.43 g cm–3. Least-squares refinement based on 1413 observed reflections led to a final conventional R value of 0.093. The 18-C-6 complex belongs to the triclinic space group P1 with a=8.414(4), b=12.193(6), c=12.394(6) Å, =73.14(4), =86.07(4), =81.52(4)o, and Z=2 for =1.45 g cm–3. Refinement based on 2605 observed reflections led to R=0.063. The complex aluminum-containing species are related to a class of compounds called aluminoxanes. 相似文献