全文获取类型
收费全文 | 2406篇 |
免费 | 274篇 |
国内免费 | 99篇 |
专业分类
化学 | 1481篇 |
晶体学 | 5篇 |
力学 | 175篇 |
综合类 | 46篇 |
数学 | 248篇 |
物理学 | 824篇 |
出版年
2024年 | 5篇 |
2023年 | 43篇 |
2022年 | 143篇 |
2021年 | 126篇 |
2020年 | 111篇 |
2019年 | 81篇 |
2018年 | 80篇 |
2017年 | 165篇 |
2016年 | 178篇 |
2015年 | 153篇 |
2014年 | 154篇 |
2013年 | 184篇 |
2012年 | 128篇 |
2011年 | 136篇 |
2010年 | 115篇 |
2009年 | 101篇 |
2008年 | 118篇 |
2007年 | 115篇 |
2006年 | 129篇 |
2005年 | 75篇 |
2004年 | 93篇 |
2003年 | 61篇 |
2002年 | 42篇 |
2001年 | 33篇 |
2000年 | 29篇 |
1999年 | 31篇 |
1998年 | 19篇 |
1997年 | 22篇 |
1996年 | 18篇 |
1995年 | 12篇 |
1994年 | 13篇 |
1993年 | 10篇 |
1992年 | 5篇 |
1991年 | 10篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 7篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 5篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1971年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有2779条查询结果,搜索用时 15 毫秒
1.
Mariusz Marć Marek Tobiszewski Bożena Zabiegała Miguel de la Guardia Jacek Namieśnik 《Analytica chimica acta》2015
This review summarizes the different tools and concepts that are commonly applied in air quality monitoring. The monitoring of atmosphere is extremely important as the air quality is an important problem for large communities. Main requirements for analytical devices used for monitoring include a long period of autonomic operation and portability. These instruments, however, are often characterized by poor analytical performance. Monitoring networks are the most common tools used for monitoring, so large-scale monitoring programmes are summarized here. Biomonitoring, as a cheap and convenient alternative to traditional sample collection, is becoming more and more popular, although its main drawback is the lack of standard procedures. Telemonitoring is another approach to air monitoring, which offers some interesting opportunities, such as ease of coverage of large or remote areas, constituting a complementary approach to traditional strategies; however, it requires huge costs. 相似文献
2.
Technical advances in the development of field-deployable capillary and microchip electrophoretic instruments and reports of their deployment between 2013 and 2017 were reviewed. Strategies and considerations in the design of the injection, separation and detection hardware, chemistry and associated infrastructure were discussed from an in-field perspective, with portability, robustness and automation/“ease of use” featuring as key requirements. Integration of functionality is important for adequate in-field performance. Progress was made towards the use of multiple channel devices for increased throughput and/or resolving power, mixing devices for on-line/in-line sample derivatization, battery operation and temperature control. The strengths and weaknesses of the various approaches described in the literature are discussed from the perspective of in-field operation. An overview of the applications of the field electrophoretic instruments is provided, including environmental science and planetary investigation. 相似文献
3.
A novel technique to overcome the long-term drift and hysteresis of a scanning Fabry–Perot filter was developed and applied to wavelength and power monitoring of DWDM system. By using the comb peaks generated by a temperature-stabilized, near threshold-biased Fabry–Perot diode laser as wavelength reference for the scanning Fabry–Perot filter, wavelength and power measurement accuracy of better than ±10 pm and 0.2 dB, respectively, were achieved. 相似文献
4.
激光诱导荧光探测水体中溶解有机物浓度 总被引:2,自引:2,他引:0
用Nd∶YAG激光器的三倍频355 nm光作为激发光源,根据激光诱导荧光(LIF)方法激发并探测污染水体的荧光光谱.通过对荧光光谱的分析处理研究归一化荧光强度,即450 nm处水中溶解有机物(DOM)峰与405 nm处水的拉曼峰的比值,反演溶解有机物浓度.用商品腐殖酸和去离子水配置成已知浓度的溶液代替标准DOM溶液进行标定,得到回归方程.结果证明,DOM的归一化荧光强度与水体中DOM浓度有较好的线性关系,因此LIF方法是对大面积水域水质进行动态遥测的较理想方法. 相似文献
5.
6.
为了准确计算出镀膜过程中每层膜的折射率,介绍了实时监控过程中确定膜层折射率的2种方法:一种是由实测的透射比光谱直接反算出膜层的折射率;另一种是用最小二乘法的优化算法实时拟合折射率。试验结果表明:在线反算适合单点监控,所得折射率误差小于2%。然而在实际镀膜过程中,由于宽带内膜层参数误差较大,一般大于25%。为此,采用最小二乘法拟合,即在整个宽光谱范围内采集每个波长点的信息,所得结果误差很小,一般都在2%~5%之间,有时可达到10%,在很大程度上提高了实际镀膜时膜厚监控的精度。 相似文献
7.
8.
9.
10.
N. Srinivasan R.C. Johnson N. Kasthurikrishnan P. Wong R.G. Cooks 《Analytica chimica acta》1997,350(3):128-271
An overview of membrane introduction mass spectrometry (MIMS) is presented and comparisons are made with other direct sample introduction techniques. Special attention is given to the unique advantages and the limitations of newer variants on the MIMS technique, including affinity MIMS, reverse-phase and trap MIMS. The salient features of the interfaces used in MIMS are summarized and the various membrane materials commonly used are delineated. The applicability of MIMS is illustrated via discussion of
- 1. (i) bioreactor monitoring (represented by yeast fermentation),
- 2. (ii) environmental monitoring (illustrated by analysis of contaminated ground water samples) and
- 3. (iii) on-line chemical reaction monitoring (exemplified by the photolysis of aryl esters).