分离扇回旋加速器的等时场在线优化

针对兰州重离子加速器冷却储存环（HIRFL-CSR）的分离扇回旋加速器（SSC）的等时场优化问题,依托HIRFL-CSR的主数据库系统Oracle,设计了系统控制界面,该界面不仅能够读取和给定电源电流值,而且能够实时更新束流相位信息。根据束流相位的实时数据,利用Kb-Kr方法以及Lagrange插值算法建立的等时场,实现了对SSC束流等时场的在线优化。优化后的等时场可以有效控制束流相位的漂移,提高束流品质。     

Amperometric Biosensor for Hypoxanthine Based on Immobilized Xanthine Oxidase on Iron (III) Meso‐tetraphenylporphyrin Nanoparticles Modified Glassy Carbon Electrode

Abstract

The preparation and performance of hypoxanthine (Hx) electrochemical biosensor, which was based on iron (III) meso‐tetraphenylporphyrin (FeTPP) nanoparticles (NPs), is reported in this work. FeTPP NPs prepared by mixing solvent techniques with diameters ca. 25~45 nm and were used as a mediator. The XOD/FeTPPNP/GC electrode exhibited good amperometric signal for Hx. Based on the consumption of dissolved oxygen during the oxidation process of Hx catalyzed by the immobilized XOD, the biosensor could detect the concentration of Hx up to 0.34 mM with a detection limit of 1.0 µM. The usefulness of this biosensor for the analysis of real sample was also demonstrated by determining Hx in rat brain dialysate coupled with microdialysis.     

A Microbial Biosensor using Pseudomonas Putida Cells Immobilised in an Expanded Bed Reactor for the Online Monitoring of Phenolic Compounds

ABSTRACT

A cell based biosensor for phenolic substances has been developed. The set up is based on a flow injection system with an expanded bed column with immobilised Pseudomonas cells. The cells were immobilised on glass particles pretreated with poly (ethylene diamine). The system responds to a range of phenolic substances. Storage and operational stabilities are good. The expanded bed concept makes the system reliable also when treating samples with particulate matter.     

基于图像的磨粒在线监测系统关键技术研究

针对磨粒在线监测系统开发要求,对其中的关键技术进行了深入研究.构建了基于显微图像分析和微泵进样的磨粒在线监测系统,给出了图像检测子系统和微流控分析芯片的详细设计原理和方法;利用粗糙集理论对磨粒特征参数进行了优化;根据系统光路特点,对磨粒图像进行了基于彩色特征的转换,并通过与背景图像的差值处理来快速提取磨粒目标.最后,利用颗粒计数器和铁谱分析技术对系统性能进行了检验,结果表明本系统磨粒统计与识别准确率分别达到90%和95%,具有较高的检测精度,满足磨粒在线监测要求.     

在线固相萃取/液相色谱-线性离子阱质谱法同时检测生物样品中18种氨基甲酸酯类农药

建立了同时测定全血、尿液和肝组织等生物样品中18种氨基甲酸酯类农药的在线固相萃取/液相色谱-线性离子阱质谱(On-line SPE/LC-LIT/MS)分析方法。样品经乙腈处理,稀释和离心后直接进样。经Waters OasisHLB在线SPE柱富集纯化,以BETASIL C18柱为分析柱,甲醇-水(均含0.1%甲酸)为流动相进行梯度洗脱;使用电喷雾电离(ESI)正离子模式测定,扫描方式为选择反应监测(SRM)和连续反应监测(CRM)。18种农药在考察的质量浓度范围内线性关系良好(权重因子1/X),相关系数为0.994 3~0.999 4;在全血和尿液中的检出限为0.1~5 ng/m L,在肝组织中的检出限为0.1~5 ng/g;3个加标水平的回收率为90.2%~114.5%,相对标准偏差(n=4)为0.5%~7.5%。该方法简单准确,灵敏度高,能够满足生物样品中18种氨基甲酸酯类农药的快速分析要求。     

Cobalt Determination by Means of Flow Injection On-line Sorbent Preconcentration-Flame Atomic Absorption Spectrometry with 1-Nitroso-2-naphthol as a Complexing Reagent

The suitability of 1-nitroso-2-naphthol(NN) as a complexing agent for on-line preconcentration of cobalt eluted on the C_(18) microcolumn by means of the FI-FAAS system was tested. Various parameters affecting the complex formation and its elution were optimized. A 2.3×10~(-3) mol/L reagent solution and the aqueous sample solution acidified with 0.1％ (volume fraction) nitric acid were on-line mixed (6.4 mL/min) on a reaction coil set at (65±1)℃ and flowed through the microcolumn for 30 s. The pH of the mixed solution was adjusted to 3—4 with HNO_3(1 mol/L) or NaOH(1 mol/L). The adsorbed complexes in the microcolumn were eluted into the nebulizer of FAAS in 10 s with ethanol acidified with 1％ HNO_3(3.0 mL/min). A good precision(1.6％ for 100μg/L Co(Ⅱ), n=10), a high enrichment factor 17.2, with detection limit (3σ) 3.2μg/L, and sample throughput (90 h~(-1)) were obtained. The method was applied to the certified reference materials(CRMs), NBS-362 and NBS-364, for the determination of cobalt and the results were in good agreement with the certified values.     

On-line Time Differential Perturbed Angular Correlation with Light Probe Nucleus 19F

An on-line time differential perturbed angular correlation technique has been developed with the light probe nucleus ¹⁹F. The first on-line TDPAC measurement was carried out to determine the field gradient in Cd and quadrupole moment of ¹⁹F (0.197 MeV: I ^π = 5/2⁺, T_1/2 = 89 ns). This revised version was published online in September 2006 with corrections to the Cover Date.     

Measurement of the Magnetic Moment of the First Excited State in 93Sr Using on-line TDPAC technique

The g-factor of the first excited state of ⁹³Sr (E = 213 keV, T _1/2 = 4.6 ns) was measured by an on-line TDPAC technique with use of the strong hyperfine field in Fe metal. The Larmor frequency ω _L = (2.60 ± 0.15) × 10⁸ rad/s was obtained. The g-factor is derived as g = −0.227 ± 0.013 from g = −ℏω _L/B _hf μ _N. If the spin of the first excited state of ⁹³Sr is assumed to be 3/2, the g-factor is predicted by a simple core-excitation model as g = −0.22, which is in good agreement with the present experimental result.     

一种用于同位素分离在线穆斯堡尔谱学的PPAC

研制了一种用于同位素分离在线穆斯堡尔谱学的平行板雪崩计数器，计数器仅重40g。用它测量由穆斯堡尔共振吸收后放出的内转换电子，采用85％^119Sn同位素增丰的SnO2作为阴极吸收材料，测得的穆斯堡尔谱的信噪比为11，是一种适合在线穆斯堡尔实验的计数器。对该计数器的性能进行了讨论。A Parallel Plate Avalanche Counter （PPAC） with weighted about 40 g was developed for isotope separator on-line Moessbauer Spectroscopy. It detects the internal conversion electrons emitted from the resonance Moessbauer nuclide. The signal-to-noise ratio of the spectra reaches 11 for 85% enriched ^119SnO2 cathode and absorber. It is an effective detector for on-line Moessbauer experiments. The perform ance of the counter was discussed in detail.     

A 2.79 COMPETITIVE ON-LINE ALGORITHM FOR TWO PROCESSOR REAL-TIME SYSTEMS WITH UNIFORM VALUE DENSITY

We consider the problem of competitive on-liae scheduling in two processor real-timesystems. In our model all tasks have common value density. Each task has a release time. an exe-cution time and a deadline. The scheduler is given no information about a task until it is released.And the value will be achieved if and only if the task is completed by its deadlirte. Moreover. wesuppose that migratbn is not allowed. The goal of the scheduler is to obtain as much value as pos-sible. In this paper we show that the competitive multipber of Safe-Risky-fixed Algorithm irt [4]is really 3 and presents a modified algorithm (Safe-Risky-unfixed Algorithm) that achieves a com-petitive mukiplier of 2. 79.