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81.
应用一种反映分子局部微环境描述子--原子电性相互作用矢量(vector of atomic electronegative interaction,AEIV)和原子杂化状态指数(Atomic Hybridation State Index, AHSI)对饱和脂肪酮类化合物的55种分子中的153个13C NMR谱建模模拟,应用多元线性回归方法得到定量结构波谱关系(QSSR)模型的复相关系数RMM=0.997, 标准偏差为SDMM=7.155. 采用留一法交互检验的结果是RCV=0.993,SDCV=10.195. 并随机抽出三部分分子进行检验,得到的相关系数分别是RMM1=0.996,RMM2=0.996,RMM3=0.999. 研究结果表明使用AEIV和AHSI所建模型预测能力是相当稳定的. 相似文献
82.
Soliton solution and interaction property for a coupled modified Korteweg-de Vries (mKdV) system 下载免费PDF全文
Hirota's bilinear direct method is applied to constructing soliton solutions to a special coupled modified Korteweg- de Vries (mKdV) system. Some physical properties such as the spatiotemporal evolution, waveform structure, interactive phenomena of solitons are discussed, especially in the two-soliton case. It is found that different interactive behaviours of solitary waves take place under different parameter conditions of overtaking collision in this system. It is verified that the elastic interaction phenomena exist in this (1+1)-dimensional integrable coupled model. 相似文献
83.
制备了表面带阴/阳离子的多孔二氧化硅纳米颗粒, 通过QCM-D研究了颗粒在不同pH值环境下与磷脂膜的非特异性吸附情况. 结果表明, NH2-MSN 在4–8的pH值范围内与磷脂膜相互吸引, 而COOH-MSN由于与磷脂膜的电性始终保持一致而无法发生吸附现象. 本研究能够帮助理解和预测纳米颗粒与细胞膜间的相互作用, 为药物输运提供载体, 有助于多孔二氧化硅纳米颗粒在药物输运体系中的应用.
关键词:
多孔二氧化硅纳米颗粒
磷脂膜
非特异性吸附
QCM-D 相似文献
84.
求出了高阶Hirota方程在可积条件下的一种精确呼吸子解,并基于此呼吸子解得到了Hirota方程的一种怪波解.在此怪波解的基础上研究了怪波的激发,发现对平面波进行周期性扰动可以激发怪波,对平面波进行高斯扰动可以更快地激发怪波,还可以直接在常数项上增加高斯扰动激发怪波.作为一个实例,采用分步傅里叶方法数值研究了在考虑自频移和拉曼增益时怪波的传输特性,自频移使怪波中心发生偏移,拉曼增益使得怪波分裂得更快,而且拉曼增益值越大怪波分裂得越快,但是拉曼增益对怪波的峰值强度没有明显影响.最后数值模拟了相邻怪波之间的相互作用特点,随着怪波之间距离的减小,怪波将合二为一,成为一束怪波,之后再分裂,并分析了拉曼增益和自频移对怪波相互作用的影响. 相似文献
85.
Deformed Hartree-Fock calculations are performed for some light nuclei in a large configuration space consisting of first
four major shells. The interaction employed is the modified Skyrme interaction in which the deformed density is replaced by
the band averaged scalar density that makes the Hamiltonian rotationally invariant rendering the spectroscopic calculations
feasible. It is shown that the introduction of density dependence spreads out the energy spectra and that the Skyrme variant
SIV which has a weak density dependence gives best overall agreement for energy spectra and the available data for the electromagnetic
properties of the nuclei studied. It is found that the maximum contribution to the energy of any state in the low lying spectrum
comes from thes-state attractive ands-state repulsive parts of the Skyrme interaction. It is also shown that when two-body density dependent version of Skyrme
interaction is used, the Koopmans theorem no longer holds. 相似文献
86.
Effects of Organic Acids on the Release of Fruity Esters in Water: An Insight at the Molecular Level
It is well known that organic acids (OAs) could affect the flavour of fruit juices and beverages. However, the molecular mechanism of aroma release is still unclear. In this study, the effects of citric acid (CA), L-(-)-malic acid (MA) and L-lactic acid (LA) on the release of six selected esters and their sensory perception were investigated by means of HS-GC-MS analyses and odour detection threshold determination, respectively. Meanwhile, the density functional theory (DFT) calculation was employed to explore the interaction modes between esters and OAs. HS-GC-MS analyses showed that the concentration and the type of OAs regulated the release of esters. The results were basically consistent with the detection threshold change of those esters. The DFT calculation suggested that the main intermolecular interaction was hydrogen bonds, and several esters could form a ternary ring structure with OAs through hydrogen bonds. The interactions can induce the different release behaviours of esters in OAs water solution. The number of carboxyl functional groups in OAs and the spatial conformation of esters appeared to influence the magnitude of the interaction. The above results demonstrated the mechanism of OAs affecting the release of esters and indicated a possible flavour control way by using different OAs and OA concentrations. 相似文献
87.
研究了存在内禀退相干时,对于不同的系统初态,具有DM相互作用和各向异性的三粒子XXZ海森伯模型的对纠缠动力学特性.得出了一些结论:系统的对纠缠度与各向异性参数?无关,但内禀退相干对系统的纠缠有明显的抑制作用;在内禀退相干存在时,若系统初态为纠缠态,选择合适的DM相互作用的参数,系统的对纠缠有一个非零的稳定值;系统初态为分离态时,系统的对纠缠会随时间震荡衰减,并且每次震荡会出现纠缠突然死亡现象,系统的对纠缠最终达到解纠缠状态.因此,选择合适的系统初态和DM相互作用参数可以有效地控制系统的对纠缠. 相似文献
88.
89.
Daniel Merino‐Garcia 《Journal of Dispersion Science and Technology》2013,34(3):339-347
A model, previously developed to determine the asphaltene precipitation onset, considered that asphaltene separation is ruled by the solvent quality of the surrounding media. Here, it is shown that it is equivalent to Flory‐Huggins model, when it is hypothesized that the asphaltene concentration is always in the instability range. With this, the controversy on the use of a concentration‐dependent model to describe a phenomenon that is practically independent of concentration is by‐passed. Moreover, improvements of the model are presented, together with sensitivity analysis with respect to its parameters. Two field case applications are reported, showing that the model gives a reasonable fit. 相似文献
90.