芳香烃中位取代氟硼二吡咯的薄膜放大自发辐射稳定性研究

对苯基、萘基和蒽基在中位取代的氟硼二吡咯(BODIPY)衍生物薄膜的放大自发辐射(ASE)性能进行了研究,探讨了影响材料ASE稳定性的因素。首先,将3种BODIPY衍生物材料PhBOD、NaBOD和EnBOD掺入聚苯乙烯经溶液旋涂法制备成薄膜,接下来测试了吸收光谱和荧光光谱,然后在光泵浦条件下测量了3种样品的ASE性能,获得了材料的ASE阈值。进一步通过长时间泵浦、环境中长时间放置和高温环境下泵浦等方法研究了材料的光稳定性、ASE环境稳定性和热稳定性。最后使用Gaussian 09计算了分子基态性质。实验结果表明,PhBOD、NaBOD和EnBOD薄膜的初始阈值分别为12.4,4.55,3.4 k W/cm~2,其中PhBOD有较强的ASE稳定性。ASE稳定性差异可能与分子结构的共轭程度和化学稳定性相关。分子中各个基团的共轭程度较大、Mulliken电荷分布对称性较好的材料具有较好的ASE稳定性。     

先进光刻胶材料的研究进展

本文简述了光刻技术及光刻胶的发展过程,并对应用于193纳米光刻和下一代EUV光刻的光刻胶材料的研究进展进行了综述,特别对文献中EUV光刻胶材料的研发进行了较为详细的介绍,以期对我国先进光刻胶的研发工作有所帮助.     

铋基掺铒光纤放大器中放大自发辐射处理研究

分别设计了一个带光隔离器和一个带光环形器的复合型宽带铋基掺铒光纤放大器(Bi-EDFA),理论上研究了Bi-EDFA中对于后向传输放大自发辐射(ASE)的处理对放大器性能的影响。研究表明,在C+L波段多波长信号同时输入情形下,通过在铋基掺铒光纤中插入一个光隔离器抑制后向传输的ASE,可以提高放大器各波长信号增益,降低噪声系数。利用一个光环形器引导后向传输的ASE去泵浦一段未抽运的低掺杂铋基掺铒光纤,可以显著地提高放大器长波段信号增益,而噪声系数只是略有增加,理论研究与报道的实验结果达到了比较好的一致。研究结果对于新型宽带Bi-EDFA的设计和应用具有一定实际指导意义。     

The Use of Single Drop Microextraction and Field Amplified Sample Injection for CZE Determination of Homocysteine Thiolactone in Urine

Two cheap, simple and reproducible methods for the electrophoretic determination of homocysteine thiolactone (HTL) in human urine have been developed and validated. The first method utilizes off-line single drop microextraction (SDME), whereas the second one uses off-line SDME in combination with field amplified sample injection (FASI). The off-line SDME protocol consists of the following steps: urine dilution with 0.2 mol/L, pH 8.2 phosphate buffer (1:2, v/v), chloroform addition, drop formation and extraction of HTL. The pre-concentration of HTL inside a separation capillary was performed by FASI. For sample separation, the 0.1 mol/L pH 4.75 phosphate buffer served as the background electrolyte, and HTL was detected at 240 nm. A standard fused-silica capillary (effective length 55.5 cm, 75 μm id) and a separation voltage of 21 kV (~99 μA) were used. Electrophoretic separation was completed within 7 min, whereas the LOD and LOQ for HTL were 0.04 and 0.1 μmol/L urine, respectively. The calibration curve in urine was linear in the range of 0.1–0.5 μmol/L, with R² = 0.9991. The relative standard deviation of the points of the calibration curve varied from 2.4% to 14.9%. The intra- and inter-day precision and recovery were 6.4–10.2% (average 6.0% and 6.7%) and 94.9–102.7% (average 99.7% and 99.5%), respectively. The analytical procedure was successfully applied to the analysis of spiked urine samples obtained from apparently healthy volunteers.     

MEH-PPV薄膜的放大自发发射特性

研究了MEH-PPV薄膜的放大自发发射特性。当激发强度增加时,从样品边缘发射的光谱发生增益窄化现象并具有明显的阈值特性。我们发现随着薄膜厚度的增加,MEH-PPV薄膜的阈值有所降低,而其增益系数则随之增加。在150nm厚时测得最大净增益系数为25.03cm^-1,最低阈值为2.2μJ/pulse。结果表明MEH-PPV是一种优良的激光和光放大材料。     

基于环形芯光纤的超低差分模式增益涡旋光纤放大器

提出了一种基于环形芯铒离子部分掺杂光纤的涡旋光纤放大器。针对该掺铒光纤的放大特性,研究了光纤长度、掺铒浓度与抽运功率对信号模式增益特性的影响。研究结果表明,该光纤放大器能够支持22个轨道角动量模式稳定传输,且C波段(1 530～1 565 nm)所有信号模式增益大于23 dB,信噪比高于27 dB,差分模式增益小于0.015 dB。所提出的基于环形芯光纤的涡旋光纤放大器具有支持轨道角动量模式数量多、差分模式增益低、信噪比高的优势,对于OAM复用长距离传输系统中的在线放大具有重要参考价值。     

大口径掺钛蓝宝石晶体放大的实验研究

分析了口径为80 mm的钛宝石晶体内的增益特性,对大口径钛宝石晶体中的泵浦光能量密度和泵浦光口径进行了优化设计。对于80 mm×17 mm的晶体,最佳工作光束口径为55 mm,泵浦能量为50 J;对于80 mm×30 mm的晶体,最佳工作光束口径为60 mm,泵浦能量为90 J,且其横向小信号增益远小于80 mm×17 mm晶体的。对影响大口径钛宝石晶体放大的横向放大自发辐射（ASE）和寄生振荡采用折射率匹配的包边技术进行了抑制。实验表明,该方法把允许横向增益从13提高到了2 100。实验系统为100 J绿光台面泵浦激光器,100 TW主放大器采用四程空间构型放大光路。80 mm×17 mm钛宝石晶体c轴水平放置,泵浦光和主激光均为水平偏振。当以泵浦光能量为49 J对主放大器进行双端泵浦,注入信号光能量为1.2 J,光束口径60 mm时,获得了14.2 J的放大光输出和286 TW的最高峰值功率。     

The role of polymers in random lasing

In this review article, we describe the basic principles of random laser operation with particular emphasis on π‐conjugated, dye‐doped and biologically inspired polymers. Random lasers are unusual types of lasers that use disorder in the light amplifying medium to provide positive feedback for laser operation. Organic systems like polymers are affected with disorder resulting both from their molecular structure and fabrication techniques. Due to this fact polymers seem to fit to role of random lasers and now are being extensively studied in this direction. Despite multiline and multidirectional operation polymeric random lasers have potential for several interesting applications. Here we show that they can be successfully applied to sensing in biology and medicine, encoding of information, display technology and search and rescue. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 951–974     

Quantifying the efficiency of förster‐assisted optical gain in semiconducting polymer blends by excitation wavelength selective amplified spontaneous emission

We study the correlation between Förster resonance energy transfer (FRET) and optical gain properties in conjugated polymer blends based on regioregular poly(3‐hexylthiophene) (P3HT) and poly(9,9‐dioctylfluorene‐alt‐benzothiadiazole) (F8BT). First, FRET dynamics are investigated with femtosecond transient absorption spectroscopy observing a sub‐picosecond energy transfer from F8BT to P3HT (550 fs) at medium doping levels (40% wt P3HT in F8BT). Amplified spontaneous emission (ASE) is then characterized in blends upon exciting predominantly the host and guest polymers, respectively. The corresponding density of absorbed photons at threshold conditions is compared upon host or guest photoexcitation as a method to quantitatively determine the FRET‐assisted ASE efficiencies. We observe a reduction in ASE efficiency upon host photoexcitation of 20%, in the best case, respect to guest photoexcitation. Our results confirm that even in strongly coupled host:guest mixtures delayed exciton population by energy transfer is subtle to losses ascribed to exciton–exciton annihilation. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 2311–2317.