全文获取类型
收费全文 | 2760篇 |
免费 | 233篇 |
国内免费 | 238篇 |
专业分类
化学 | 380篇 |
晶体学 | 13篇 |
力学 | 1391篇 |
综合类 | 38篇 |
数学 | 434篇 |
物理学 | 975篇 |
出版年
2024年 | 5篇 |
2023年 | 18篇 |
2022年 | 34篇 |
2021年 | 36篇 |
2020年 | 73篇 |
2019年 | 58篇 |
2018年 | 70篇 |
2017年 | 80篇 |
2016年 | 105篇 |
2015年 | 99篇 |
2014年 | 126篇 |
2013年 | 262篇 |
2012年 | 91篇 |
2011年 | 135篇 |
2010年 | 104篇 |
2009年 | 138篇 |
2008年 | 136篇 |
2007年 | 161篇 |
2006年 | 164篇 |
2005年 | 129篇 |
2004年 | 163篇 |
2003年 | 119篇 |
2002年 | 114篇 |
2001年 | 87篇 |
2000年 | 87篇 |
1999年 | 87篇 |
1998年 | 92篇 |
1997年 | 83篇 |
1996年 | 55篇 |
1995年 | 53篇 |
1994年 | 42篇 |
1993年 | 36篇 |
1992年 | 44篇 |
1991年 | 45篇 |
1990年 | 17篇 |
1989年 | 13篇 |
1988年 | 13篇 |
1987年 | 11篇 |
1986年 | 9篇 |
1985年 | 11篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1971年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有3231条查询结果,搜索用时 15 毫秒
61.
This work extends our previous understanding concerning the nonlinear responses of entangled polymer solutions and melts to large external deformation in both simple shear and uniaxial extension. Many similarities have recently been identified for both step strain and startup continuous deformation, including elastic yielding, i.e., chain disentanglement after cessation of shear or extension, and emergence of a yield point during startup deformation that involves a deformation rate in excess of the dominant molecular relaxation rate. At a sufficiently high constant Hencky rate, uniaxial extension of an entangled melt is known to produce window-glass-like rupture. The present study provides evidence against the speculation that chain entanglements tie up into "dead knots" in constant-rate extension because of the exponentially growing chain stretching with time. In particular, it is shown that even Instron-style tensile stretching, i.e., extending a specimen by applying a constant velocity on both ends, results in rupture. Yet, in the same rate range, the same entangled melt only yields in simple shear, and the resulting shear banding is clearly not a characteristic of rupture. Thus, we conclude that chain entanglements respond to simple shear in the manner of yielding whereas uniaxial extension is rather effective in causing some entanglements to lock up, making it impossible for the entanglement network to yield at high rates. 相似文献
62.
Elastic analysis of a functionally graded thick-walled cylindrical pressure vessel is analytically studied in the present research. Gradation is considered for all mechanical properties along the thickness direction based on a power function. The constitutive relations are developed in the general cylindrical coordinate system for an axisymmetric pressurized cylinder. For simulation of these two deformation components, first order shear deformation theory is considered. The FG cylinder is subjected to longitudinally non-uniform pressure along the length of the cylinder. The present problem is applicable for simulation of non-uniform pressurized cylinder by fluids or gases. 相似文献
63.
Nanoparticles usually exhibit pronounced anisotropic properties, and a close insight into the atomic-scale deformation mechanisms is of great interest. In present study, atomic simulations are conducted to analyse the compression of bcc nanoparticles, and orientation-dependent features are addressed. It is revealed that surface morphology under indenter predominantly governs the initial elastic response. The loading curve follows the flat punch contact model in [1 1 0] compression, while it obeys the Hertzian contact model in [1 1 1] and [0 0 1] compressions. In plastic deformation regime, full dislocation gliding is dominated in [1 1 0] compression, while deformation twinning is prominent in [1 1 1] compression, and these two mechanisms coexist in [0 0 1] compression. Such deformation mechanisms are distinct from those in bulk crystals under nanoindentation and nanopillars under compression, and the major differences are also illuminated. Our results provide an atomic perspective on the mechanical behaviours of bcc nanoparticles and are helpful for the design of nanoparticle-based components and systems. 相似文献
64.
《Journal of computational chemistry》2017,38(13):981-997
A novel approach for calculating deformation densities is presented, which enables to calculate the deformation density resulting from a change between two chemical states, typically conformers, without the need for radical fragments. The Fragment, Atom, Localized, Delocalized, and Interatomic (FALDI) charge density decomposition scheme is introduced, which is applicable to static electron densities (FALDI‐ED), conformational deformation densities (FALDI‐DD) as well as orthodox fragment‐based deformation densities. The formation of an intramolecular NH⋅⋅⋅N interaction in protonated ethylene diamine is used as a case study where the FALDI‐based conformational deformation densities (with atomic or fragment resolution) are compared with an orthodox EDA‐based approach. Atomic and fragment deformation densities revealed in real‐space details that (i) pointed at the origin of density changes associated with the intramolecular H‐bond formation and (ii) fully support the IUPAC H‐bond representation. The FALDI scheme is equally applicable to intra‐ and intermolecular interactions. © 2017 Wiley Periodicals, Inc. 相似文献
65.
The dynamic analysis of a generalized linear elastic body undergoing large rigid rotations is investigated. The generalized linear elastic body is described in kine-matics through translational and rot... 相似文献
66.
67.
68.
Sergio Conti Matteo Focardi Flaviana Iurlano 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2019,36(2):455-474
We consider the Griffith fracture model in two spatial dimensions, and prove existence of strong minimizers, with closed jump set and continuously differentiable deformation fields. One key ingredient, which is the object of the present paper, is a generalization to the vectorial situation of the decay estimate by De Giorgi, Carriero, and Leaci. This is based on replacing the coarea formula by a method to approximate functions with small jump set by Sobolev functions, and is restricted to two dimensions. The other two ingredients will appear in companion papers and consist respectively in regularity results for vectorial elliptic problems of the elasticity type and in a method to approximate in energy functions by ones. 相似文献
69.
We develop a variational optimization method for crystal analysis in atomic resolution images, which uses information from a 2D synchrosqueezed transform (SST) as input. The synchrosqueezed transform is applied to extract initial information from atomic crystal images: crystal defects, rotations and the gradient of elastic deformation. The deformation gradient estimate is then improved outside the identified defect region via a variational approach, to obtain more robust results agreeing better with the physical constraints. The variational model is optimized by a nonlinear projected conjugate gradient method. Both examples of images from computer simulations and imaging experiments are analyzed, with results demonstrating the effectiveness of the proposed method. 相似文献
70.
In this paper we are interested in developing constitutive equations for fiber-reinforced nonlinearly viscoelastic solids. It has been shown that constitutive equations for such bodies can be expressed in terms of a complete minimal set of 18 classical invariants associated with deformation and fiber orientation. In this paper, we give an alternative formulation using a set of spectral invariants. It is shown via the use of spectral invariants that only 11 of the 18 classical invariants are independent. We analyze the spectral invariants for two illustrative deformation gradients: (i) simple tension, and (ii) simple shear. 相似文献