Kinetics of the Complex of Terbium o-methylbenzoate with 1,10-Phenanthroline. Synthesis,decomposition mechanism

The complex of [Tb₂(o-MBA)₆(PHEN)₂] (o-MBA: o-methylbenzoate and PHEN:1,10-phenanthroline) were synthesized and characterized by elemental analysis and IR spectroscopy. The thermal behavior of [Tb₂(o-MBA)₆(PHEN)₂] in dynamic nitrogen atmosphere was investigated by TG-DTG techniques. The thermal decomposition process of the [Tb₂(o-MBA)₆(PHEN)₂] occurred in three consecutive stages at T_p 294, 427 and 512°C. The kinetic parameters and mechanisms of first decomposition stage from analysis of the TG-DTG curves were obtained by the Malek method. This revised version was published online in August 2006 with corrections to the Cover Date.     

乙烯-辛烯共聚物/淀粉共混体系的非等温结晶动力学

通过差示扫描量热仪(DSC)研究了乙烯-辛烯共聚物/淀粉共混体系的非等温结晶动力学,用Jeziorny和Ozawa方程描述了结晶动力学过程.共混物的结晶温度和结晶焓强烈依赖于淀粉含量和冷却速率.结果表明,随着冷却速率的增加,每个试样的结晶放热曲线均变宽,并向低温区移动.当温度一定高时,所有试样均具有较快的结晶速率. Jeniorzy方程可以较好地描述POE/淀粉共混物的非等温结晶模式,而Ozawa方程对于POE/淀粉共混体系不太适合.     

氨合氯化镁非等温热分解过程动力学研究

由有机溶剂法得到的中间产物氨合氯化镁[1]制备电解炼镁的无水氯化镁,煅烧过的程中的条件对无水氯化镁的纯度有较大的影响.     

一种研究聚合物非等温结晶动力学的方法

作者基于多年对聚合物结晶动力学方面研究的工作积累,联合Avrami方程和Ozawa方程,提出了一种研究聚合物非等温结晶动力学的新方法.该方法既克服了使用Ozawa方程所获得的数据点过少,常常出现非线性,不能获得可靠的动力学参数的缺点,又克服了使用经Jeziorny修正的Avrami方程所获得的表观Avrami指数无法准确预测非等温过程成核生长机理的缺点.该方法已成功用于多种聚合物体系,被国内外学者引用数百次,已成为研究聚合物非等温结晶动力学一种有效方法.     

多孔介质非等温渗流的(火用)传递分析研究

在求解非等温单相渗流的温度场、压力场基础上,以压(火用)为统一特征项,对电加热热驱模拟过程的驱动功、驱动功率、驱动阻力、驱油速率及其相互关系作了初步分析,揭示了热采过程非等温渗流的驱替机理:通过改变温度场、减小驱动(火用)阻力,以增强驱动效果、提高采收率.     

Nonisothermal thermogravimetry of polymers

The model of weight loss taking place in each step of a scheme of consecutive reactions was applied to nonisothermal thermogravimetric records of bromomethylated poly(2,6-dimethyl-1,4-phenylene oxide). The release of HBr was found to be faster in air than in nitrogen. A significant reduction in the apparent activation energy of dehydrobromination as compared with decomposition of the nonbrominated polymer was ascribed not only to a reduction in the activation energy of the initiation reaction, but also to an increase in the order of the termination reaction (from 1 for the nonbrominated polymer to 2 for the highly brominated polymer).     

The Thermal Decomposition of Fe(NO3)3·9H2O

Using thermogravimetric analyses as well as isothermal gravimetric measurements, the thermal stability of the iron(III) nitrate nanohydrate has been determined. Several decomposition stages are the result of melting, evaporation and hydrolysis processes occurring in the salt—water system in the temperature range of 20–400°C. Some of the intermediates and the final product (-Fe₂O₃) are characterized by means of chemical analyses, X-ray diffraction patterns and IR spectra.This revised version was published online in November 2005 with corrections to the Cover Date.     

High Accuracy Numerical Simulation of Non-Isothermal Viscoelastic Polymer Fluid Past a Cylinder北大核心CSCD

采用同位网格有限体积(coupled and linked equations algorithm revised,CLEAR)方法求解黏性和XPP (eXtended Pom-Pom)黏弹性流动的控制方程,基于延时修正方法构造了动量和本构方程对流项的高精度AVLsmart格式。首先,为了验证该文方法的有效性,对不同Reynolds数下不可压黏性流体圆柱绕流问题进行了模拟。随后,对等温及非等温不可压XPP黏弹性流体圆柱绕流问题进行了有效模拟,给出了速度矢量、应力分量、拉升量以及温度的分布规律,分析了We数对水平速度、法向应力及拉升量的影响。该文研究成果能为精确预测复杂型腔纤维增强黏弹性聚合物熔体动态充填过程提供理论基础。     

TG-DTA determination of water evolved from CaSO4·xH2O

To improve the separation of the dihydrate and hemihydrate phases, different sample masses, heating rates and crucibles were used. A TG-DTA method was developed for the determination of water evolved from CaSO₄·_xH₂O. The new crucible introduced for the Q-1500D MOM derivatograph gives a possibility for the evolved water to be determined independently from the TG and DTA curves.I am very grateful to Prof. Pelovski for the opportunity to use the Gypsum & Lime collection. This study was supported by the National Fund Science Research-Bulgaria.     

Synthesis, Characterization and Thermal Studies of Some Iron(III) Complexes of o-Vanillin Oxime

Iron(III) complexes of o-vanillin oxime have been synthesized and characterized by different physicochemical techniques. The complexes containing thiocyanate, iodide and sulphate ionshave been subjected to non-isothermal decomposition studies in N₂ using TGand DTG techniques. The kinetic parameters for both stages of decomposition of these complexes were evaluated by weighted least-squares method using the general approach as well as the Coats–Redfern and Horowitz–Metzger equations. The results indicate that the values of kinetic parameters obtained by these three different approaches agree well. This revised version was published online in July 2006 with corrections to the Cover Date.