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161.
A method for the quantification of clindamycin in animal plasma using high-performance liquid chromatography combined with electrospray ionization mass spectrometry (LC/ESI-MS/MS) is presented. Lincomycin is used as the internal standard. The sample preparation includes a simple deproteinization step with trichloroacetic acid. Chromatographic separation is achieved on an RP-18 Hypersil column using gradient elution with 0.01 M ammonium acetate and acetonitrile as mobile phase. Good linearity was observed in the range 0-10 microg ml(-1). The limit of quantification of the method is 50 ng ml(-1) and the limit of detection is 1.3 ng ml(-1). The method was shown out to be of use for pharmacokinetic studies of clindamycin formulations in dogs. 相似文献
162.
This paper proposes a quick, novel method for tin determination in organotin chemicals by slurry nebulization inductively coupled plasma atomic emission (ICP-AES) spectrometry. The method was tested by the measurement of five organotin carboxylate complexes of known composition for obtaining simple stoichiometric data. The slurries were prepared by first dissolving the organotins in an adequate solvent (methanol, pyridine or acetone) well miscible with water and then adding this solution drop-by-drop to a 0.005% TX-100 tenzide solution while maintaining intensive mixing. Dynamic laser light scattering experiments showed that the average equivalent particle size in the resulting slurry was ≈0.3 μm for all samples and solvents. Under suitable ICP-AES measuring conditions, the signal recoveries were found to be between 101.8 and 106.6%, which allowed direct nebulization and calibration against aqueous solutions. Typically, 70 μg l−1 detection limit and 1–5% relative S.D. on five replicates can be achieved by the described method. 相似文献
163.
Pulverized coal plasma gasification 总被引:11,自引:0,他引:11
R. A. Kalinenko A. P. Kuznetsov A. A. Levitsky V. E. Messerle Yu. A. Mirokhin L. S. Polak Z. B. Sakipov A. B. Ustimenko 《Plasma Chemistry and Plasma Processing》1993,13(1):141-167
A number of experiments on the plasma-vapor gasification of brown coals of three types have been carried out using an experimental plant with an electric-arc reactor of the combined type. On the basis of the material and heat balances, process parameters have been obtained: the degree of carbon gasification (c), the level of sulfur conversion into the gas phase (s), the synthesis gas concentration (CO+Hz) in the gaseous products, and the specific power consumption for the gasification process. The degree of gasification was 90.5-95.0%, the concentration of the synthesis gas amounted to 84.7–85.7%, and the level of sulfur conversion into the gas phase was 94.3–96.7%. Numerical study of the process of plasma gasification of coals was carried out using a mathematical model of motion, heating, and gasification of polydisperse coal particles in an electric-arc reactor of the combined type with an internal heat source (arc). The initial conditions for a conjugate system of nonlinear differential equations of the gas dynamics and kinetics of a pulverized coal stream interacting with the electric arc and oxidizer (water vapor) agree with the initial conditions of the experiments. The computation results satisfactorily correlate with the experimental data. The mathematical model can be used for the determination of reagent residence time and geometrical dimensions of the plasma reactor for the gasification of coals.Nomenclature
c
i
volume concentration of components (kmol m–3)
-
x
longitudinal coordinate (m)
-
f
i
source members, determined by variation of the ith component due to chemical reactions in unit volume in unit time (kmol m–3s–1)
-
velocity (m s–1)
-
M
s
ash mass in one particle (kg)
-
C
D
particle drag coefficient
-
3.14
-
r
s
particle radius (m)
-
d
particle diameter (m)
-
density (kg m–3)
-
C
p
heat capacity of components (J molt– K–1)
-
Q
j
thermal effect of reaction (J kmol–1)
- Ej
activation energy of reaction
-
N
l
volume concentration of particles of thelth fraction (m–3)
-
T
temperature (K)
-
emissivity factor of coal particles
-
5.67 × 10–8, blackbody emissivity coefficient (W m–2 K–4)
-
P
pressure (Pa)
-
S
reactor cross section (m2)
-
D
reactor diameter (m)
-
V
reactor volume (m3)
-
L
R
reactor length (m)
-
F
W
friction force on the wall (N)
-
f
g
friction coefficient
-
residence time (s)
- Nu
Nusselt number
- Re
Reynolds number
- Pr
Prandtl number
-
thermal conductivity of gas (J m– s–1 K–1)
-
R
8.3 × 103, universal gas constant (J kmol K–1)
- µ
i
molecular mass of component (kg kmol–1)
-
dynamic viscosity coefficient of gas (kg m–1 s–1)
-
thermal efficiency of plasma reactor
- qarc
specific heat flow from arc (W m–3)
-
P
1
heat supplied in vapor at T = 405 K (W)
-
P
2
heat loss to wall (W)
-
P
3
heat loss in the gas and slag separator chamber (W)
-
P
4
heat loss in the synthesis gas oxidation chamber (W)
-
P
5
heat loss in the slag catcher (W)
-
P
6
heat carried away in the off-gas (W)
- P
heat input of arc (W)
-
P
arc
electric power of arc (W)
- Qsp
specific power consumption (kw Hr kg–1)
-
d
w
specific heat flow to wall (W m–2)
-
c
degree of carbon gasification (%)
-
s
level of sulfur conversion into gas phase (%) 相似文献
164.
S. G. Hutchison C. M. Wai J. Dong R. J. Kearney 《Plasma Chemistry and Plasma Processing》1995,15(2):353-367
The feasibility of producing titanium metal from titanium tetrachloride in a thermal plasma under equilibrium and adiabatic expansion conditions has been theoretically investigated. Free energy minimization and adiabatic expansion calculations to simulate a nozzle expansion were used to study the practicality of production. The crucial requirements for the production of titanium powder from TiCl4 and H2 appear to be rapid quenching of the plasma gas at high temperature (e.g., 3700 K) and appropriate reactant concentrations. Quenching of tire plasma gas and production of titanium powder can be achieved by adiabatic expansion through a nozzle. Preliminary experimental data indicate that titanium powder of approximately 5 nm in size can be produced in an argon plasma rising a nozzle expansion approach. 相似文献
165.
An inductively coupled plasma atomic emission spectrometry (ICP-AES) procedure has been developed and examined for the determination of boron content (0.01 up to about 2% B) in boron-alloyed steels such as POLDI ATA BOR (65% Fe, 19%Cr, 12% Ni, 1.5% Mn, 1% B), POLDI ATA BOR EXTRA (62% Fe, 18% Cr, 13% Ni, 2.5% Mo, 1.5% Mn, 1% B) and POLDI ATA BOR-R (75% Fe, 18% Cr, 3.5% Ti, 1.8% B). The steel sample is dissolved with a mixture of hydrochloric, nitric, sulfuric and phosphoric acids in a quartz vessel. Borides of alloyed metals, especially of iron and chromium, are quantitatively decomposed. The presence of phosphoric acid in a sample solution reduces the volatility of boric acid with water vapour.Presented in part at the 1989 European Winter Conference on Plasma Spectrochemistry, Reutte, Austria 相似文献
166.
构造了氮-镍相互作用的5-参数Morse势,研究了氮原子在Ni(\r\n100),Ni(110)和Ni(111)平坦表面的吸附和振动,获得了氮原子\r\n在三个低指数表面的吸附位、吸附构型、结合能和本征振动等数据,计\r\n算结果与实验结果非常吻合.同时,与Ni(100)表面对比,系统研究\r\n了氮原子在Ni(510)台阶面的吸附和扩散.计算结果表明,氮原子在\r\n台阶下部形成最稳定的吸附态,台阶对下台面上扩散的氮原子形成捕获\r\n势,对上台面上扩散的氮原子形成反射势. 相似文献
167.
Effects of double substitution on the thermodynamic stabilities of nitrogen radicals 总被引:1,自引:0,他引:1
Studiesonkineticsofradicalreactions[1]andonCHbonddissociationenergies(BDE)[2]haveshownthatcarbonradicalsarestabilizedbyeitheranelectrondonatinggroup(EDG)oranelectronwithdrawinggroup(EWG),andthatifacarbonradicalissubstitutedwithbothanEDGandanEWGatthesamecen… 相似文献
168.
Adsorption of proteins and the effect of the chemical nature of membrane surfaces on protein adsorption were investigated
using14C-tagged albumin and several microporous membranes (polyvinilydene fluoride, PVDF; nylon; polypropylene, PP; and polycarbonate,
PC). The membrane surfaces were modified by exposing them to low-temperature plasma of several different monomers (n-butane, oxygen, nitrogen alone or as mixtures) in a radiofrequency plasma reactor. Transients in the permeability of albumin
solutions through the membranes and changes in flux of distilled water through the membranes before and after adsorption of
albumin were used to investigate the role of protein adsorption on membrane fouling. The results show that the extent of adsorption
of albumin on hydrophobic membranes was considerably more than that on hydrophilic membranes. The hydrophilic membranes were
susceptible to electrostatic interactions and less prone to fouling. A pore-blocking model was successfully used to correlate
the loss of water flux through pores of defined geometry 相似文献
169.
应用ahinitio计算程序,我们对飞行时间质谱产生的谱图进行了理论分析。稳定的MnnPm+和CrnPm+的结构基本上是多面体,仅有少数结构为环状和平面的。在计算中,我们尚未发现有链状的簇合物,这与风簇绝大多数是多面体是相一致的。因此,单枚金属簇合物的形成机制很大可能是金属进入磷形成的笼簇中。一般地说,除了磷的个别笼状团簇外,金属和磷相互成键是普遍存在的;在二核、多核金属磷簇合物中,金属间相互作用不常见,绝大多数是通过桥磷相连的。 相似文献
170.
Inis C. Tornieporth-Oetting Thomas M. Klaptke 《Angewandte Chemie (International ed. in English)》1995,34(5):511-520
The chemistry of covalent inorganic azides originated with the synthesis of aqueous HN3 solutions by Tony Curtis in 1890. A little later, in 1900, it proved possible to prepare iodine azide, IN3, as the first member of the meanwhile complete series of halogen azides. Since then it has been possible to synthesize, in addition to HN3 and the stable salt H2NSbF, azide compounds of elements from Groups 13 to 17. In these compounds the N3 moiety acts as a pseudohalogen and is primarily covalently coordinated to the nonmetal. Only a few organic azides, however, as well as HN3, H2N, and all halogen azides have been thoroughly studied with respect to structure and bonding. The combined application of diffraction methods (X-ray and electron diffraction) and microwave spectroscopy together with quantum chemical approaches such as ab initio SCF and density functional calculations have led in the last few years to an improved understanding of the molecular properties of numerous nonmetal azides, almost all of which are explosive. This interaction of theory and experiment has greatly enhanced the development of azide chemistry and has led to realistic expectations for the synthesis of as yet unknown nonmetal azides. 相似文献