醇体系中新型晶体磷酸锆的合成和表征

醇体系中新型晶体磷酸锆的合成和表征赵玉娥，宋天佑，徐家宁，徐如人（吉林大学化学系，长春，１３００２３）关键词磷酸锆，合成，表征自１９６４年首次合成磷酸锆晶体［１］以来，人们又合成出多种磷酸锆晶体［２～４］。但在非水体系中合成磷酸锆的工作尚未见报道。本...     

Formation of a disordered layer lattice during the intercalation of water into anhydrous vanadyl phosphate

The course of intercalation of water into ₁-VOPO₄ has been studied by thermomechanical analysis and X-ray diffraction. Neither formation of vanadyl phosphate monohydrate nor staging were observed during the intercalation. The broadening and the shift of the positions of the lines in the diffractograms have been explained by the random stacking of intercalated and nonintercalated layers in the sample.     

Direct and stepwise intercalation of alkylalcohols intoα-zirconium phosphate

Intercalation of alkylalcohols into -zirconium phosphate was investigated at 25°C and/or under reflux.n-Alcohols having two to five carbons and 2-propanol were taken up at 25°C. These alcohols, andn-hexanol and heptanol, also intercalated under reflux.n-Alcohols having eight to eighteen carbon atoms intercalated when a stepwise method was employed. 2-Butanol and tertiary amylalcohols intercalated under reflux using a butanol intercalate as a starting material. Ethanol-to-butanol intercalates were unstable at room temperature, losing alcohols and changing to -zirconium phosphate. The particle size of the -zirconium phosphate did not affect the intercalation of alcohols.     

A Novel Photoproduct of 1, 3-Dimethyluracil in Phosphate Buffered-saline

1, 3-Dimethyluracil （DMU） in phosphate buffered-saline （PBS, pH=8） was irradiated by a medium pressure mercury lamp （MPML） and produced a novel compound C6H9N2O6P. The composition and structure of the compound has been identified by elemental analysis, EIMS, UV, IR, ^1H and ^31P-NMR.     

Synthetic analogs of active centers of iron-sulfur proteins: Reactions with phosphates

The interaction of synthetic analogs of active centers of iron-sulfur proteins with phosphates of different structures was studied. It was shown that the process involves ligand exchange and obeys the first-order reaction kinetic equation. The most rapid exchange occurred with the most acidic compound diphenyl phosphate.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center, Russian Academy of Sciences, 420083 Kazan'. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10, pp. 2301–2305, October, 1992.     

溶剂萃取法制备Co(PO_3)_2超细微粉

本文用溶剂萃取法成功地制备了偏磷酸钴超细微粉并通过ＸＲＤ，ＩＲ，ＴＧ，ＤＴＡ，ＴＥＭ等实验对超细微粉的组成、结构进行了表征。     

Microwave assisted low temperature synthesis of sodium zirconium phosphate (NaZr<Subscript>2</Subscript>P<Subscript>3</Subscript>O<Subscript>12</Subscript>)

Sodium zirconium phosphate [NaZr₂P₃O₁₂], a potential ceramic matrix for fixation of high level nuclear waste, was synthesized by heating the mixture of sodium carbonate [Na₂CO₃], zirconyl nitrate hydrate [ZrO(NO₃)₂·5H₂O] and ammonium dihydrogen phosphate [NH₄H₂PO₄] in air, in a resistance heated furnace and a microwave heating system respectively in the temperature range 450 to 650°C. The mixture heated for 1 h in a resistance furnace at 450°C yielded a poorly crystalline NaZr₂P₃O₁₂ [NZP]. Increasing the temperature to 650°C produced a highly crystalline product. The same mixture heated in a microwave oven at 450°C for 1 h however, yielded the most crystalline NZP.In an alternate method, the mixture of sodium dihydrogen phosphate (NaH₂PO₄), zirconium dioxide (ZrO₂) and diammonium hydrogen phosphate [(NH₄)₂HPO₄] heated in resistance furnace at 650°C for the same period did not react in air. It also did not yield the pure product at 450°C when heated in microwave assembly for 1 h.The authors thank the Board of Research in Nuclear Sciences (BRNS) of the Department of Atomic Energy (DAE) for the financial support for this work under the project No. 2000/37/19/BRNS/1959 dtd09-02-02.     

二羟基丙酮磷酸酯的合成

本文报道由3-氯-1,2-丙二醇(1)经七步反应,合成二羟基丙酮磷酸酯缩乙酮(7)的方法,总收率43%。在温和条件下,7可以水解为游离的二羟基丙酮磷酸酯(8)。     

Tributyl phosphate degradation by immobilized cells of aCitrobacter sp.

Tributyl phosphate (TBP), a plasticizer and solvent, is used in nuclear fuel reprocessing, generating TBP wastes laden with residual uranium. ACitrobacter sp. accumulated heavy metals via a phosphohydrolase(s) that precipitated metals with inorganic phosphate liberated from an organic phosphate “donor” molecule (TBP). Mutant analysis suggested that TBP hydrolysis was not attributable to a previously documented acid phosphatase (monoesterase). Purified monoesterase had little activity against phospho di- and triesters, had no requirement for Mg²⁺ or Mn²⁺, and was EDTA-resistant. Conversely, TBP cleavage by immobilized cells was enhanced by Mg²⁺, and ininhibited by Mn²⁺ and EDTA. A separate phosphotri/diesterase was implicated.     

Synthesis and characterization of mixed-morphology CePO4 nanoparticles

Cerium phosphate nanoparticles with diameters of 10-180 nm were synthesized by a variety of solution techniques. X-ray diffraction (XRD) determined the crystalline phase(s) present in each sample. Population, shift, and spin-lattice relaxation ³¹P solid-state nuclear magnetic resonance (NMR) measurements accounted for all the ³¹P nuclei expected in each sample, and were able to distinguish between phosphorous nuclei in different environments and phases. Transmission electron microscopy (TEM) characterized the morphology and crystallinity of the powder samples as well as of the sintered compacts of the powders. In conjunction with TEM, energy-dispersive spectroscopy (EDS) provided a measure of the composition of the bulk intergranular regions within each CePO₄ sample. The presence of an amorphous, phosphate-rich intergranular phase was found in those samples prepared by dissolution of ceria in H₃PO₄ under various conditions.