全文获取类型
收费全文 | 6856篇 |
免费 | 1281篇 |
国内免费 | 674篇 |
专业分类
化学 | 3600篇 |
晶体学 | 280篇 |
力学 | 123篇 |
综合类 | 41篇 |
数学 | 104篇 |
物理学 | 4663篇 |
出版年
2024年 | 11篇 |
2023年 | 61篇 |
2022年 | 181篇 |
2021年 | 203篇 |
2020年 | 192篇 |
2019年 | 211篇 |
2018年 | 222篇 |
2017年 | 297篇 |
2016年 | 329篇 |
2015年 | 322篇 |
2014年 | 426篇 |
2013年 | 783篇 |
2012年 | 498篇 |
2011年 | 506篇 |
2010年 | 397篇 |
2009年 | 440篇 |
2008年 | 444篇 |
2007年 | 477篇 |
2006年 | 425篇 |
2005年 | 318篇 |
2004年 | 299篇 |
2003年 | 224篇 |
2002年 | 227篇 |
2001年 | 195篇 |
2000年 | 163篇 |
1999年 | 142篇 |
1998年 | 122篇 |
1997年 | 122篇 |
1996年 | 77篇 |
1995年 | 75篇 |
1994年 | 58篇 |
1993年 | 60篇 |
1992年 | 38篇 |
1991年 | 28篇 |
1990年 | 20篇 |
1989年 | 22篇 |
1988年 | 72篇 |
1987年 | 25篇 |
1986年 | 12篇 |
1985年 | 17篇 |
1984年 | 17篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 16篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 2篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有8811条查询结果,搜索用时 15 毫秒
51.
A wetting/dewetting process was utilized to prepare self-organized organic dye particles of micrometer and submicrometer size.
Near-field scanning optical microscopy successfully identified near-field excited near-field fluorescence from single particles.
The majority of the small particles with diameters around 2 mm or less, however, did not show fluorescence under near-field
observation. In contrast, far-field fluorescence, when excited by a polarized evanescent field, was observed, with the intensity
depending on the excitation polarization, indicating that molecules' transition moment within dye particles was oriented parallel
to the substrate surface. Single particle fluorescence spectrum consistently showed an identical sharp peak with a large redshift,
indicating that the particles were composed of identical dye aggregates similar to J-aggregates. These observations suggest
that the near-field at the probe tip was polarized parallel to the probe axis. Another observation, that molecules were oriented
in a similar direction among adjacent particles, suggests that the dewetting process contributed to the alignment of the molecular
direction among adjacent particles, which further proves that the present specimen was formed by a self-organizing mechanism. 相似文献
52.
Anisha Gokarna Yong Hwan Kim Yong-Hoon Cho Min Su Lee In Cheol Kang Hyun Kyu Park Min Gon Kim Bong Hyun Chung 《Optical Review》2006,13(4):288-291
We demonstrate the fluorescence mapping of protein microarrays by the technique of scanning near-field optical microscopy
(SNOM) and confocal microscopy. Micron sized spots (300 μm) of human Immunoglobulin G (hIgG) protein with and without a Cy3
dye labeling have been fabricated on glass substrates by an immobilization method which makes use of calixcrown derivatives
termed Prolinker. We have also tried to probe into the well-known “doughnut effect” observed in fluorescence images of proteins
using the SNOM technique. The topographic and fluorescence SNOM images revealed that the number of proteins at the boundary
of the spot were more than at the center in the case of the microarray spot which showed brighter luminescence at the edge
than at the center in the confocal image. 相似文献
53.
Najate Bensari-zizi Claude Alamichel 《International Journal of Infrared and Millimeter Waves》1989,10(1):137-151
About 2500 lines of CH3
35Cl have been assigned. The strong xy Coriolis resonance between thev
2 andv
5 modes is quite visible between thev
4+v
4
±1
perpendicular band, centered around 4383 cm–1, and thev
4
±1
+v
5
±1
perpendicular component, centered around 4475 cm–1, with a crossing of upper energy levels allowing the observation of lines which are normally forbidden. Although not yet observed with certainty, because of the great density of lines of the spectrum, thev
4
1
+v
5
±1
parallel component is nevertheless detectable by its effects onv
2+v
4
±1
which is linked by Coriolis resonance to both components ofv
4+v
5. Moreover the spectrum is much complicated by many other resonances with weak bands which occur at level crossings: it is the case ofv
2+3v
6
±1
, connected tov
2+v
4
±1
by the well known Darling Dennison resonance which couplesv
4
±1
and 3v
6
±1
, and also ofv
5
±1
+3v
6
±1
connected tov
4
±1
+v
5
±1
by the same resonance; but this last case is complicated by an anharmonic resonance betweenv
5
±1
+3v
6
±1
and 2v
3+3v
6
1
. Two more perturbations occur on the K=–1 side ofv
2+v
4: a weak Coriolis resonance gives rise to one subband ofv
1+v
2 at a level crossing withv
2+v
4, and thev
1+v
5 band (linked of course tov
1+v
2 by the Coriolis resonance between thev
2 andv
5 modes) is quite visible and perturbs several subbands ofv
2+v
4 of high values of K through an anharmonic resonance. Moreover, the complex (3v
5
±1
,v+2v
5
0
, 2v
2+v
5
±1
, 3v
2,v
2+2v
5
±2
, 3v
5
±3
) system of Coriolis-connected bands is linked to the bands studied in the present work by two Fermi resonances: one betweenv
2+2v
5
0
andv
1+v
2, and the other one betweenv
1+v
5 and 3v
5
±1
, whose several subbands have been observed on the low part of the spectrum. The values of all the band centres and of the different coupling constants have been estimated, but all these interactions make the line assignments and the interpretation of the spectrum very difficult. 相似文献
54.
聚乙烯单晶的退火效应 总被引:1,自引:1,他引:1
用混合晶红外光谱法和SAXS、DSC和LAM等方法研究了聚乙烯单晶在75℃、90℃和105℃退火前后的结构变化,发现在90℃以下和105℃以上退火,遵循不同的退火机制 相似文献
55.
本文以二苯基甲酮的KBr压片为标样,在Bruker IFS 120HR付里叶变换红外光谱仪上系统考察了该仪器折一些重要操作参数(光源光栏、切趾函数、扫描速度)对光谱质量(信噪比,分辨率)的影响。从而获得了测样时的优化操作条件。 相似文献
56.
超细Sr2CeO4 粉体微乳液-高温法制备条件的正交试验及其发光性能研究 总被引:2,自引:0,他引:2
本文首先利用正交试验确定了微乳液-高温法合成蓝色发光Sr2CeO4超细粉体的最佳制备条件。接着研究了最佳条件下制备的Sr2CeO4超细粉体的性能。场发射扫描电镜(FE-SEM)显示,在850 ℃、900 ℃、1 000 ℃或者更高温度下退火4 h制备的粉体的形状分别呈球状、梭状和球状,平均粒径分别在100 nm左右和1 μm以内。X射线粉末衍射数据分析表明,该超细粉体属于正交晶系。室温下的光致发光光谱显示,该粉体的激发光谱有3个激发峰,主峰分别位于262 nm、281 nm和341 nm,而其发射光谱只呈现出1个发射峰,主峰位于约470 nm。与高温固相制备方法相比,微乳液-高温法可以在较低温度下制备出超细的粉体,而且它不但在262 nm处出现了一个新的激发峰,主激发峰和发射峰的位置也分别蓝移了大约30 nm和12 nm。 相似文献
57.
58.
报道了FTS-20F富里叶红外光谱仪数据系统改造的工作采用IBM486计算机及新的数据接口取代了陈旧的NOVA4数据系统,文章详细描述了其硬件设计和软件编辑,改造不仅更新了FTS-20E里叶红外光谱仪,而且还使其达到90年代的水平。 相似文献
59.
Fabrication of hexaphenylsilole nanowires and their morphology-tunable photoluminescence. 总被引:1,自引:0,他引:1
Liping Heng Jin Zhai Anjun Qin Yuqi Zhang Yongqiang Dong Ben Zhong Tang Lei Jiang 《Chemphyschem》2007,8(10):1513-1518
Immersion of nanoporous alumina membranes into saturated solutions of hexaphenylsilole with subsequent solvent evaporation affords aligned organic nanowires. The luminescent properties of the hexaphenylsilole nanowires can be manipulated by varying their morphologies, which were controlled by changing the channel sizes of the alumina templates. 相似文献
60.
Vora A. Riga A. Dollimore D Alexander K. 《Journal of Thermal Analysis and Calorimetry》2004,75(3):709-717
This study attempts to identify the degradative process which folic acid undergoes in the solid-state under thermal stress.
In order to facilitate the process, the various pieces of the chemical structure, namely, p-amino benzoic acid, pterin and glutamic acid as both its d- and l-isomers were investigated as separate entities. These structured solid-state pieces were then compared to the composite solid
state folic acid degradative curves in order to identify the peaks seen and provide direction for the interpolation of the
degradative mechanism. It was observed that none of the structural pieces could be superimposed as assumed earlier and hence
an attempt was made to identify the decomposition products using various analytical techniques such as infrared spectroscopy,
mass spectroscopy and X-ray diffraction which suggested that the glutamic acid fragment is lost first as evidenced by acid
loss and amide enhancement in the IR spectra. The vitamin was ultimately degrading to carbon fragments and that further identification
was not necessary.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献