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41.
吡唑啉衍生物具有高的蓝色荧光,并且具有高量子效率,很易于用作发光材料中电子传输层。依据Schellhammer经验中化学结构与荧光性关系,在吡唑啉的1-位引入了苯并噻唑基,3-位引入苯基衍生物,使其具有荧光性,5-位引入呋喃基作为助色团,可使荧光波长红移,增加荧光性。文章设计并合成了六种5-位引入呋喃基苯并噻唑吡唑啉类荧光化合物,通过红外光谱、荧光光谱、1HNMR、元素分析对合成的化合物进行了表征,表明这类化合物具有良好的荧光性,其最大发射波长在440~460 nm之间,经过分析得知其荧光强度的大小与衍生物中不同的取代基有关。 相似文献
42.
Jos Antonio Andrades Manuel Lojo-Lpez Agata Egea-Corbacho Jos María Quiroga 《Molecules (Basel, Switzerland)》2022,27(14)
Different advanced oxidation processes (AOPs) (ultraviolet radiation, hydrogen peroxide photolysis and photo-Fenton) were applied to test the degradation of terbuthylazine in three types of water: (a) ultrapure water, (b) surface water from the Gaditana area (Los Hurones reservoir, Cádiz, Spain) and (c) groundwater from the Tempul spring in Jerez de la Frontera (Cádiz, Spain). The experiments were carried out on a laboratory scale, using two different types of reactors, batch and semi-continuous. In batch reactors, the most efficient process for the experiments carried out with both ultrapure water and underground groundwater was ultraviolet radiation, whereas for surface water from the Gaditana area, the process that obtained the best results was the photolysis of hydrogen peroxide with 2.5 mg L−1 of H2O2. In semi-continuous reactors, the most efficient process was the photolysis of hydrogen peroxide with 2.5 mg L−1 of H2O2 for all the matrices studied. In both types of reactors, terbuthylazine degradation percentages higher than 90% were achieved; the main difference was in the reaction time, which varied from minutes in the batch reactor to seconds in the semi-continuous reactor. In all the applied AOPs, N-terbutyl-6-hydroxy-N′ethyl-1,3,5-triazine-2,4-diamine (TBA-212) was generated as a reaction intermediate. 相似文献
43.
作者受厂家委托,对美国制造的《SZJ-10型沼泽检波器》的主要部件——《振荡探头》进行了有关技术参数的测试,测试结果基本符合实际,为生产厂家提供了测试方法和基本数据.本文《振荡钻探头》两个主要静态参数的测试方法做简单介绍。 相似文献
44.
45.
David E. Mery Amanda J. Compadre Paola E. Ordez Edward J. Selvik Vladimir Morocho Jorge Contreras Omar Malagn Darin E. Jones Philip J. Breen Michael J. Balick Flavio G. Gaudio Monica L. Guzman Cesar M. Compadre 《Molecules (Basel, Switzerland)》2022,27(9)
A method to identify anticancer compounds in plants was proposed based on the hypothesis that these compounds are primarily present in plants to provide them with an ecological advantage over neighboring plants and other competitors. According to this view, identifying plants that contain compounds that inhibit or interfere with the development of other plant species may facilitate the discovery of novel anticancer agents. The method was developed and tested using Magnolia grandiflora, Gynoxys verrucosa, Picradeniopsis oppositifolia, and Hedyosmum racemosum, which are plant species known to possess compounds with cytotoxic activities. Plant extracts were screened for growth inhibitory activity, and then a thin-layer chromatography bioautography assay was conducted. This located the major antileukemic compounds 1, 2, 4, and 5 in the extracts. Once the active compounds were located, they were extracted and purified, and their structures were determined. The growth inhibitory activity of the purified compounds showed a significant correlation with their antileukemic activity. The proposed approach is rapid, inexpensive, and can easily be implemented in areas of the world with high biodiversity but with less access to advanced facilities and biological assays. 相似文献
46.
本文对53种NnHn(n=3~7)氮氢化合物进行了理论计算,应用自然键轨道理论(Nature Bond Orbital,NBO)和分子中的原子理论(Atoms In Molecules,AIM)分析了化合物的成键特征、相对稳定性.氮原子孤对电子与氮氮键以及氮氮键相互之间的超共轭作用是影响氮氮键长的重要因素.采用原子基团... 相似文献
47.
利用分子轨道从头算理论和密度泛函理论结合不同理论基组对于N-H…O蓝移氢键进行了详细的研究.利用标准方法和均衡校正方法对二聚体进行了几何优化,振动频率和相互作用能的计算.拓扑学和自然键轨道理论对于蓝移氢键的本质进行分析.自然键轨道(NBO)分析表明,σ*(N-H)轨道上电子密度降低是电子密度重排效应的结果.分子内电子重排、轨道再杂化和电子受体内部结构重组共同作用结果导致了N-H的振动频率大幅蓝移现象的出现. 相似文献
48.
The measurement of radial directional natural frequency and damping ratio in a vehicle tire has been studied. Natural frequencies and damping ratios in the radial direction of various tires, from passenger car tires to truck bus tires, are reported. The radial direction modal parameters of tires subjected to different levels of inflation pressure, have been determined by using a frequency response function method. To obtain the theoretical natural frequency and mode shape, the plane vibration of a tire has been modeled as though it were that of a circular beam. By using the Tielking method that is based on Hamilton’s principle, theoretical results have been determined by considering the rotational velocity, tangential and radial stiffness, radial directional velocity and tension force which is due to tire inflation pressure. The results show that experimental conditions can be considered as the parameters that shift the natural frequency and damping ratio. 相似文献
49.
The radiation directivity of a complicated conformal array of underwater acoustic transducers is presented based on the boundary "element method. It includes the element directivity of each transducer, the natural beam pattern and the controlled beam pattern of the transducer array. At first, the boundary element model of the conformal array is built up, and then the boundary condition is exerted on the model according to the design and environment in which the transducer array is used, and the radiation directivity of the conformal array is calculated. An experiment has been done to measure the directivity in an anechoic water tank. The calculated and the experimental results are compared and analyzed. They are consistent to each other. It is shown that the boundary element method together with the detailed calculations is successful to simulate and predict the radiation directivity of an underwater acoustic transducer array. 相似文献
50.