全文获取类型
收费全文 | 177篇 |
免费 | 63篇 |
国内免费 | 136篇 |
专业分类
化学 | 229篇 |
晶体学 | 31篇 |
力学 | 3篇 |
综合类 | 4篇 |
物理学 | 109篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 11篇 |
2021年 | 7篇 |
2020年 | 11篇 |
2019年 | 16篇 |
2018年 | 11篇 |
2017年 | 19篇 |
2016年 | 15篇 |
2015年 | 17篇 |
2014年 | 21篇 |
2013年 | 41篇 |
2012年 | 26篇 |
2011年 | 30篇 |
2010年 | 24篇 |
2009年 | 22篇 |
2008年 | 18篇 |
2007年 | 19篇 |
2006年 | 8篇 |
2005年 | 19篇 |
2004年 | 7篇 |
2003年 | 7篇 |
2002年 | 2篇 |
2001年 | 4篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
排序方式: 共有376条查询结果,搜索用时 15 毫秒
81.
基于金纳米棒-壳聚糖复合膜的葡萄糖生物传感器 总被引:3,自引:0,他引:3
本文采用金纳米棒-壳聚糖复合膜固定葡萄糖氧化酶构建电流型葡萄糖生物传感器.通过电化学交流阻抗法和循环伏安法对酶膜状态进行了表征,得到了相应的等效电路和动力学参数.实验结果表明,金纳米棒-壳聚糖复合膜可以辅助电子传递,提高电极的电流响应,并使生物传感器的使用温度范围有很大的扩展.此传感器表现出对葡萄糖溶液浓度的优良响应,线性范围在2.78×10-5mol/L—2.22×10-3mol/L,响应灵敏度约为7.819μA·cm-2(mmol/L)-1,表观米氏常数为10mmol/L.本工作还研究了温度和溶液pH值对电极电流响应的影响. 相似文献
85.
Highly Sensitive Silver Nanorod Arrays for Rapid Surface Enhanced Raman Scattering Detection of Acetamiprid Pesticides
下载免费PDF全文
![点击此处可从《化学物理学报(中文版)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Cai-qin Han Yue Yao Wen Wang Liu-qian Tao Wen-xin Zhang Whitney Marvella Ingram Kang-zhen Tian Ying Liu Ai-xia Lu Ying Wu Chang-chun Yan Lu-Lu Qu Hai-tao Li 《化学物理学报(中文版)》2018,31(2):152-158
The determination of pesticide residue on agricultural products is increasingly important.Exposure to pesticides can cause severe acute reactions in humans, including aplastic anemia and leukemia.In this work, we developed a rapid and sensitive method to detect acetamiprid pesticide residue based on surface-enhanced Raman scattering.Silver nanorod (AgNR) arrays were fabricated by oblique angle deposition technology and were used as SERS substrates.Prior to detection, the AgNR arrays were cleaned with nitric acid solution or a mixture of methanol and acetone.Compared to the unwashed AgNR arrays, the AgNR arrays washed with methanol and acetone shows a signal enhancement 1000 times greater than the unwashed AgNR array due to the effective removal of the impurities on its surface.The limit of detection of acetamiprid was determined to be 0.05 mg/L.In addition, the molecular structure of acetamiprid was simulated and the corresponding vibration modes of the characteristic bands of acetamiprid were calculated by density function theory.To demonstrate its practical application, the AgNRs array substrates were applied successfully to the rapid identification of acetamiprid residue on a cucumber's surface.These results confirmed possibility of utilizing the AgNRs SERS substrates as a new method for highly sensitive pesticide residue detection. 相似文献
86.
Young Jung Kim Huamei Shang Guozhong Cao 《Journal of Sol-Gel Science and Technology》2006,38(1):79-84
This paper reports direct growth of [001] ZnO nanorod arrays on ITO substrate from aqueous solution with electric field assisted
nucleation, followed with thermal annealing. X-ray diffraction analyses revealed that nanorods have wurtzite crystal structure.
The diameter of ZnO nanorods was 60–300 nm and the length was up to 2.5 μm depending on the growth condition. Photoluminescence
spectra showed a broad emission band spreading from 500 to 870 nm, which suggests that ZnO nanorods have a high density of
oxygen interstitials. Low and nonlinear electrical conductivity of ZnO nanorod array was observed, which was ascribed to non-ohmic
contact between top electrode and ZnO nanorods and the low concentration of oxygen vacancies. 相似文献
87.
Well-aligned ZnO nanorod arrays were prepared on substrates by hydrothermal growth under different conditions. The effect of preparing conditions on the deposition of ZnO nanorods was systematically studied by scanning electron microscopy, X-ray diffraction and photoluminescence spectroscopy. It is demonstrated that the growth conditions such as pre-treatment of the substrates, growth temperature, deposition time and the concentration of the precursors have great influence on the morphology and the alignment ordering of ZnO nanorod arrays. Pre-treatment of substrates, including dispersion of ZnO nanoparticles and subsequent annealing, not only plays a main role in governing the rod diameter, but also greatly improves the rod orientation. Although the rod diameter and its distribution are mainly determined by pre-coated ZnO nanoparticles, they can also be monitored to some extent by changing the concentration of the precursors. The growth temperature has a little influence on the orientation of nanorods but it has great impact on their aspect ratio and the photoluminescent property. Kinetic studies show that the growth of ZnO nanorods contains two distinct step: a fast steps within the first hour, in which the nanorods tend to be short and wide, and a slow step, in which long rods with high aspect ratio are obtained. 相似文献
88.
Ti-doped ZnO nanorod arrays were grown onto Si substrate using chemical bath deposition (CBD) method at 93 °C. To investigate the effect of time deposition on the morphological, and structural properties, four Ti-doped ZnO samples were prepared at various deposition periods of time (2, 3.5, 5, and 6.5 h). FESEM images displayed high-quality and uniform nanorods with a mean length strongly dependent upon deposition time; i.e. it increases for prolonged growth time. Additionally, EFTEM images reveal a strong erosion on the lateral side for the sample prepared for 6.5 h as compared to 5 h. This might be attributed to the dissolution reaction of ZnO with for prolonged growth time. XRD analysis confirms the formation of a hexagonal wurtzite-type structure for all samples with a preferred growth orientation along the c-axis direction. The (100) peak intensity was enhanced and then quenched, which might be the result of an erosion on the lateral side of nanorods as seen in EFTEM. This study confirms the important role of growth time on the morphological features of Ti-doped ZnO nanorods prepared using CBD. 相似文献
89.
90.
SnO2 纳米棒的氧化还原特性 总被引:2,自引:0,他引:2
利用室温固相反应在 NaCl-KCl 熔盐介质中, 通过焙烧含 SnO2 纳米颗粒前驱体合成了 SnO2 纳米棒, 并采用 X 射线衍射、扫描电镜、透射电镜、选区电子衍射和 X 射线光电子能谱对 SnO2 纳米棒进行了表征. 结果表明, SnO2 纳米棒是表面光滑、结晶完整的金红石结构单晶体, 直径为 10~20 nm, 长度为几百纳米到几个微米. 程序升温还原结果表明, SnO2 纳米棒具有较好的氧化还原性能和催化活性. 探讨了 SnO2 纳米棒的氧化还原机理. 相似文献