Metal chelate monomers (MCMs) have been widely used as precursors for the production of advanced functional polymers and nanomaterials. In this articel, new metal chelate monomers based on nickel(II) cinnamate (cinn) and various chelating N-heterocycles, [Ni(cinn)2(bpy)(C2H5OH)] and [Ni(cinn)2(phen)(C2H5OH)2] (bpy = 2,2′-bipyridine and phen = 1,10-phenanthroline), were first synthesized and characterized. A detailed analysis of the main stages and features of the kinetics of thermolysis of MCMs was carried out. Metal-polymer nanocomposites with a core-shell structure containing metal nanoparticles evenly distributed in a stabilizing nitrogen-containing polymer matrix were obtained by thermolysis at 300?°C. Thermolysis at 450?°C resulted in pure nickel oxide nanoparticles. The nature of the ligand has been shown to affect the structure and size of the product obtained. The tribological characteristics of nanoparticles as additives to lubricating oils were studied using the pin-on-disc tribometer. At the optimum concentration of nanoparticles, the coefficient of friction is the smallest, and an increase in the concentration above the optimum level leads to an increase in the coefficient of friction. 相似文献
The development of the methods for early and accurate diagnosis of acute myocardial infarction are needed to facilitate immediate treatment of patients. One of the ways to achieve that is the detection of cardiac biomarkers for myocardial infarction, such as thrombin, cardiac troponins (I and T), myoglobin, etc. Nanotechnology has played an important role in the development of sensitive and efficient electrochemical sensors for cardiac biomarkers. In this review, we discuss recent progress on nanomaterial‐based electrochemical sensing of various cardiac biomarkers for acute myocardial infarction. 相似文献
The use of tubular halloysite clay as a nanotemplate for layer‐by‐layer (LbL) shell assembly and its utilization for controlled release of drug macromolecules are studied. The LbL nanoshell allowed additional control for the sustained release of drug loaded halloysite tubes. The number of polymeric layers in the shell and molecular weight of the assembled polymers influences the drug release rate. Three bilayer shells of chitosan and gelatin of 15 nm thicknesses gave the best encapsulation and retardation in the release rate of dexamethasone. An encapsulation of the macromolecules inside the lumen of the biocompatible clay nanotubes coupled with the polyelectrolyte shell formation provides a novel formulation for the controlled release of bioactive agents.
The development of nanoscale systems capable to perform specific functions under external control is a challenging task and a fascinating objective in Chemistry. Photochromic compounds undergo radical changes in their physico‐chemical properties upon light excitation, for this reason they are valuable building blocks for the construction of photo‐controllable molecular devices, machines and materials. The E–Z photoisomerization of azobenzene has been known for almost 80 years and – owing to its high efficiency and excellent reversibility – has been widely employed to introduce an element of photo‐control in a large variety of compounds, biomolecules, nanosystems and materials. Here we present some of our research results highlighting how this outstanding photochrome can be utilized to develop systems with light‐induced functionalities. 相似文献
Pristine and substituted tetrahedrite nanoparticles have shown immense potential as low-cost and sustainable materials for energy conversion applications. However, the commonly used synthetic methods for their production are cumbersome and are not easily scalable. In this work, we report a facile colloidal synthetic protocol for the preparation of phase-pure samples of pristine (Cu12Sb4S13) and Zn-substituted (Cu11ZnSb4S13) tetrahedrite nanoparticles on the gram scale. Both tetrahedrite compositions were found to be photothermally responsive, enabling their use in solar-driven water evaporation. 相似文献