High pressure measurement of n-dodecane heat capacity up to 100 MPa. Calculation from equations of state

Abstract

Isobaric heat capacities of liquid n-dodecane were measured at temperatures from 313.15 to 373.15 K and at pressures up to 100 MPa using a calorimetric device based on a Calvet calorimeter (Setaram (280). These experimental data were used to perform a comparative study in order to choose, from among the great number of equations of state proposed in the literature, the most appropriate to calculate the isobaric heat capacity.     

Generalized entropy production analysis for mechanism reduction

The paper introduces a generalized formulation for the computation of the relative contribution of each elementary reaction to the total entropy production, which has been proposed as a measure of the importance of elementary reactions and used for the reduction of detailed chemical reaction mechanisms. The reduction method is extended for the cases where the principle of detailed balance does not hold or apply, namely in the case of irreversible reactions or when the reverse rate constants are not computed via the thermodynamic equilibrium constants. Using a mechanism for n-butane consisting exclusively of reversible reactions, the new formulation is compared to the original one, and then applied for the construction of a skeletal mechanism for n-dodecane starting from a detailed mechanism which includes predominantly irreversible reactions. The skeletal scheme is found to accurately capture the ignition delay times over an extended range of pressure, initial temperature and equivalence ratio, the steady-state temperature as function of the residence time in a non-isothermal adiabatic perfectly stirred reactor, and the laminar flame speed of atmospheric flames at different unburned mixture temperatures and equivalence ratios.     

溶剂热法合成用于正十二烷异构化的高活性富蛙Pt/SAPO-11催化剂

采用溶剂热法,利用不同的硅源和铝源合成了富硅的SAPO-11分子筛. 结果显示,与水热法合成的样品相比,溶剂热法合成的Pt/SAPO-11催化剂具有较大的外表面积,同时其硅含量、酸度和对正十二烷异构化的催化活性均显著提高. 在所有合成的Pt/SAPO-11催化剂样品中,以正硅酸乙酯与异丙醇铝为原料,采用溶剂热法合成的催化剂具有最高的酸度与正十二烷异构化活性.     

Probabilistic parameter estimation in a 2-step chemical kinetics model for n-dodecane jet autoignition

This paper demonstrates the development of a simple chemical kinetics model designed for autoignition of n-dodecane in air using Bayesian inference with a model-error representation. The model error, i.e. intrinsic discrepancy from a high-fidelity benchmark model, is represented by allowing additional variability in selected parameters. Subsequently, we quantify predictive uncertainties in the results of autoignition simulations of homogeneous reactors at realistic diesel engine conditions. We demonstrate that these predictive error bars capture model error as well. The uncertainty propagation is performed using non-intrusive spectral projection that can also be used in principle with larger scale computations, such as large eddy simulation. While the present calibration is performed to match a skeletal mechanism, it can be done with equal success using experimental data only (e.g. shock-tube measurements). Since our method captures the error associated with structural model simplifications, we believe that the optimised model could then lead to better qualified predictions of autoignition delay time in high-fidelity large eddy simulations than the existing detailed mechanisms. This methodology provides a way to reduce the cost of reaction kinetics in simulations systematically, while quantifying the accuracy of predictions of important target quantities.