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991.
采用金属与金属氧化物复合靶的射频溅射法,在S_1,Au,Pt和Ti基片上沉积制备Bi_4Ti_3O_(12)(BTO)铁电薄膜,对不同基片沉积的BTO薄膜,以及不同退火温度下的薄膜的相结构、成分及形貌进行了分析。结果表明,BTO薄膜的结构与退火温度和沉积基片有关,不同基片上钙钛矿结构形成的温度按T_t相似文献
992.
岩体具有复杂的内部结构,内部结构对于岩土的力学性质具有决定性的影响.文章从岩体结构层次的角度研究了岩体的动力变形与破坏过程,在松弛模型的框架内研究了变形破坏的空间尺度与应变率之间的关系.讨论了裂纹传播速度与荷载强度之间的关系,研究了岩体变形破坏的层次特性.最后从岩体结构层次角度研究了岩体的破坏准则.研究表明:岩体的动力变形与破坏具有层次特性,这一层次特性依赖于外载的空间与时间特性、岩体的结构层次和岩体变形与破坏过程速度的有限性.时间准则与极限变形准则可以较好地描述岩体的动力破坏. 相似文献
993.
陈松良 《武汉大学学报(理学版)》2013,59(3):295-300
设p,q为奇素数,且p>q.本文对Sylow子群皆交换的p2q 3阶群进行了完全分类并获得了其全部构造:1)当q(p2-1)且p(q2+q+1)时,G恰有6个不同构的类型;2)当q(p-1)但p|(q2+q+1)时,G恰有8个不同构的类型;3)当q|(p-1)但q2(p-1)且p(q2+q+1)时,G恰有q2+19个不同构的类型;4)当q|(p-1)且p|(q2+q+1)但q2(p-1)时,G恰有q2+21个不同构的类型;5)当q2|(p-1)但q3(p-1)时,G恰有2q2+q+24个不同构的类型;6)当q3|(p-1)时,G恰有(q3+5q2+2q+52)/2个不同构的类型;7)当q|(p+1)但q2(p+1)时,G恰有10个不同构的类型;8)当q2|(p+1)但q3(p+1)时,G恰有12个不同构的类型;9)当q3|(p+1)时,G恰有13个不同构的类型. 相似文献
994.
By the reaction of KCN with Cp2TiCl2 (Cp = η5-C5H5) in boiling methanol, bis(cyclopentadienyl)-methoxytitanium(IV) cyanide, Cp2Ti(OCH3)CN, is formed which in air is converted into the dinuclear oxygen-bridged derivative (Cp2TiCN)2O. By the same procedure, the bis(methylcyclopentadienyl) analogue [MeCp2TiCN]2O has been obtained. An X-ray diffraction study of (Cp2TiCN)2O has shown that the CN group acts as a unidentate ligand with a Ti? C bond length of 2.158 Å and a Ti? C? N bond angle of 177.7°, very close to linearity. The Ti? O bond distance, 1.836 Å, and the bond angle at the bridging O atom, 174.1°, are normal. The ligands are arranged in a nearly tetrahedral way around the Ti atoms. The structural results are compared to those for similar dinuclear titanium complexes. 相似文献
995.
Two New Alkylimido-Methylgallanes with Cage Structure The tetrameric alkylimido-methylgallanes (MeGa? NR)4 (R = CH(CH3)2 ( iPr), C(CH3)3 ( tBu) and Me = CH3) have been prepared by pyrolyses of the dimeric amido compounds (Me2Ga? N(H)R)2 at 250–260°C. The mass, NMR and vibrational spectra are discussed, they prove almost identical structures of the skeletons. The X-Ray structure determination of (MeGa? NtBu)4 shows four heterocubane molecules in the trigonal unit cell (space group P3 c1, a = b = 1061.7(1), c = 3191.8(5) pm) and two disordered benzene solvate molecules. The Ga? N bonds range between 198.4 to 199.9 pm, the Ga? N? Ga and N? Ga? N bond angles lie between 90.6 to 91.4 and 88.6 to 89.2°, respectively. The structure was refined to an R1(R2)-value of 0.049 (0.057). 相似文献
996.
I. P. Romanova O. G. Sinyashin G. G. Yusupova V. I. Kovalenko Yu. Ya. Efremov Yu. V. Badeev I. I. Vandyukova I. A. Arakelyan 《Russian Chemical Bulletin》1999,48(11):2144-2148
The reaction of [60]fullerene with diphenylphosphinoyl azide in toluene or ino-dichlorobenzene in the presence of traces of water affords 2-[N-(diphenylphosphoryl)amino]-1-hydroxy[60]fullerene This reaction in THF gives a mixture of (N-diphenylphosphoryl)[60]fullerenol[1,2-b]aziridine and a product of partial hydrolysis of the bisadduct of phosphorylated azide and fullerene.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2168–2172, November, 1999. 相似文献
997.
A straightforward preparation has been found for bis(dichlorosilyl)methylamine, (SiHCl2)2NMe ( 1 ), involving reaction between H2NMe and an excess of SiHCl3, dissolved either in pentane or THF at 253 K. 1 and a side‐product, 1,3,5‐trichloro‐2,4,6‐trimethylcyclotrisilazane, (–SiHCl–NMe–)3 ( 2 ), were identified by elemental analysis, mass spectrometry and 1H‐NMR‐spectroscopy. Some physical, NMR‐ and IR spectroscopical properties of 1 were determined. The molecular and crystal structure of 1 was investigated by single crystal X‐ray diffraction. Selected structural parameters: r(Si–N) 169.7(5), r(Si–Cl) 203.1(2)–204.4(2), r(C–N) 150.0(8) pm; a(SiNSi) 123.6(3), a(SiNC) 118.3(4)/118.0(4)°. Ab initio force field data and infrared intensities were calculated for four conformers of 1 . Comparison of the observed and calculated IR spectra favours the two structures found ab initio provided that their actual abundancies are different from those calculated. 相似文献
998.
Structure and Coordination Chemistry of Sterically Demanding Phenylcycloarsoxane Tetrameric phenylcycloarsoxane (C6H5AsO)4 1 exhibits a boat‐chair‐conformation in the solid state. Its reaction with CuI in benzonitrile leads to the formation of coordination polymers. [(CuI · C6H5CN){cyclo‐(C6H5AsO)4}] ( 2 ) underlines the structure‐directing steric requirements of the phenyl side chains. Treatment of 1 with M(CO)6 (M = Cr, Mo) confirms its capability to undergo metal‐mediated ring expansion. In [{M(CO)3}2{cyclo‐(C6H5AsO)6}] with M = Cr ( 3 ) and M = Mo ( 4 ), twelve membered As–O‐rings are stabilised by the participation of alternating As atoms in the coordination spheres of opposite facial transition metal carbonyl fragments M(CO)3. 相似文献
999.
CsC2H: Synthesis, Crystal Structure, and Spectroscopic Properties CsC2H was synthesised by the reaction of caesium solved in liquid ammonia with acetylene. The crystal structure could be solved and refined from X‐ray and neutron powder diffraction data (space group: R3c, Z = 18). The structure is characterised by C2H– trimers which are surrounded by caesium ions. Spectroscopic investigations (IR and Raman) of the stable monoalkalimetal acetylides mainly confirm the data given in the literature and show that the alkalimetal cation has a marked influence on the vibrational properties of the C2H– anion. 相似文献
1000.
1-Ethoxycarbonyl-3-ferrocenyl-propane-1,3-dion and Ferrocene-1,1′bis(2,4-dioxobutanoic acid ethylester) as Ligands for Transition Metal Ions. Crystal Structure of Bis(1-ethoxycarbonyl-3-ferrocenyl-propane-1,3dionato)copper(II) The ligands 1-ethoxycarbonyl-3-ferrocenyl-propane-1,3-dion and ferrocene-1,1′-bis(2,4-dioxo-butanoic acid ethylester) have been prepared by reaction of acetylferrocene or 1,1′-diacetylferrocene and diethyl oxalate. They yield neutral chelates with CuII, NiII, ZnII, CoII, and MnII. The acid dissociation constants of the ligands and the stability constants of their metal complexes including FeII complexes are reported. The structure of bis(1-ethoxycarbonyl-3-ferrocenyl-propane-1,3-dionato)copper(II) was determined by X-ray structure analysis. A cis arrangement with a nearly square planar coordination sphere at the Cu atom is found. 相似文献