全文获取类型
收费全文 | 1050篇 |
免费 | 67篇 |
国内免费 | 55篇 |
专业分类
化学 | 864篇 |
晶体学 | 6篇 |
力学 | 84篇 |
综合类 | 15篇 |
数学 | 44篇 |
物理学 | 159篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 23篇 |
2021年 | 27篇 |
2020年 | 32篇 |
2019年 | 24篇 |
2018年 | 19篇 |
2017年 | 34篇 |
2016年 | 37篇 |
2015年 | 34篇 |
2014年 | 36篇 |
2013年 | 84篇 |
2012年 | 38篇 |
2011年 | 31篇 |
2010年 | 40篇 |
2009年 | 29篇 |
2008年 | 39篇 |
2007年 | 55篇 |
2006年 | 58篇 |
2005年 | 41篇 |
2004年 | 80篇 |
2003年 | 44篇 |
2002年 | 30篇 |
2001年 | 42篇 |
2000年 | 39篇 |
1999年 | 47篇 |
1998年 | 27篇 |
1997年 | 30篇 |
1996年 | 28篇 |
1995年 | 25篇 |
1994年 | 25篇 |
1993年 | 26篇 |
1992年 | 18篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1172条查询结果,搜索用时 31 毫秒
101.
Determinations of soil moisture witli the aid of neutron moisture meters require calibrations under real conditions. Some efficient methods for calibrating such moisture gauges are described and working examples are presented. 相似文献
102.
103.
Ken-Ichi Okamoto Nozomu Tanihara Hitoshi Watanabe Kazuhiro Tanaka Hidetoshi Kita Asumaru Nakamura Yoshihiro Kusuki Kanji Nakagawa 《Journal of Polymer Science.Polymer Physics》1992,30(11):1223-1231
Sorption and diffusion of water vapor are investigated gravimetrically for polyimide films. The activity dependence of the solubility and diffusion coefficients, S and D, respectively, is classified under four types: (1) constant S and D type, (2) dual-mode sorption and transport type, (3) dual-mode type followed by a deviation due to a plasticization effect at high vapor activity, and (4) constant S and D type followed by a deviation due to water cluster formation at high activity. For the dual-mode type, the Henry's law component is much larger than the Langmuir component except at low activity, and therefore deviation in behavior from the first type is small. S is larger for polyimides with higher content of polar groups such as carbonyl, carboxyl, and sulfonyl. D is larger for polyimides with a higher fraction of free space, with some exceptions. The polyimide from 3,3′,4,4′-biphenyltetracarboxylic dianhydride and dimethyl-3,7-diaminodibenzothiophene-5, 5-dioxide belongs to the third type and displays both large S and large D. The polyimide from 2,2-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride and 4,4′-oxydianiline belongs to the fourth type, and has the largest D but rather small S because of the hydrophobic C(CF3)2 groups. © 1992 John Wiley & Sons, Inc. 相似文献
104.
Regression relations between the first main component, slope of the SBC curve towards the wavelength axis, and the degree
of mineralization of peat soils are established from experimental data. Errors in determination of peat soil productivity
are estimated using different spectral indices. For practical use it is recommended to measure the spectral brightness coefficients
of peat soils in the 0.50–0.75 μm range.
B. I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, 70, F. Skorina Ave., Minsk, 220072, Belarus.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 1, pp. 102–106, January–February, 1998. 相似文献
105.
The temperature dependence of gas sorption and transport properties is examined for two polyimide isomers. The permeabilities and solubilities of five gases in these materials are reported over an extensive temperature range from 35 to 325°C. Also, the activation energies for permeation, the heats of sorption, and the activation energies for diffusion obtained for both polyimides are compared and correlated with physical properties of the polymers and penetrants. The influence of temperature on the selective properties of these membrane materials is discussed for three gas separations; He/N2, CO2/CH4, and O2/N2. Thorough analysis of these data provides insight into the influence of the subtle difference in chain structure of the two isomers. The performance of the 6FDA-6Fp DA as a separation membrane at high temperatures suggests that it is an outstanding candidate for use in novel elevated temperature applications. ©1995 John Wiley & Sons, Inc. 相似文献
106.
It has been observed that noble gases, such as helium, neon and argon produce heat evolution when contacted with Pd powder partially saturated with hydrogen. These phenomena have been studied with flow-through adsorption microcalorimetry. The observed exothermic effects are comparable to those usually associated with the heat of sorption of hydrogen in palladium. It is suggested that the noble gases displace the adsorbed H species from the surface of Pd, causing their reabsorption in the Pd lattice with the exothermic heat of PdH bonds formation, or the formation of H2, both heat evolutions being observed with a flow-through microcalorimeter. 相似文献
107.
The interaction of 1-anilinonaphthalene-8-sulphonate (ANS) with cross-linked poly(N-vinyl-2-pyrrolidone) (CPVP) was studied
by the adsorption technique at different temperatures and at two different pH values. Analysis by the Scatchard method and
the study made in the presence of urea showed that the iceberg structure of water affects the sorption of ANS to CPVP, leading
to cooperativity. The observed Giles sorption isotherms at both the pH values were of theL-type which indicated the interaction of ANS in flat configuration with the binding site in CPVP. The sorption of ANS to CPVP
was enhanced considerably at acidic pH due to some structural factors which also resulted in multilayer sorption at this pH.
Comparison of binding of ANS to CPVP and to linear poly(N-vinyl-2-pyrrolidone) demonstrated the greater contribution of hydrophobic
interaction in CPVP than in the linear polymer. 相似文献
108.
Moisture removal from a two-layer porous media in which air is circulated through one layer and moisture is removed from the second has not been well studied due to the emphasis given to single-layer systems. This two-layer configuration is common in natural and engineered systems and can be used as a means to create a barrier to downward migrating fluids and to remove liquids and gases that may be present in the finer layer. However, there is little data on moisture removal from a two-layer porous media in which air is circulated through one layer parallel to the interface and moisture is removed from the finer second layer by evaporation. A conceptual model of the moisture removal from a two-layer porous media system was developed and compared to experimental moisture removal rates from laboratory scale dry barriers. The limited experimental data agrees well with the results predicted by the conceptual model, providing an initial validation. 相似文献
109.
土壤内水分流动及温度分布计算——耦合型模型 总被引:3,自引:0,他引:3
本文目的在于发展一个计算土壤内水分输送及能量交換的物理模型——耦合型模型,驱动该模型的大气条件是由实测而得的,引用对蒸发的土壤表面阻抗关联了在大气中水汽通量与从地表的蒸发,由于这种阻抗引入,计算模拟的结果与实测值达到了较好的吻合。 相似文献
110.
This article presents solutions for the transient heat and moisture transport due to both disk heat source and cylindrical
heat source buried in an unsaturated half space. The solutions are presented in Hankel–Laplace transform domain and in dimensionless
style. Coupled effect of thermally driven moisture transport is especially investigated because of its importance to alter
the flow field in low-permeability medium. Parametric study has been performed to assess the effects of five independent dimensionless
parameters on flow field. The stability and accuracy of the present solutions are demonstrated from the comparison between
the results obtained from these solutions and those by using a well-established finite element code CODE_BRIGHT. Despite the
simplified assumptions required in order to obtain analytical solutions in Hankel–Laplace transform domain, the results incorporate
the main mechanisms involved in the coupled thermo-hydraulic (T-H) problem, and they may be eventually used for validation
purposes. 相似文献