混合溶剂对P3HT:PCBM基太阳能电池的影响

以poly(3-hexylthiophene)(P3HT)为电子给体材料,[6,6]-phenyl-C60-butyric acid methyl ester (PCBM)为电子受体材料,制备了纯氯苯(CB)溶剂、纯氯仿(CF)溶剂和氯苯/氯仿(CB/CF)不同比例混合溶剂的共混体系太阳能电池.研究了不同溶剂及不同比例混合的混合溶剂对电池性能的影响.结果表明:以CB/CF(3/1)为溶剂制备的器件,紫外可见吸收光谱和器件外量子效率曲线显示出红移现象,原子力显微图表明P3HT和PCBM间形成良好的相分离结构.在100 mW/cm2强度光照射下,其开路电压Voc为0.61 V短路电流密度Jsc为9mA/cm2,填充因子FF为57.9％,能量转换效率PCE为3.2％.     

氩-氮混合气电感耦合等离子体在元素和同位素分析中的应用进展

在传统Ar等离子体中引入其他活性气体(如氮气等)已经成为拓展其分析性能的一种重要手段。本文较系统的阐述了Ar-N₂混合气体电感耦合等离子体的基本物理化学性质,从N₂气引入引起传统Ar-ICP基本物理化学参数变化的层面出发探讨了Ar-N₂混合气等离子体特殊性质产生的机制,回顾了Ar-N₂混合气电感耦合等离子体在质谱分析中近40年的应用成果,并且展望了该技术在未来元素和同位素分析领域的应用前景。     

车辆的长度和速度对单车道混合交通流的影响

在NaSch交通流模型的基础上，建立了单车道上由两种长度不一样、可分别以不同最大速度行驶的车辆构成的混合交通流模型.在周期性边界条件下，通过计算机模拟研究了车辆的长度、最大速度和混合比例系数对混合交通流的影响. 关键词： 元胞自动机 混合交通流 计算机模拟     

A boron-lined proportional counter (BLPC) used in a mixed field of reactors

A boron-lined proportional counter (BLPC) with a count rate limit close to the multi-wire proportional counter was manufactured to measure the mixed field around reactors. After measurement with a standard Am-Be neutron source (activity: 100 mCi), the results show that the operating voltage of the BLPC is 800 V, the plateau length is 100 V and the slope is 13.2%/100 V. The width and rise time of the output pulse of the BLPC are 1.26 μs and 370 ns, respectively. When the BLPC works at a count rate of 1.0×10⁵ count/s, the pulse pile-up probability of the BLPC is 3.6%. A clear peak can be seen in the pulse height spectrum of the BLPC. and the performances illustrate that a BLPC working in pulse mode can serve as a source range detector of reactors.     

Influence of the Type of a Ligand on the Intensity of Luminescence of Ln3+ Ions in Aqueous Solutions

The luminescence characteristics of hydrated Ln³⁺ ions and their complexes with some acidic ligands have been investigated. The possibility of determining the stability of the complexes of lanthanides in solutions from the intensity of luminescence bands is shown. The influence of the characteristic features of the f-electron shell of Ln³⁺ on the formation of the spectrochemical series is discussed.     

Entanglement and Classical Correlations in the Quantum Frame

The frame of classical probability theory can be generalized by enlarging the usual family of random variables in order to encompass nondeterministic ones. This leads to a frame in which two kinds of correlations emerge: the classical correlation that is coded in the mixed state of the physical system and a new correlation, to be called probabilistic entanglement, which may occur also at pure states. We examine to what extent this characterization of correlations can be applied to quantum mechanics. Explicit calculations on simple examples outline that a same quantum state can show only classical correlations or only entanglement depending on its statistical content; situations may also arise in which the two kinds of correlations compensate each other.     

Deriving Internal Energy by Virtue of Generalized Feynman-Hellmann Theorem for Mixed States

We show how to directly use the generalized Feynman-Hellmann theorem, which is suitable for mixed state ensemble average, to derive the internal energy of Hamiltonian systems. A concrete example, which is a two coupled harminic oscillators, is used for elucidating our approach.     

模拟海市蜃楼实验的配液新方案

分析了配制传统模拟海市蜃楼溶液的方法的不足,提出了新的配制溶液的方案,推导出了所配制的溶液浓度梯度随高度的分布公式,从而使实验过程中配液的时间大大缩短,实验现象更加明显,提高了实验的成功率.     

装备电子设备边界扫描系列标准及测试性设计技术研究

随着新一代电子产品的复杂化和密集程度的不断提高,电路和系统的可测试性急剧下降,传统测试技术已经不能满足需要。针对我国军用电子设备的测试及诊断工作需求,通过对IEEE1149系列边界扫描测试标准进行了研究分析,分析各标准的特征范围、适用对象、各标准相互关系,可以分析梳理IEEE1149标准在我国军用电子设备测试性设计中的可行性和适用性,探索得到将边界扫描技术在测试性设计上的应用思路。将边界扫描技术应用于电子设备不同范围的测试设计,能有效地解决传统测试性设计的问题,能够提升诊断能力,缩减产品生产周期及研制费用。     

EPR evidence of local lattice mode in K3H(SO4)2 and Rb3H(SO4)2 fast-proton conductors

The observation of an anomalous temperature dependence of Mn²⁺ EPR spectra linewidth and nonaxial crystal-field parameter in K₃H(SO₄)₂ and Rb₃H(SO₄)₂ allows one to suggest the presence of “local mode” predicted by Yamada (Ferroelectrics 170 (1995) 23). The activation energy for this kind of excitation was found and equals 11.3 (0.5) and 7.4 (0.3) meV for Mn²⁺ doped K₃H(SO₄)₂ and Rb₃H(SO₄)₂, respectively.