Estimation of the protonic concentration and mobility in Ba(Zr0.81Yb0.15Zn0.04)O3−δ ceramic

Rare earth doped BaZrO₃ is one of most promising proton conducting oxides as it has high proton conductivity and sound chemical stability. Sintering aids such as ZnO, however, should be incorporated in order to improve poor sinterability. In this study, the effects of adding ZnO on proton conductivity of Yb-doped BaZrO₃ (BZYb) were investigated. From the electrical conductivities measured under various water vapor pressures, concentration and mobility of the proton were obtained. Proton mobility of BZYb with ZnO (BZYb-Zn) was smaller than that of BZYb while hydration enthalpy of BZYb-Zn was more negative than that of BZYb.     

Stochastic resonance in a time-delayed asymmetric bistable system with mixed periodic signal

This paper studies the phenomenon of stochastic resonance in an asymmetric bistable system with time-delayed feedback and mixed periodic signal by using the theory of signal-to-noise ratio in the adiabatic limit. A general approximate Fokker--Planck equation and the expression of the signal-to-noise ratio are derived through the small time delay approximation at both fundamental harmonics and mixed harmonics. The effects of the additive noise intensity $Q$, multiplicative noise intensity $D$, static asymmetry $r$ and delay time $\tau$ on the signal-to-noise ratio are discussed. It is found that the higher mixed harmonics and the static asymmetry $r$ can restrain stochastic resonance, and the delay time $\tau $ can enhance stochastic resonance. Moreover, the longer the delay time $\tau $ is, the larger the additive noise intensity $Q$ and the multiplicative noise intensity $D$ are, when the stochastic resonance appears.     

Error Estimates of Mixed Methods for Optimal Control Problems Governed by General Elliptic Equations

In this paper, we investigate the error estimates of mixed finite element methods for optimal control problems governed by general elliptic equations. The state and co-state are approximated by the lowest order Raviart-Thomas mixed finite element spaces and the control variable is approximated by piecewise constant functions. We derive $L^2$ and $H^{-1}$-error estimates both for the control variable and the state variables. Finally, a numerical example is given to demonstrate the theoretical results.     

SrF2-CaF2混合物薄膜的物理及红外光学特性研究

采用热蒸发和电子束蒸发两种沉积方式分别沉积了相同厚度的SrF₂-CaF₂ (比例为1∶1) 的混合物薄膜,对其物理和光学特性进行了研究,并定量地给出了其在红外波段的光学常数,填补了这一数据的空白. 同时提供了一种获得不同低折射率薄膜的方法.文中还以该比例的混合物作为低折射率材料,研制出具有很好的光学性能的长波红外宽光谱增透膜.     

The effects of cubic potentials on discrete breathers in a mixed Klein－Gordon /Fermi－Pasta－Ulam chain

Nonlinearity has a crucial impact on the symmetry properties of dynamical systems. This paper studies a one-dimensional mixed Klein--Gordon/Fermi--Pasta--Ulam diatomic chain using the expanded rotating plane-wave approximation and numerical calculations to determine the effect of cubic potentials on the symmetry properties of discrete breathers in this system. The results will be very useful to researchers in the field of numerical calculations on discrete breathers.     

有源介观LC电路的量子涨落

本文利用含时微扰论,研究了电源幅值较小时介观LC电路中电荷与电流的量子涨落。在确定的温度下,系统将处在混合态,进一步得到有限温度下含源介观LC电路的量子涨落。研究表明有源介观LC电路的量子涨落不仅与电路参数有关,还与时间和温度有关。     

Reactivity of mixed organozinc and mixed organocopper reagents. Part 4: a kinetic study of group transfer selectivity in C?C coupling of mixed diorganocuprates

The competitive rate data and Taft relationships for the coupling of bromomagnesium n‐butyl (substituted phenyl) cuprates with alkyl bromides show that selective n‐butyl transfer can be explained by an oxidative addition mechanism. Taft reaction constants also show that the residual group FG‐C₆H₄ in the mixed cuprate n‐Bu(FG‐C₆H₄)CuMgBr changes the ability of the copper nucleophile to react with the electrophile RBr. These results provide support for the commonly accepted hypothesis regarding the dependence of the R¹ group transfer ability on the strength of R²? Cu bond in reactions of R¹R²CuMgBr reagents. Copyright © 2009 John Wiley & Sons, Ltd.     

纳米混合分子聚集体材料中弗兰克尔激子迁移的相位弛豫

在有机染料ＰＩＣ－１中引入其衍生物ａｚａＰＩＣ－Ｉ形成能量势垒，改变在混合分子聚集体中ＰＩＣ－Ｉ的Ｊ－聚集体的实体长度。用双调制外差检测的累积光子回波技术研究了相干弗兰克尔激子失相过程。观测到激子失相时间Ｔ２随ａｚａＰＩＣ－１克分子数的增大从６０ｐｓ变为２２４ｐｓ。     

一种改进的视觉传感器与激光测距雷达特征匹配点提取算法

激光测距雷达与视觉传感器的配准是视觉图像与激光距离信息融合的前提。激光测距雷达与视觉传感器的配准可分为点匹配与平面匹配。由于混合像素和非结构空间特征激光点丢失现象,使得基于点匹配的视觉传感器与激光测距雷达配准算法精度难以提高。通过对混合像素和非结构空间特征激光点丢失问题的分析,提出了一种结合平面建模思想,利用假想激光光束与平面模型相交提取匹配特征点的方法。验证了实验结果并进行了算法精度比较。实验结果表明,这种改进的特征匹配点提取算法解决了特征点缺失,并且提高了点匹配的精度,使匹配性能大大地改善。     

大气风场探测萨尼亚克干涉仪光程差的计算及探测模式研究

提出了基于时空混合调制的大气风场探测模式;应用光线追迹方法推导了一种改型萨尼亚克干涉仪在任意角入射时的光程差;从理论上对该干涉仪的参量作了分析计算;通过对同种、异种材料组合的理论分析,得出了异种材料组合的改型萨尼亚克干涉仪更加适合高层大气风场探测。该干涉仪具有稳态、大视场、大光程差、时空混合调制探测模式等显著特点。该研究发展了高层大气风场的被动探测理论,对风场探测技术研究、探测模式和工程化都具有十分重大的理论及实践意义。