添加剂Si对NiMnCo触媒合成金刚石的影响

本文研究了添加剂Si对NiMnCo粉末触媒合成金刚石生长特性的影响.实验中将不同比例的无定形Si粉直接添加到Ni-Mn-Co-C体系中并均匀混合,在国产六面顶压机上进行了金刚石单晶的合成实验.结果表明,由于掺Si量的不同,合成金刚石的最低生长压力有所不同,"V"形区发生了移动;通过考察Ni-Mn-Co-C和Ni-Mn-Co-Si-C两种体系中合成金刚石的情况并借助于光学显微镜,发现两种体系所合成的晶体颜色变化并不大,但随着Si含量的增加,晶体的完整性变差,包裹体增多;通过XPS检测发现,在Ni-Mn-Co-Si-C体系所合成的金刚石当中存在SiC.     

Transitional Process of Ploy（N-isopropylacrylamide） in Deuterated Solution

The fast phase-transitional process of ploy（N-isopropylacrylamide） （PNIPAM） in deuterated solution was studied by laser induced temperature jump technique combined with time-resolved mid-infrared absorbance difference spectroscopy on nanosecond level. The multi-peaks of amide I＇band of PNIPAM among the energy range of 1565-1700 cm^-1 was experimentally resolved to three groups （i, ii, iii） for the first time, while the distinct threestage procedure in the phase transitional process of long-chain PNIPAM was observed firstly too. Furthermore, proper assignments were also made for the three group peaks in amide I＇band and the three steps in the kinetics process of long-chain PNIPAM.     

Chaos control of a nonlinear oscillator with shape memory alloy using an optimal linear control: Part II: Nonideal energy source

In Part II of this two-part work, we apply an optimal linear control technique to suppress chaotic behavior in a SMA oscillator, driven by a DC motor with limited power supply (Nonideal sources). Nonideal sources of vibrations of structures are those whose characteristics are coupled to the motion of the structure. Thus, in this case, an additional equation of motion is written, related to the motor rotation. Special attention is focused into the resonance region, when the nonideal excitation frequency is near the natural frequency of the SMA oscillator. Numerical results are presented, which show the efficiency of the method in resonance region. The ideal case, when we do not consider the interaction between an energy source and structure was considered in Part I of this paper.     

CH3SS与XO (X＝F,Cl, Br)反应过程的电子密度拓扑研究

利用MP2/6-311＋＋G(d,p)//B3LYP/6-311＋＋G(d,p)对CH3SS与XO (X＝F, Cl, Br)的反应机理进行了研究. 着重从电子密度拓扑分析角度讨论了化学键的生成和断裂. 计算结果表明单线态反应为主要反应通道, 且由于该通道的反应能垒低、放热明显, 说明CH3SS与XO在大气中比较容易进行. 电子密度拓扑分析表明, 在单线态抽氢反应通道中存在着四元环状过渡结构, 随着反应进行, 此四元环状过渡结构通过一个T-型结构变为三元环状过渡结构, 最后环状结构消失得到产物.     

大豆蛋白的中红外和近红外光谱研究*

大豆蛋白在各领域的应用已得到广泛的关注,因此大豆蛋白及其改性材料在结构性能方面的研究显得越来越重要。中红外光谱(mid-infrared spectroscopy,MIR)和近红外光谱(near-infrared spectroscopy,NIR)正是对蛋白质进行定性定量分析的有力手段。中红外光谱可以有效地分析大豆蛋白在溶液和薄膜中的二级结构以及大豆衍生材料内蛋白质的结构变化情况。近红外光谱则在蛋白质定量分析方面有着独特的优势。本文介绍了运用这两种光谱技术进行研究的一些工作,这些实例表明了中红外和近红外光谱在大豆蛋白研究领域的重要应用价值。     

汶川地震后四川省巴州区地质灾害特征研究

5•12汶川大地震震后,对四川省巴州区次生地质灾害应急调查表明,地质构造和地形地貌是巴州区地质灾害形成的主导因素,降雨是地质灾害的主要诱发因素。巴州区主要的地质灾害类型为崩塌和滑坡,其中崩塌的危害性较大。现场调查表明,巴州区崩塌地质灾害类型以岩质崩塌为主,滑坡地质灾害类型以残积层滑坡为主,主要分布在构造侵蚀中低山和侵蚀剥蚀桌状低山地貌区。5•12汶川地震对潜在的崩塌危岩体的稳定性有不良的影响。     

内部带特征约束的任意平面域的三角形网格生成方法

基于Ｄｅｌａｕｎａｙ三角化方法 ,给出了内部带有任意复杂特征约束的任意平面域的三角形网格生成方法。区域内部特征约束可以是点、直线、圆、圆弧、平面样条曲线以及由它们组合构成的封闭环或者不封闭环。     

SR8型双踪示波器软故障分析及判断

本应用静态工作点测量电路工作状态,应用动态波形测量法分析判断故障产生原因,对失真波形进行定量测量及分析原因。     

离散元数值模拟中查找邻居元关系的改进算法

离散元方法是近年发展起来的有前途的新概念数值模拟方法,然而查找邻居元关系耗费大量机时和内存。本文引入一种改进算法-“区域法”,并对其原理、算法、运行时间和空间进行了分析。和原算法中的“窗口法”的比较结果表明,新算法在运行时间和空间方面均明显优于原算法。     

TWO ALGORITHMS FOR LC~1 UNCONSTRAINED OPTIMIZATION

1. IntroductionThe LCI optimization problems exist extensively in various optimization problems.FOr example, the problems from nonlinear complementarity) variational inequality andCd nonlinear programming can be formed as LCI optimization problems. In addition,LCI optimization problems also arise from the extended linear-quadratic programmingproblems, nonlinear minimax problems, stochastic optimization problems and somesemi-infinite programs. See [6] [9] [11] [13] [14] [151 [17] [21].In t…