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81.
Hierarchical structure in polymer‐based drug delivery systems as probed by calorimetric measurements
Pascale Valot Nathalie Sintes‐Zydowicz Jean‐Marie Nedelec Mohamed Baba 《Journal of Polymer Science.Polymer Physics》2010,48(18):1939-1945
Thermoporosimetry (TPM), a differential scanning calorimetry technique that relies on the shift of transition temperatures caused by the confinement of liquids, was applied to elucidate the complex morphology of drug‐loaded polymeric microcapsules prepared by the emulsion solvent evaporation method. For the very first time, TPM has been applied simultaneously with two liquids as structural probes. It was found that Miglyol, which dissolves the selected drug (Ibuprofen), is confined inside vesicles having a mean radius of 26.3 nm, whereas water, which is the continuous phase, is trapped inside a swollen polymeric network of Eudragit with an average mesh radius of 1.7 nm. A proposed hierarchical structure is given, which predicts that Eudragit microcapsules are formed from a collection of inert oil vesicles partitioned by polymeric Eudragit membranes swollen by water. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1939–1945, 2010 相似文献
82.
Blue vitriol (copper(II) sulfate pentahydrate), CuSO4·5H2O has been chosen and investigated for its effectiveness as a flame-retardant, when impregnated into cotton fabric (cotton
with a plain structure; woven 180 g m−2, with 22 numbers of yarns per 10 mm). Using the vertical flame test, the extent of resistance to burning of the specimens
has been determined. The impregnation was accomplished via dipping and stirring of bone-dried, weighed fabrics into the individual
and suitable concentrations of the salt at room temperature. Afterwards the samples were squeeze rolled and dried horizontally
at 110°C for 30 min in an oven and cooled in a desiccator and reweighed with an analytical precision. They were then kept
under ordinary conditions overnight prior the fulfillment of the vertical flame test. The efficient quantities of the aforesaid
salt expressed in g per 100 g dry fabric have been determined in an average figure of 12.75%. Estimation of uniformity in
a selected sample was carried out via a spectrophotometer and results are in favor of the heterogeneous distribution of the
salt in the fabric’s middle sectors. However initial and final parts of specimen showed to be rather uniformed. Thermogravimetric
analysis of the pure cotton and the treated ones with insufficient and effective amounts of the salt were fulfilled and their
thermograms were compared and commented. The results obtained for the effect of copper(II) sulfate comply with ‘The Dust or
Wall Effect Theory’. This action is also assigned to the condensed phase retardation. 相似文献
83.
Yapeng Fang Saphwan Al-Assaf Glyn O. Phillips Katsuyoshi Nishinari Takahiro Funami Peter A. Williams 《Structural chemistry》2009,20(2):317-324
The physiological functions of the two ions, Ca2+ and H+, in controlling mechanical properties of plant cell wall are reviewed. The interactions of these ions with major cell wall
polysaccharides during cell growth and development are described. Experimental results for Ca2+/H+-induced molecular associations of some polysaccharides in solutions are also given. This article aims to bridge the understandings
of molecular associations in solutions (in vitro) with those occurring in cell wall matrix of high order structure (in vivo). 相似文献
84.
In a previous paper[1], a method has been developed to study the stability characteristics of laminar boundary layers over compliant walls. In this
paper, the effect of double layered compliant wall and Kramer type compliant wall on delaying the transition is investigated,
and it is shown that there does exist the possibility to delay the transition by applying such compliant walls.
The project supported by the National Natural Science Foundation of China. 相似文献
85.
Daniel P. N. Vlasveld Hartmut R. Fischer Erik Swierenga Stephen J. Picken 《Journal of Polymer Science.Polymer Physics》2008,46(18):1914-1922
The results of a calorimetric study on the melting and crystallization behavior of concentrated sulfuric acid containing dispersed single wall carbon nanotubes (SWCNT), dissolved water, and dissolved poly‐p‐phenyleneterphthalate (PPTA) polymer are presented. The measured reduction of the heat of crystallization is caused by the build‐up of an associated layer of structured acid molecules around SWCNT and PPTA. The freezing point depression is related to the number of dissolved species such as ions. It is shown that this theory accurately describes the experimental data for dissolved water and sulfur trioxide, but not for large molecules such as SWCNT. A mechanism for the interaction between sulfuric acid and SWCNT is proposed, based on preferred adsorption of sulfur trioxide and dissociation of sulfuric acid, leading to an increased number of dissolved low‐molecular‐weight species. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 1914–1922, 2008 相似文献
86.
This paper reports on geometry dependent viscosity curves of the biaxial thermotropic LC-Polymer Vectra B 950 measured with rectangular slit dies. The geometry dependence of the flow behaviour originates from the flow of two layers. The layer near the wall is highly flow oriented and free from defects. The layer in the bulk has an ordered texture. The thickness of the wall layer decreases with wall shear stress. Based on the Frank theory and the assumption that the core of a moving disclination is the smallest radius of distortion, the wall layer thickness is predicted and compared with experimental data. 相似文献
87.
Faruk Civan 《Transport in Porous Media》2007,67(2):329-334
An Arrhenius-type asymptotic-exponential function is derived to describe the temperature dependence of the power needed for
detachment of fine particles from pore walls in porous media. 相似文献
88.
89.
Pulsatile flows in a lateral aneurysm anchored on a stented and curved parent vessel 总被引:5,自引:0,他引:5
We present particle tracking velocimetry measurements and flow visualization of pulsatile flow fields in a stented cerebrovascular
lateral aneurysm model with a wide ostium anchored on a curved parent vessel. Among the stent parameters, the blocking ratioC
α ranging from 0% to 75% was selected to study its effect on the changes of intra-aneurysmal hemodynamics for the reference
of minimally invasive endovascular aneurysm treatment. The Womersley number was 3.9 and the mean, peak, and minimal Reynolds
numbers based on the bulk average velocity and diameter of the parent vessel were 600, 850, and 300, respectively. The results
are characterized in terms of velocity vector field, coded streak images, region averaged velocity, vorticity, and wall shear
stress. A critical range ofC
α related to the inflow location as well as the shape and number of intra-aneurysmal vortices is identified. The intra-aneurysmal
flow activity, vortex strength, and wall shear stress are found to decrease with increasingC
α. Among theC
α examined,C
α=75% is the most favorable in attenuating the risk of aneurysmal rupture and promoting intra-aneurysmal thrombus. 相似文献
90.
V. N. Zaikovskii S. P. Kiselev V. P. Kiselev 《Journal of Applied Mechanics and Technical Physics》2005,46(5):670-676
Large-scale streamwise vortices in the vicinity of a perforated wall in the supersonic part of the nozzle are studied. The governing effect of gas inflow through a perforated wall on origination and parameters of streamwise vortices is experimentally established.__________Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 46, No. 5, pp. 68–75, September–October, 2005. 相似文献