全文获取类型
收费全文 | 1848篇 |
免费 | 199篇 |
国内免费 | 660篇 |
专业分类
化学 | 2310篇 |
晶体学 | 8篇 |
力学 | 47篇 |
综合类 | 25篇 |
数学 | 11篇 |
物理学 | 306篇 |
出版年
2024年 | 6篇 |
2023年 | 15篇 |
2022年 | 42篇 |
2021年 | 54篇 |
2020年 | 73篇 |
2019年 | 79篇 |
2018年 | 78篇 |
2017年 | 57篇 |
2016年 | 71篇 |
2015年 | 82篇 |
2014年 | 99篇 |
2013年 | 133篇 |
2012年 | 126篇 |
2011年 | 122篇 |
2010年 | 125篇 |
2009年 | 120篇 |
2008年 | 128篇 |
2007年 | 148篇 |
2006年 | 129篇 |
2005年 | 129篇 |
2004年 | 115篇 |
2003年 | 104篇 |
2002年 | 86篇 |
2001年 | 79篇 |
2000年 | 77篇 |
1999年 | 66篇 |
1998年 | 56篇 |
1997年 | 49篇 |
1996年 | 41篇 |
1995年 | 43篇 |
1994年 | 31篇 |
1993年 | 20篇 |
1992年 | 13篇 |
1991年 | 20篇 |
1990年 | 13篇 |
1989年 | 13篇 |
1988年 | 11篇 |
1987年 | 9篇 |
1986年 | 6篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有2707条查询结果,搜索用时 265 毫秒
21.
22.
23.
XinZHANG DeHuaHE QiJiangZHANG BoQingXU QiMingZHU 《中国化学快报》2003,14(10):1066-1069
Comparatively high CH3OH selectivity (60.0%) and yield (6.7%) were obtained on MoOx/(LaCoO3 Co3O4) catalysts in selective oxidation of methane to methanol using molecular oxygen as oxidant. The interaction between MoOx and La-Co-oxide modified the molecular structure of molybdenum oxide and the ratio of O^-/O^2- on the catalyst surface, which controlled the catalytic performance of MoOx/(LaCoO3 Co3O4) catalysts. 相似文献
24.
Ryashentseva M. A. Egorova E. V. Trusov A. I. Antonyuk S. N. 《Russian Chemical Bulletin》2002,51(9):1698-1701
The activity and selectivity of mono- and bimetallic catalysts containing copper and rhenium on sibunite were studied in the decomposition of methanol to methyl formate (MF), water, H2, CO, and CO2at 200—400 °C. Methane is also formed on rhenium-containing catalysts at 300—400 °C. The dehydrogenating activity and selectivity to form MF are higher on the copper-sibunite catalysts than on the rhenium-sibunite samples. The introduction of 0.25% Re into the 4% copper-containing catalyst enhances its total activity and stability. 相似文献
25.
IntroductionIthasbccndcmonstratcdthatmcthancrcformingt"ithcarbondioxidcpr0ducessynthcsisgasrichincarbonmonoxidc-x"hichisuscfulforthcs}nthcsisofaccticacid'dimcthylcthcrando.o-alcoholsll'2].Carbondioxidcref0rmingismorccndothcrmicthanstcamrcformingfCH4 CO2,'2CO 2H2Ai/'2,,=2473kJ..ol-1(l)Accordingl\"thisrcact1onnccdshighcrtcmpcraturcandlimitsspaccvclocityoffccdgas,Wehavcprct'ious1\studicdmcthancrcformingt"lthC02inthcmonotubcproccssl3J.Inordertoconvcrtmcthancinfccdgascomplctcl}',thcspaccvcloci… 相似文献
26.
The molar conductances of dilute solutions of salicylic and monochloroacetic acids in binary mixtures of methanol, ethanol, 1-propanol, N,N-dimethylformamide, acetone, acetonitrile, tetrahydrofuran and dioxane with water have been measured at 25°C. The Lee-Wheaton conductance equation was fitted to the data in order to derive thermodynamic dissociation constants and limiting molar conductances. The results were compared with those in the literature pertaining to analogous media, mostly derived potentiometrically. The findings are interpreted in terms of a solvent effect on the ionization of these acids in mixed solvent systems.This paper is dedicated to the late Professor Raymond M. Fuoss on his 3rd anniversary. 相似文献
27.
NdOx作为助催化剂对PtRu/C电催化氧化甲醇活性的影响 总被引:5,自引:0,他引:5
采用沉积-还原法制备了PtRu-NdOx/C催化剂, 借助TEM、EDS和XRD等测试手段对其进行了微结构和组成的表征. 结果表明, 催化剂中Pt与Ru以合金形式存在, 而Nd的氧化物则以无定形形态存在. 催化剂粒子的平均粒径在2 nm左右, 晶胞参数为0.3896 nm, Nd氧化物的加入对PtRu合金的晶体结构影响不明显. 采用循环伏安法和计时电流法, 比较了PtRu-NdOx/C催化剂和PtRu /C催化剂对甲醇氧化的电催化活性, 结果表明, 加入Nd的氧化物作为助催化剂能明显提高PtRu /C催化剂对甲醇氧化的电催化性能. 相似文献
28.
29.
H.-L. Liu S.-J. Liu Z.-L. Xiao Q.-Y. Chen D.-W. Yang 《Journal of Thermal Analysis and Calorimetry》2006,85(3):541-544
Excess molar enthalpies of binary mixtures for tributyl
phosphate (TBP)+methanol/ethanol were measured with a TAM air Isothermal calorimeter
at 298.15 K and ambient. The results for xTBP+(1–x)CH3OH
are negative in the whole range of composition, while the values for xTBP+(1–x)C2H5OH
change from positive values at low x to
small negative values at high x. The experimental
results have been correlated with the Redlich–Kister polynomial. IR
spectra of the mixtures were measured to investigate the effect of hydrogen
bonding in the mixture. 相似文献
30.
The densities of H2O, D2O, and MeOH solutions in acetonitrile with the solute concentrations up to 0.07 molar fractions at 278.15, 288.15, 298.15, 308.15, and 318.15 K were measured using vibrating-tube densimetry with an error 8·10–6 g cm–3. The limiting partial molar volumes for the H/D isotopomers of water and IaII in acetonitrile (V–
2
) and the isotope effects in V–
2
and in excess molar volumes of acetonitrile—water mixtures were calculated. Molecules of H2O, D2O, and IaII form associates with acetonitrile molecules via hydrogen bonds. The associates have the packing volumes close to those in the individual solute. The water and methanol molecules were assumed to be incorporated into the acetonitrile structure without substantial changes in the latter. However, this process results in some compression of the system with a simultaneous increase in its expansibility. 相似文献