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121.
In this article we propose two kinds of new fiber ring structure with a semiconductor optical amplifier. The first structure is a one-fiber-ring amplifier with an 8 × 8 fiber coupler and a semiconductor optical amplifier (SOA). The second fiber ring structure is a two-fiber-ring laser including an 8 × 8 fiber coupler, a 2 × 2 E/O modulator, and an SOA. The 14-output spectra of the fiber laser are measured. The gain coefficients of each port of the multiple-output-fiber-ring amplifiers are also measured. We apply these two kinds of fiber ring structures in a hybrid CATV and ADSL broadcasting optical fiber communication system. This application can develop a broadcasting system with large coverage area without using many laser diodes and optical amplifiers. The performance of such a system is also analyzed in this article. 相似文献
122.
123.
《International Journal of Polymer Analysis and Characterization》2012,17(4):289-300
Abstract In this study, polyethylene oxide chains have been hydrophobically end-modified with naphthalene groups (PEO-N), and water soluble ß-cyclodextrin polymers (ß-CD/EP) have been synthesized. An original associating system can be obtained by mixing these two polymers in aqueous solutions. Inclusion complex formation between the hydrophobic moieties of the PEO-N chains and the ß-cyclodextrin cavities of the ß-CD/EP polymers are at the origin of the polymolecular associations. Fluorescence anisotropy measurements allowed the determination of the complexation constants, and the onset of the polymolecular associations have been monitored by viscosimetry. The PEO chain length influence has been studied by using two molecular weights, 6000 and 20000. 相似文献
124.
125.
PSO萃取色层分离原子发射光谱测定氧化钇中十四个稀土杂质 总被引:3,自引:0,他引:3
本将石油亚砜浸渍在一种特制的吸附树脂上,用PSO为固定相的萃取色层法分离氧化钇中痕量稀土杂质,可以分析6-7N级的氧化钇样品,加入试验的回收率为67-120%,相对标准偏左为±4-19.4%。 相似文献
126.
127.
《结构化学》2024,43(7):47-53
Zero-dimensional(0D)hybrid metal halides are considered as promising light-emitting materials due to their unique broadband emission from self-trapped excitons(STEs).Despite substantial progress in the development of these materials,the photoluminescence quantum yields(PLQY)of hybrid Sb-Br analogs have not fully realized the ca-pabilities of these materials,necessitating a better fundamental understanding of the structure-property relation-ship.Here,we have achieved a pressure-induced emission in 0D(EATMP)SbBr5(EATMP=(2-aminoethyl)trimethylphosphanium)and the underlying mechanisms are investigated using in situ experimental characterization and first-principles calculations.The pressure-induced reduction in the overlap between the STE states and ground states(GSs)results in the suppression of phonon-assisted non-radiative decay.The photoluminescence(PL)evo-lution is systematically demonstrated to be controlled by the pressure-regulated exciton-phonon coupling,which can be quantified using Huang-Rhys factorS.Through detailed studies of the S-PLQY relation in a series of 0D hybrid antimony halides,we establish a quantitative structure-property relationship that regulating S value toward 21 leads to the optimized emission.This work not only sheds light on pressure-induced emission in 0D hybrid metal halides but also provides valuable insights into the design principles for enhancing the PLQY in this class of materials. 相似文献
128.
The orientations of water molecules next to metal ions in salt hydrates are useful indications of the orientations which may be expected for water molecules which are next to metal ions in aqueous solution. A survey of the data for the salt hydrates shows that a water molecule may often be tetrahedral (i.e., coordinated to the metal ion, accepting a hydrogen bond from another water molecule, and donating two hydrogen bonds) if it is next to a +1 ion, a+2 ion, or a+3 ion of the rare earth series, although apparently not for smaller +3 ions. 相似文献
129.
1,3-Dimethylethyleneurea (DMEU) and 1,3-dimethylpropyleneurea (DMPU) were investigated as electrolytic media for a number of alkali metal and triisoamylbutylammonium salts via conductivity measurements over a concentration range of 1–100×10–4
M at 25°C. The data were analyzed by the Fuoss-Shedlovsky, Fuoss-Onsager, and expanded Pitts equations. The limiting equivalent conductivities were about 1.5 times greater in DMEU than in DMPU, which is exactly the ratio of the viscosities. From the Fuoss-Onsager analysis, all salts studied were found to be essentially unassociated in both solvents. From the expanded Pitts equation the extent of association was small, but within a salt series the equation indicated that association decreased in the order iodides, thiocyanates > perchlorate > tetraphenylborates. Neither solvent differentiated between sodium and potassium ion mobilities, indicating a type of solvation behavior different from that in acyclic urea solvents such as tetramethyl- and tetraethylurea. 相似文献
130.
A potentiometric method using a glass electrode has been applied to determination of ionization constants for deuterium oxide (D2O) in binary mixtures of D2O with dioxane, tetrahydrofuran, acetone, dimethylsulfoxide, CH3CH2OD, and CH3OD at 25°C. The results are compared with values of ionization constants for H2O obtained previously in the corresponding H2O-organic mixtures, and the isotope effect is shown to be small. Further calculations with the D2O results show that the first five solvents mentioned above are neither appreciably acidic nor basic in D2O solution, but that CH3OD shows slightly acidic behavior (pKa=16.0±0.3). 相似文献